@article{Firestone2005,
abstract = {Photochemical reduction of tetrachloroaurate (AuCl 4 -) ions in the highly constrained aqueous domains of a nanostructured ionogel template, formed via self-assembly of the ionic liquid 1-decyl-3- methylimidazolium chloride (C 10mim +Cl) in water, results in the formation of anisotropic gold nanoparticles with a variety of sizes and morphologies, which include previously unattainable trigonal prismatic nanorods. Unexpectedly, small-angle X-ray scattering studies of the Au-ionogel composite reveal that the in situ formation of the nanoparticles increases the mesoscopic order of the ionogel, which results in its conversion to a near-monodomain structure. The findings demonstrate that nanostructured, ionic liquid-based gels can be used to template the formation of new nanoparticle morphologies with technologically important optical, electronic, and catalytic properties. It may also be possible to design soft templates that permit the fabrication of highly ordered nanoparticle array-liydrogel composites, thereby enabling control and tuning of the collective properties of the encapsulated nanoparticles. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA,.},
address = {Materials Science Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439, United States},
annote = {Cited By (since 1996): 53

        
Export Date: 15 January 2013

        
Source: Scopus

        
doi: 10.1002/smll.200500030

        
Language of Original Document: English

        
Correspondence Address: Firestone, M.A.; Materials Science Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439, United States; email: firestone@anl.gov

        
Chemicals/CAS: gold, 7440-57-5; Gels; Gold, 7440-57-5; Hydrogel, 25852-47-5; Ionic Liquids

        
References: Katz, E., Shipway, A., Willner, I., (2003) Nanoscale Materials, pp. 5-64. , Eds.: L. M, Liz-Marzan, P.V. Kamat, Kluwer, London; 
Crooks, R.M., Chechik, V., (2000) J. Am. Chem. Soc., 122, pp. 1243-1244; 
Dirix, Y., Bastiaansen, C., Caseri, W., Smith, P., (1999) Adv. Mater., 11, pp. 223-227; 
Barnes, W.L., Dereux, A., Ebbesen, T.W., (2003) Nature, 424, pp. 824-830; 
Maier, S.A., Kik, P.G., Atwater, H.A., Meltzer, S., Marel, E., Koel, B.E., Requlcha, A.A.G., (2003) Nat. Mater., 2, pp. 229-232; 
Haes, A.J., Van Duyne, R.P., (2002) J. Am. Chem. Soc., 124, pp. 10596-10604; 
Cao, Y.W.C., Jin, R.C., Mirkin, C.A., (2002) Science, 297, pp. 1536-1540; 
Jensen, T.R., Duval, M.L., Kelly, K.L., Lazarides, A.A., Schatz, C.C., Van Duyne, R.P., (1999) J. Phys. Chem. B, 103, pp. 9846-9853; 
Haynes, C.L., McFarland, A.D., Zhao, L.L., Van Duyne, R.P., Schatz, C.C., Gunnarsson, L., Prikulls, J., Kall, M., (2003) J. Phys. Chem. B, 107, pp. 7337-7342; 
Mohamed, M.B., Volkov, V., Link, S., El-Sayed, M.A., (2000) Chem. Phys. Lett., 317, pp. 517-523; 
Schider, G., Krenn, J.R., Gotschy, W., Lamprecht, B., Ditlbacher, H., Leitner, A., Aussenegg, F.R., (2001) J. Appl. Phys., 90, pp. 3825-3830; 
