Precipitation of LDPE-EPDM and LDPE-EVA mixtures from ternary solutions. Esperidião, M. C. A. & Galembeck, F. European Polymer Journal, 33(8):1387–1393, August, 1997. Paper doi abstract bibtex The fast precipitation of mixtures of low-density polyethylene (LDPE) with ethylene-propylene-diene terpolymer (EPDM) and ethylene-vinyl acetate (EVA) copolymer, from xylene solutions by cooling, leads to fractionation of the mixtures. LDPE/EPDM mixtures are also fractionated by cooling followed by nonsolvent addition. Studies by density-gradient centrifugation, IR spectroscopy, optical microscopy and wide-angle X-ray diffraction showed that the composition and morphology of LDPE/EPDM fractions depend on the precipitation procedures. LDPE crystalline structure in each fraction is different, changes with the time and depends on EPDM content. EVA fractions that co-precipitate are richer in -CH2-CH2-units. LDPE/EPDM and LDPE/EVA precipitates showed chemical composition distribution and morphological characteristics different among themselves. Larger aggregates were observed in the LDPE/EPDM precipitates. These differences were attributed to differences in the phase diagrams and in the phase separation mechanisms.
@article{esperidiao_precipitation_1997,
title = {Precipitation of {LDPE}-{EPDM} and {LDPE}-{EVA} mixtures from ternary solutions},
volume = {33},
issn = {0014-3057},
url = {https://www.sciencedirect.com/science/article/pii/S0014305796002455},
doi = {10.1016/S0014-3057(96)00245-5},
abstract = {The fast precipitation of mixtures of low-density polyethylene (LDPE) with ethylene-propylene-diene terpolymer (EPDM) and ethylene-vinyl acetate (EVA) copolymer, from xylene solutions by cooling, leads to fractionation of the mixtures. LDPE/EPDM mixtures are also fractionated by cooling followed by nonsolvent addition. Studies by density-gradient centrifugation, IR spectroscopy, optical microscopy and wide-angle X-ray diffraction showed that the composition and morphology of LDPE/EPDM fractions depend on the precipitation procedures. LDPE crystalline structure in each fraction is different, changes with the time and depends on EPDM content. EVA fractions that co-precipitate are richer in -CH2-CH2-units. LDPE/EPDM and LDPE/EVA precipitates showed chemical composition distribution and morphological characteristics different among themselves. Larger aggregates were observed in the LDPE/EPDM precipitates. These differences were attributed to differences in the phase diagrams and in the phase separation mechanisms.},
language = {en},
number = {8},
urldate = {2022-10-20},
journal = {European Polymer Journal},
author = {Esperidião, Maria Cecilia A. and Galembeck, Fernando},
month = aug,
year = {1997},
pages = {1387--1393},
}
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