Chloride Inclusion and Hole Transport Material Doping to Improve Methyl Ammonium Lead Bromide Perovskite-Based High Open-Circuit Voltage Solar Cells. Edri, E., Kirmayer, S., Kulbak, M., Hodes, G., & Cahen, D. The Journal of Physical Chemistry Letters, 5(3):429-433, 2, 2014.
Chloride Inclusion and Hole Transport Material Doping to Improve Methyl Ammonium Lead Bromide Perovskite-Based High Open-Circuit Voltage Solar Cells [link]Website  abstract   bibtex   
Low-cost solar cells with high VOC, relatively small (E G - qVOC), and high qVOC/EG ratio, where EG is the absorber band gap, are long sought after, especially for use in tandem cells or other systems with spectral splitting. We report a significant improvement in CH3NH3PbBr3-based cells, using CH3NH3PbBr3-xClx, with EG = 2.3 eV, as the absorber in a mesoporous p-i-n device configuration. By p-doping an organic hole transport material with a deep HOMO level and wide band gap to reduce recombination, the cell's VOC increased to 1.5 V, a 0.2 V increase from our earlier results with the pristine Br analogue with an identical band gap. At the same time, in the most efficient devices, the current density increased from ∼1 to ∼4 mA/cm2. © 2014 American Chemical Society.
@article{
 title = {Chloride Inclusion and Hole Transport Material Doping to Improve Methyl Ammonium Lead Bromide Perovskite-Based High Open-Circuit Voltage Solar Cells},
 type = {article},
 year = {2014},
 identifiers = {[object Object]},
 keywords = {high open-circuit voltage,organic-inorganic lead halide perovskite,solar cell},
 pages = {429-433},
 volume = {5},
 websites = {http://pubs.acs.org/doi/10.1021/jz402706q},
 month = {2},
 day = {6},
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 abstract = {Low-cost solar cells with high VOC, relatively small (E G - qVOC), and high qVOC/EG ratio, where EG is the absorber band gap, are long sought after, especially for use in tandem cells or other systems with spectral splitting. We report a significant improvement in CH3NH3PbBr3-based cells, using CH3NH3PbBr3-xClx, with EG = 2.3 eV, as the absorber in a mesoporous p-i-n device configuration. By p-doping an organic hole transport material with a deep HOMO level and wide band gap to reduce recombination, the cell's VOC increased to 1.5 V, a 0.2 V increase from our earlier results with the pristine Br analogue with an identical band gap. At the same time, in the most efficient devices, the current density increased from ∼1 to ∼4 mA/cm2. © 2014 American Chemical Society.},
 bibtype = {article},
 author = {Edri, Eran and Kirmayer, Saar and Kulbak, Michael and Hodes, Gary and Cahen, David},
 journal = {The Journal of Physical Chemistry Letters},
 number = {3}
}

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