Valden, M., Lai, X., Goodman, D.W., (1998) Science, 282, pp. 1647-1650; 
Gittins, D.I., Bethell, D., Schiffrin, D.J., Nichols, R.J., (2000) Nature, 408, pp. 67-69; 
Appell, D., (2002) Nature, 419, pp. 553-555; 
Martin, C.R., (1996) Chem. Mater., 8, pp. 1739-1746; 
Van Der Zande, B.M.I., Bohmer, M.R., Fokkink, L.G.J., Schonenberger, C., (2000) Langmuir, 16, pp. 451-458; 
Schonenberger, C., Van Der Zande, B.M.I., Fokkink, L.G.J., Henny, M., Schmid, C., Kruger, M., Bachtold, A., Staufer, U., (1997) J. Phys. Chem. B, 101, pp. 5497-5499; 
Martin, C.R., Nishizawa, M., Jirage, K., Kang, M., (2001) J. Phys. Chem. B, 105, pp. 1925-1934; 
Crowley, T.A., Ziegler, K.J., Lyons, D.M., Erts, D., Olin, H., Morris, M.A., Holmes, J.D., (2003) Chem. Mater., 15, pp. 3518-3522; 
Mandal, M., Ghosh, S.K., Kundu, S., Esumi, K., Pal, T., (2002) Langmuir, 18, pp. 7792-7797; 
Huang, L.M., Wang, H.T., Wang, Z.B., Mitra, A.P., Zhao, D., Yan, Y.H., (2002) Chem. Mater., 14, pp. 876-880; 
Faure, C., Derre, A., Neri, W., (2003) J. Phys. Chem. B, 107, pp. 4738-4746; 
Gao, J.X., Bender, C.M., Murphy, C.J., (2003) Langmuir, 19, pp. 9065-9070; 
Firestone, M.A., Tiede, D.M., Seifert, S., (2000) J. Phys. Chem. B, 204, pp. 2433-2438; 
Andersson, M., Alfredsson, V., Kjellin, P., Palmqvist, A.E.C., (2002) Nano Lett., 2, pp. 1403-1407; 
Holbrey, J.D., Seddon, K.R., (1999) Clean Products Processes, 1, pp. 223-236; 
Earle, M.J., Seddon, K.R., (2000) Pure Appl. Chem., 72, pp. 1391-1398; 
Wasserscheid, P., Welton, T., (2003) Ionic Liquids in Synthesis, , Wiley-VCH, Weinheim; 
Firestone, M.A., Dzielawa, J.A., Zapol, P., Curtiss, L.A., Seifert, S., Dietz, M.L., (2002) Langmuir, 18, pp. 7258-7260; 
Dietz, M.L., Dzielawa, J.A., Jensen, M.P., Firestone, M.A., (2003) Ionic Liquids as Green Solvents: Progress and Prospects, 856, pp. 526-543. , Eds.: R. D. Rogers, K. R. Seddon, American Chemical Society, Washington, DC; 
Zhou, Y., Schattaka, J.H., Antoniette, M., (2004) Nano Lett., 4, pp. 477-481; 
Kimizuka, N., Nakashima, T., (2001) Langmuir, 17, pp. 6759-6761; 
Firestone, M.A., Rickert, P.G., Seifert, S., Dietz, M.L., (2004) Inorg. Chim. Acta, 357, pp. 3991-3996; 
Dupont, J., Fonseca, G.S., Umpierre, A.P., Fichtner, P.F.P., Telxelra, S.R., (2002) J. Am. Chem. Soc., 124, pp. 4228-4229; 
Huang, J., Jiang, T., Han, B., Gao, H., Chang, Y., Zhao, G., Wu, W., (2003) Chem. Commun., pp. 1654-1655; 
Fonseca, G.S., Umpierre, A.P., Fichtner, P.F.P., Teixeira, S.R., Dupont, J., (2003) Chem. Eur. J., 9, pp. 3263-3269; 
Scheeren, C.W., Machado, G., Dupont, J., Fichtner, P.F.P., Texelra, S.R., (2003) Inorg. Chem., 42, pp. 4738-4742; 
Anderson, K., Fernandez, S.C., Hardacre, C., Marr, P.C., (2004) Inorg. Chem. Commun., 7, pp. 73-76; 
Zhu, Y.J., Wang, W.W., Qi, R.J., Hu, X.L., (2004) Angew. Chem., 236, pp. 1434-1438; 
(2004) Angew. Chem. Int. Ed., 43, pp. 1410-1414; 
Dupont, J., (2004) J. Braz. Chem. Soc., 15, pp. 341-350; 
Pastoriza-Santos, I., Liz-Marzan, L.M., (2002) Langmuir, 18, pp. 2888-2897; 
