N , N ′, N ′′ versus N , N ′, O imine-containing coordination motifs: ligand-directed synthesis of mononuclear and binuclear Cu II compounds. Ferraz de Paiva, R., E., Nakahata, D., H., Carvalho, M., A., d., Rodrigues Goulart Bergamini, F., & Corbi, P., P. Acta Crystallographica Section E Crystallographic Communications, 73(10):1563-1567, 10, 2017. ![N , N ′, N ′′ versus N , N ′, O imine-containing coordination motifs: ligand-directed synthesis of mononuclear and binuclear Cu II compounds [link]](https://bibbase.org/img/filetypes/link.svg "link")
Website doi abstract bibtex It is demonstrated here that tridentate imine ligands can control the nuclearity of copper(II) complexes based on the donor atoms present in the ligand. The N , N ′, N ′′-donating imine ligand led to a mononuclear compound, namely dichlorido[ N , N -dimethyl- N ′-(pyridin-2-ylmethylidene)ethane-1,2-diamine]copper(II) monohydrate, [CuCl 2 (C 10 H 15 N 3 )]·H 2 O, 1 , while the N , N ′, O -donating imine ligand produced a binuclear metal complex, namely μ 2 -chlorido-dichlorido(μ 2 -2-[2-(dimethylamino)ethyl]iminomethylphenolato)( N , N -dimethylethylenediamine)dicopper(II) 0.11-hydrate, [Cu 2 (C 11 H 15 N 2 O)Cl 3 (C 4 H 12 N 2 )]·0.11H 2 O, 2 . The structure of 2 is a remarkable example of a binuclear copper(II) complex containing a single substituted 2-iminomethylphenolate ligand that has two copper(II) sites in square-pyramidal coordination.
@article{
title = {N , N ′, N ′′ versus N , N ′, O imine-containing coordination motifs: ligand-directed synthesis of mononuclear and binuclear Cu II compounds},
type = {article},
year = {2017},
pages = {1563-1567},
volume = {73},
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month = {10},
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abstract = {It is demonstrated here that tridentate imine ligands can control the nuclearity of copper(II) complexes based on the donor atoms present in the ligand. The N , N ′, N ′′-donating imine ligand led to a mononuclear compound, namely dichlorido[ N , N -dimethyl- N ′-(pyridin-2-ylmethylidene)ethane-1,2-diamine]copper(II) monohydrate, [CuCl 2 (C 10 H 15 N 3 )]·H 2 O, 1 , while the N , N ′, O -donating imine ligand produced a binuclear metal complex, namely μ 2 -chlorido-dichlorido(μ 2 -2-[2-(dimethylamino)ethyl]iminomethylphenolato)( N , N -dimethylethylenediamine)dicopper(II) 0.11-hydrate, [Cu 2 (C 11 H 15 N 2 O)Cl 3 (C 4 H 12 N 2 )]·0.11H 2 O, 2 . The structure of 2 is a remarkable example of a binuclear copper(II) complex containing a single substituted 2-iminomethylphenolate ligand that has two copper(II) sites in square-pyramidal coordination.},
bibtype = {article},
author = {Ferraz de Paiva, Raphael Enoque and Nakahata, Douglas Hideki and Carvalho, Marcos Alberto de and Rodrigues Goulart Bergamini, Fernando and Corbi, Pedro Paulo},
doi = {10.1107/S2056989017013652},
journal = {Acta Crystallographica Section E Crystallographic Communications},
number = {10}
}
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