Molecular chirality at surfaces. Ernst, K. physica status solidi (b), 249(11):2057–2088, 2012. _eprint: https://onlinelibrary.wiley.com/doi/pdf/10.1002/pssb.201248188
Molecular chirality at surfaces [link]Paper  doi  abstract   bibtex   
With the adsorption of larger molecules being increasingly tackled by surface scientists, the aspect of chirality often plays a role. This paper gives a topical review of molecular chirality at surfaces and gives a phenomenological overview of different aspects of adsorption and self-assembly of chiral and prochiral molecules and the principles of mirror-symmetry breaking at a surface. After a brief introduction into the history of molecular chirality and the important role it played for understanding the spatial structure of molecules, definitions of chirality are presented. Topics treated here are principle ways to create single chiral adsorbates, chiral ensembles, and monolayers by achiral molecules, adsorption of intrinsically chiral molecules at achiral and chiral surfaces, long-range symmetry breaking in two-dimensional (2D) crystals due to additional chiral bias, chiral restructuring of solid surfaces under the influence of chiral molecules, switching the handedness of adsorbates, and chirality at the liquid/air interface. An outlook onto further potential research directions and recommendations for further reading, including nonsurface-related sources of chiral topics completes this paper.
@article{ernst_molecular_2012,
	title = {Molecular chirality at surfaces},
	volume = {249},
	copyright = {Copyright © 2012 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim},
	issn = {1521-3951},
	url = {https://onlinelibrary.wiley.com/doi/abs/10.1002/pssb.201248188},
	doi = {10.1002/pssb.201248188},
	abstract = {With the adsorption of larger molecules being increasingly tackled by surface scientists, the aspect of chirality often plays a role. This paper gives a topical review of molecular chirality at surfaces and gives a phenomenological overview of different aspects of adsorption and self-assembly of chiral and prochiral molecules and the principles of mirror-symmetry breaking at a surface. After a brief introduction into the history of molecular chirality and the important role it played for understanding the spatial structure of molecules, definitions of chirality are presented. Topics treated here are principle ways to create single chiral adsorbates, chiral ensembles, and monolayers by achiral molecules, adsorption of intrinsically chiral molecules at achiral and chiral surfaces, long-range symmetry breaking in two-dimensional (2D) crystals due to additional chiral bias, chiral restructuring of solid surfaces under the influence of chiral molecules, switching the handedness of adsorbates, and chirality at the liquid/air interface. An outlook onto further potential research directions and recommendations for further reading, including nonsurface-related sources of chiral topics completes this paper.},
	language = {en},
	number = {11},
	urldate = {2023-09-28},
	journal = {physica status solidi (b)},
	author = {Ernst, Karl-Heinz},
	year = {2012},
	note = {\_eprint: https://onlinelibrary.wiley.com/doi/pdf/10.1002/pssb.201248188},
	keywords = {chirality, molecular self-assembly, scanning tunnelling microscopy, surface crystallography},
	pages = {2057--2088},
}

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