Melosh, N.A., Davidson, P., Chmelka, B.F., (2000) J. Am. Chem. Soc., 122, pp. 823-829; 
Hamley, I.W., Gehlsen, M.D., Khandpur, A.K., Koppi, K.A., Rosedale, J.H., Schulz, M.F., Bates, F.S., Mortensen, K., (1994) J. Phys. II Fr., 4, pp. 2161-2186; 
Wang, C.Y., Lodge, T.P., (2002) Macromolecules, 35, pp. 6997-7006; 
Bronstein, L.M., Svergun, D.I., Khokhlov, A.R., (2002) Polymer Gels and Networks, pp. 103-130. , Marcel Dekker, New York; 
Malinsky, M.D., Kelly, K.L., Schatz, G.C., Van Duyne, R.P., (2001) J. Phys. Chem. B, 105, pp. 2343-2350; 
Sun, Y.G., Xia, Y.N., (2003) Analyst, 128, pp. 686-691; 
Norman, T.J., Grant, C.D., Magana, D., Zhang, J.Z., Liu, J., Cao, D.L., Bridges, F., Van Buuren, A., (2002) J. Phys. Chem. B, 106, pp. 7005-7012; 
Yu, Y.Y., Chang, S.S., Lee, C.L., Wang, C.R.C., (1997) J. Phys. Chem. B, 101, pp. 6661-6664; 
Sau, T.K., Murphy, C.J., (2004) J. Am. Chem. Soc., 126, pp. 8648-8649; 
Malikova, N., Pastoriza-Santos, I., Schierhorn, M., Kotov, N.A., Liz-Marzan, L.M., (2002) Langmuir, 18, pp. 3694-3697; 
Varnavski, O.P., Mohamed, M.B., El-Sayed, M.A., Goodson, T., (2003) J. Phys. Chem. B, 107, pp. 3101-3104; 
Kim, F., Song, J.H., Yang, P.D., (2002) J. Am. Chem. Soc., 124, pp. 14316-14317; 
Kim, F., Connor, S., Song, H., Kuykendall, T., Yang, P.D., (2004) Angew. Chem., 116, pp. 3759-3763; 
(2004) Angew. Chem. Int. Ed., 43, pp. 3673-3677; 
Li, C., Cai, W., Kan, C., Fu, G., Zhang, L., (2003) Mater. Lett., 58, pp. 196-199; 
Jin, R.C., Cao, Y.W., Mirkin, C.A., Kelly, K.L., Schatz, G.C., Zheng, J.G., (2001) Science, 294, pp. 1901-1903; 
Murphy, C.J., Jana, N.R., (2002) Adv. Mater., 14, pp. 80-82; 
Pileni, M.P., (2003) Nat Mater., 2, pp. 145-150; 
Wang, Z.L., Gao, R.P., Nikoobakht, B., El-Sayed, M.A., (2000) J. Phys. Chem. B, 104, pp. 5417-5420; 
Weiner, S., Addadi, L., (1997) J. Mater. Chem., 7, pp. 689-702},
author = {Firestone, M A and Dietz, M L and Seifen, S and Trasobares, S and Miller, D J and Zaluzec, N J},
issn = {16136810 (ISSN)},
journal = {Small},
keywords = { Electron, Radiation, Scanning,1-decyl-3- methylimidazolium chloride,Catalysts,Gels,Ionic Liquids,Ionogels,Metal Nanoparticles,Microscopy,Nanoparticles,Nanostructured materials,Nanostructures,Nanotubes,Photochemical reactions,Photoreduction,Reduction,Scattering,Surface Properties,Synthesis (chemical),Template synthesis,Ultraviolet Rays,X ray,X ray scattering,X-Rays,anisotropy,article,chemistry,gel,gold,hydrogel,instrumentation,ionic liquid,metal nanoparticle,methodology,nanomaterial,nanoparticle,nanotechnology,nanotube,radiation scattering,scanning electron microscopy,surface property,ultraviolet radiation},
number = {7},
pages = {754--760},
title = {{Ionogel-templated synthesis and organization of anisotropic gold nanoparticles}},
url = {https://www.scopus.com/inward/record.url?eid=2-s2.0-33745462407&partnerID=40&md5=993148982798354fa1301d464437cbf7},
volume = {1},
year = {2005}
}

{"_id":"Dn88NrSWHTfrhnjkh","bibbaseid":"firestone-dietz-seifen-trasobares-miller-zaluzec-ionogeltemplatedsynthesisandorganizationofanisotropicgoldnanoparticles-2005","downloads":0,"creationDate":"2015-12-07T10:38:41.914Z","title":"Ionogel-templated synthesis and organization of anisotropic gold nanoparticles","author_short":["Firestone, M A","Dietz, M L","Seifen, S","Trasobares, S","Miller, D J","Zaluzec, N J"],"year":2005,"bibtype":"article","biburl":"www2.uca.es/dept/cmat_qinor/nanomat/people/Trasobares.bib","bibdata":{"bibtype":"article","type":"article","abstract":"Photochemical reduction of tetrachloroaurate (AuCl 4 -) ions in the highly constrained aqueous domains of a nanostructured ionogel template, formed via self-assembly of the ionic liquid 1-decyl-3- methylimidazolium chloride (C 10mim +Cl) in water, results in the formation of anisotropic gold nanoparticles with a variety of sizes and morphologies, which include previously unattainable trigonal prismatic nanorods. Unexpectedly, small-angle X-ray scattering studies of the Au-ionogel composite reveal that the in situ formation of the nanoparticles increases the mesoscopic order of the ionogel, which results in its conversion to a near-monodomain structure. The findings demonstrate that nanostructured, ionic liquid-based gels can be used to template the formation of new nanoparticle morphologies with technologically important optical, electronic, and catalytic properties. It may also be possible to design soft templates that permit the fabrication of highly ordered nanoparticle array-liydrogel composites, thereby enabling control and tuning of the collective properties of the encapsulated nanoparticles. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA,.","address":"Materials Science Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439, United States","annote":"Cited By (since 1996): 53 Export Date: 15 January 2013 Source: Scopus doi: 10.1002/smll.200500030 Language of Original Document: English Correspondence Address: Firestone, M.A.; Materials Science Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439, United States; email: firestone@anl.gov Chemicals/CAS: gold, 7440-57-5; Gels; Gold, 7440-57-5; Hydrogel, 25852-47-5; Ionic Liquids References: Katz, E., Shipway, A., Willner, I., (2003) Nanoscale Materials, pp. 5-64. , Eds.: L. M, Liz-Marzan, P.V. Kamat, Kluwer, London; Crooks, R.M., Chechik, V., (2000) J. Am. Chem. Soc., 122, pp. 1243-1244; Dirix, Y., Bastiaansen, C., Caseri, W., Smith, P., (1999) Adv. Mater., 11, pp. 223-227; Barnes, W.L., Dereux, A., Ebbesen, T.W., (2003) Nature, 424, pp. 824-830; Maier, S.A., Kik, P.G., Atwater, H.A., Meltzer, S., Marel, E., Koel, B.E., Requlcha, A.A.G., (2003) Nat. Mater., 2, pp. 229-232; Haes, A.J., Van Duyne, R.P., (2002) J. Am. Chem. Soc., 124, pp. 10596-10604; Cao, Y.W.C., Jin, R.C., Mirkin, C.A., (2002) Science, 297, pp. 1536-1540; Jensen, T.R., Duval, M.L., Kelly, K.L., Lazarides, A.A., Schatz, C.C., Van Duyne, R.P., (1999) J. Phys. Chem. B, 103, pp. 9846-9853; Haynes, C.L., McFarland, A.D., Zhao, L.L., Van Duyne, R.P., Schatz, C.C., Gunnarsson, L., Prikulls, J., Kall, M., (2003) J. Phys. Chem. B, 107, pp. 7337-7342; Mohamed, M.B., Volkov, V., Link, S., El-Sayed, M.A., (2000) Chem. Phys. Lett., 317, pp. 517-523; Schider, G., Krenn, J.R., Gotschy, W., Lamprecht, B., Ditlbacher, H., Leitner, A., Aussenegg, F.R., (2001) J. Appl. Phys., 90, pp. 3825-3830; Valden, M., Lai, X., Goodman, D.W., (1998) Science, 282, pp. 1647-1650; Gittins, D.I., Bethell, D., Schiffrin, D.J., Nichols, R.J., (2000) Nature, 408, pp. 67-69; Appell, D., (2002) Nature, 419, pp. 553-555; Martin, C.R., (1996) Chem. Mater., 8, pp. 1739-1746; Van Der Zande, B.M.I., Bohmer, M.R., Fokkink, L.G.J., Schonenberger, C., (2000) Langmuir, 16, pp. 451-458; Schonenberger, C., Van Der Zande, B.M.I., Fokkink, L.G.J., Henny, M., Schmid, C., Kruger, M., Bachtold, A., Staufer, U., (1997) J. Phys. Chem. B, 101, pp. 5497-5499; Martin, C.R., Nishizawa, M., Jirage, K., Kang, M., (2001) J. Phys. Chem. B, 105, pp. 1925-1934; Crowley, T.A., Ziegler, K.J., Lyons, D.M., Erts, D., Olin, H., Morris, M.A., Holmes, J.D., (2003) Chem. Mater., 15, pp. 3518-3522; Mandal, M., Ghosh, S.K., Kundu, S., Esumi, K., Pal, T., (2002) Langmuir, 18, pp. 7792-7797; Huang, L.M., Wang, H.T., Wang, Z.B., Mitra, A.P., Zhao, D., Yan, Y.H., (2002) Chem. Mater., 14, pp. 876-880; Faure, C., Derre, A., Neri, W., (2003) J. Phys. Chem. B, 107, pp. 4738-4746; Gao, J.X., Bender, C.M., Murphy, C.J., (2003) Langmuir, 19, pp. 9065-9070; Firestone, M.A., Tiede, D.M., Seifert, S., (2000) J. Phys. Chem. B, 204, pp. 2433-2438; Andersson, M., Alfredsson, V., Kjellin, P., Palmqvist, A.E.C., (2002) Nano Lett., 2, pp. 1403-1407; Holbrey, J.D., Seddon, K.R., (1999) Clean Products Processes, 1, pp. 223-236; Earle, M.J., Seddon, K.R., (2000) Pure Appl. Chem., 72, pp. 1391-1398; Wasserscheid, P., Welton, T., (2003) Ionic Liquids in Synthesis, , Wiley-VCH, Weinheim; Firestone, M.A., Dzielawa, J.A., Zapol, P., Curtiss, L.A., Seifert, S., Dietz, M.L., (2002) Langmuir, 18, pp. 7258-7260; Dietz, M.L., Dzielawa, J.A., Jensen, M.P., Firestone, M.A., (2003) Ionic Liquids as Green Solvents: Progress and Prospects, 856, pp. 526-543. , Eds.: R. D. Rogers, K. R. Seddon, American Chemical Society, Washington, DC; Zhou, Y., Schattaka, J.H., Antoniette, M., (2004) Nano Lett., 4, pp. 477-481; Kimizuka, N., Nakashima, T., (2001) Langmuir, 17, pp. 6759-6761; Firestone, M.A., Rickert, P.G., Seifert, S., Dietz, M.L., (2004) Inorg. Chim. Acta, 357, pp. 3991-3996; Dupont, J., Fonseca, G.S., Umpierre, A.P., Fichtner, P.F.P., Telxelra, S.R., (2002) J. Am. Chem. Soc., 124, pp. 4228-4229; Huang, J., Jiang, T., Han, B., Gao, H., Chang, Y., Zhao, G., Wu, W., (2003) Chem. Commun., pp. 1654-1655; Fonseca, G.S., Umpierre, A.P., Fichtner, P.F.P., Teixeira, S.R., Dupont, J., (2003) Chem. Eur. J., 9, pp. 3263-3269; Scheeren, C.W., Machado, G., Dupont, J., Fichtner, P.F.P., Texelra, S.R., (2003) Inorg. Chem., 42, pp. 4738-4742; Anderson, K., Fernandez, S.C., Hardacre, C., Marr, P.C., (2004) Inorg. Chem. Commun., 7, pp. 73-76; Zhu, Y.J., Wang, W.W., Qi, R.J., Hu, X.L., (2004) Angew. Chem., 236, pp. 1434-1438; (2004) Angew. Chem. Int. Ed., 43, pp. 1410-1414; Dupont, J., (2004) J. Braz. Chem. Soc., 15, pp. 341-350; Pastoriza-Santos, I., Liz-Marzan, L.M., (2002) Langmuir, 18, pp. 2888-2897; Melosh, N.A., Davidson, P., Chmelka, B.F., (2000) J. Am. Chem. Soc., 122, pp. 823-829; Hamley, I.W., Gehlsen, M.D., Khandpur, A.K., Koppi, K.A., Rosedale, J.H., Schulz, M.F., Bates, F.S., Mortensen, K., (1994) J. Phys. II Fr., 4, pp. 2161-2186; Wang, C.Y., Lodge, T.P., (2002) Macromolecules, 35, pp. 6997-7006; Bronstein, L.M., Svergun, D.I., Khokhlov, A.R., (2002) Polymer Gels and Networks, pp. 103-130. , Marcel Dekker, New York; Malinsky, M.D., Kelly, K.L., Schatz, G.C., Van Duyne, R.P., (2001) J. Phys. Chem. B, 105, pp. 2343-2350; Sun, Y.G., Xia, Y.N., (2003) Analyst, 128, pp. 686-691; Norman, T.J., Grant, C.D., Magana, D., Zhang, J.Z., Liu, J., Cao, D.L., Bridges, F., Van Buuren, A., (2002) J. Phys. Chem. B, 106, pp. 7005-7012; Yu, Y.Y., Chang, S.S., Lee, C.L., Wang, C.R.C., (1997) J. Phys. Chem. B, 101, pp. 6661-6664; Sau, T.K., Murphy, C.J., (2004) J. Am. Chem. Soc., 126, pp. 8648-8649; Malikova, N., Pastoriza-Santos, I., Schierhorn, M., Kotov, N.A., Liz-Marzan, L.M., (2002) Langmuir, 18, pp. 3694-3697; Varnavski, O.P., Mohamed, M.B., El-Sayed, M.A., Goodson, T., (2003) J. Phys. Chem. B, 107, pp. 3101-3104; Kim, F., Song, J.H., Yang, P.D., (2002) J. Am. Chem. Soc., 124, pp. 14316-14317; Kim, F., Connor, S., Song, H., Kuykendall, T., Yang, P.D., (2004) Angew. Chem., 116, pp. 3759-3763; (2004) Angew. Chem. Int. Ed., 43, pp. 3673-3677; Li, C., Cai, W., Kan, C., Fu, G., Zhang, L., (2003) Mater. Lett., 58, pp. 196-199; Jin, R.C., Cao, Y.W., Mirkin, C.A., Kelly, K.L., Schatz, G.C., Zheng, J.G., (2001) Science, 294, pp. 1901-1903; Murphy, C.J., Jana, N.R., (2002) Adv. Mater., 14, pp. 80-82; Pileni, M.P., (2003) Nat Mater., 2, pp. 145-150; Wang, Z.L., Gao, R.P., Nikoobakht, B., El-Sayed, M.A., (2000) J. Phys. Chem. B, 104, pp. 5417-5420; Weiner, S., Addadi, L., (1997) J. Mater. Chem., 7, pp. 689-702","author":[{"propositions":[],"lastnames":["Firestone"],"firstnames":["M","A"],"suffixes":[]},{"propositions":[],"lastnames":["Dietz"],"firstnames":["M","L"],"suffixes":[]},{"propositions":[],"lastnames":["Seifen"],"firstnames":["S"],"suffixes":[]},{"propositions":[],"lastnames":["Trasobares"],"firstnames":["S"],"suffixes":[]},{"propositions":[],"lastnames":["Miller"],"firstnames":["D","J"],"suffixes":[]},{"propositions":[],"lastnames":["Zaluzec"],"firstnames":["N","J"],"suffixes":[]}],"issn":"16136810 (ISSN)","journal":"Small","keywords":"Electron, Radiation, Scanning,1-decyl-3- methylimidazolium chloride,Catalysts,Gels,Ionic Liquids,Ionogels,Metal Nanoparticles,Microscopy,Nanoparticles,Nanostructured materials,Nanostructures,Nanotubes,Photochemical reactions,Photoreduction,Reduction,Scattering,Surface Properties,Synthesis (chemical),Template synthesis,Ultraviolet Rays,X ray,X ray scattering,X-Rays,anisotropy,article,chemistry,gel,gold,hydrogel,instrumentation,ionic liquid,metal nanoparticle,methodology,nanomaterial,nanoparticle,nanotechnology,nanotube,radiation scattering,scanning electron microscopy,surface property,ultraviolet radiation","number":"7","pages":"754–760","title":"Ionogel-templated synthesis and organization of anisotropic gold nanoparticles","url":"https://www.scopus.com/inward/record.url?eid=2-s2.0-33745462407&partnerID=40&md5=993148982798354fa1301d464437cbf7","volume":"1","year":"2005","bibtex":"@article{Firestone2005,\nabstract = {Photochemical reduction of tetrachloroaurate (AuCl 4 -) ions in the highly constrained aqueous domains of a nanostructured ionogel template, formed via self-assembly of the ionic liquid 1-decyl-3- methylimidazolium chloride (C 10mim +Cl) in water, results in the formation of anisotropic gold nanoparticles with a variety of sizes and morphologies, which include previously unattainable trigonal prismatic nanorods. Unexpectedly, small-angle X-ray scattering studies of the Au-ionogel composite reveal that the in situ formation of the nanoparticles increases the mesoscopic order of the ionogel, which results in its conversion to a near-monodomain structure. The findings demonstrate that nanostructured, ionic liquid-based gels can be used to template the formation of new nanoparticle morphologies with technologically important optical, electronic, and catalytic properties. It may also be possible to design soft templates that permit the fabrication of highly ordered nanoparticle array-liydrogel composites, thereby enabling control and tuning of the collective properties of the encapsulated nanoparticles. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA,.},\naddress = {Materials Science Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439, United States},\nannote = {Cited By (since 1996): 53\n\n \nExport Date: 15 January 2013\n\n \nSource: Scopus\n\n \ndoi: 10.1002/smll.200500030\n\n \nLanguage of Original Document: English\n\n \nCorrespondence Address: Firestone, M.A.; Materials Science Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439, United States; email: firestone@anl.gov\n\n \nChemicals/CAS: gold, 7440-57-5; Gels; Gold, 7440-57-5; Hydrogel, 25852-47-5; Ionic Liquids\n\n \nReferences: Katz, E., Shipway, A., Willner, I., (2003) Nanoscale Materials, pp. 5-64. , Eds.: L. M, Liz-Marzan, P.V. Kamat, Kluwer, London; \nCrooks, R.M., Chechik, V., (2000) J. Am. Chem. Soc., 122, pp. 1243-1244; \nDirix, Y., Bastiaansen, C., Caseri, W., Smith, P., (1999) Adv. 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Chem., 7, pp. 689-702},\nauthor = {Firestone, M A and Dietz, M L and Seifen, S and Trasobares, S and Miller, D J and Zaluzec, N J},\nissn = {16136810 (ISSN)},\njournal = {Small},\nkeywords = { Electron, Radiation, Scanning,1-decyl-3- methylimidazolium chloride,Catalysts,Gels,Ionic Liquids,Ionogels,Metal Nanoparticles,Microscopy,Nanoparticles,Nanostructured materials,Nanostructures,Nanotubes,Photochemical reactions,Photoreduction,Reduction,Scattering,Surface Properties,Synthesis (chemical),Template synthesis,Ultraviolet Rays,X ray,X ray scattering,X-Rays,anisotropy,article,chemistry,gel,gold,hydrogel,instrumentation,ionic liquid,metal nanoparticle,methodology,nanomaterial,nanoparticle,nanotechnology,nanotube,radiation scattering,scanning electron microscopy,surface property,ultraviolet radiation},\nnumber = {7},\npages = {754--760},\ntitle = {{Ionogel-templated synthesis and organization of anisotropic gold nanoparticles}},\nurl = {https://www.scopus.com/inward/record.url?eid=2-s2.0-33745462407&partnerID=40&md5=993148982798354fa1301d464437cbf7},\nvolume = {1},\nyear = {2005}\n}\n","author_short":["Firestone, M A","Dietz, M L","Seifen, S","Trasobares, S","Miller, D J","Zaluzec, N J"],"key":"Firestone2005","id":"Firestone2005","bibbaseid":"firestone-dietz-seifen-trasobares-miller-zaluzec-ionogeltemplatedsynthesisandorganizationofanisotropicgoldnanoparticles-2005","role":"author","urls":{"Paper":"https://www.scopus.com/inward/record.url?eid=2-s2.0-33745462407&partnerID=40&md5=993148982798354fa1301d464437cbf7"},"keyword":["Electron","Radiation","Scanning","1-decyl-3- methylimidazolium chloride","Catalysts","Gels","Ionic Liquids","Ionogels","Metal Nanoparticles","Microscopy","Nanoparticles","Nanostructured materials","Nanostructures","Nanotubes","Photochemical reactions","Photoreduction","Reduction","Scattering","Surface Properties","Synthesis (chemical)","Template synthesis","Ultraviolet Rays","X ray","X ray scattering","X-Rays","anisotropy","article","chemistry","gel","gold","hydrogel","instrumentation","ionic liquid","metal nanoparticle","methodology","nanomaterial","nanoparticle","nanotechnology","nanotube","radiation scattering","scanning electron microscopy","surface property","ultraviolet radiation"],"downloads":0,"html":"","metadata":{"authorlinks":{}}},"search_terms":["ionogel","templated","synthesis","organization","anisotropic","gold","nanoparticles","firestone","dietz","seifen","trasobares","miller","zaluzec"],"keywords":["electron","radiation","scanning","1-decyl-3- methylimidazolium chloride","catalysts","gels","ionic liquids","ionogels","metal nanoparticles","microscopy","nanoparticles","nanostructured materials","nanostructures","nanotubes","photochemical reactions","photoreduction","reduction","scattering","surface properties","synthesis (chemical)","template synthesis","ultraviolet rays","x ray","x ray scattering","x-rays","anisotropy","article","chemistry","gel","gold","hydrogel","instrumentation","ionic liquid","metal nanoparticle","methodology","nanomaterial","nanoparticle","nanotechnology","nanotube","radiation scattering","scanning electron microscopy","surface property","ultraviolet radiation"],"authorIDs":[],"dataSources":["Re6vfFqp6mCGKxW5p","BraPrFTJMD8Pu6SQ6"]}