@article{
 title = {Secondary Organic Aerosol Formation and Organic Nitrate Yield from NO3 Oxidation of Biogenic Hydrocarbons},
 type = {article},
 year = {2014},
 keywords = {alpha-pinene,emissions,gas,isoprene,model,monoterpenes,particle formation,product,radicals,soa formation},
 pages = {11944-11953},
 volume = {48},
 id = {461c4914-fd40-3571-89f8-adb5169a6166},
 created = {2023-01-31T22:46:07.292Z},
 file_attached = {false},
 profile_id = {2e2b0bf1-6573-3fd8-8628-55d1dc39fe31},
 last_modified = {2023-01-31T22:46:07.292Z},
 read = {false},
 starred = {false},
 authored = {true},
 confirmed = {true},
 hidden = {false},
 citation_key = {Fry2014a},
 source_type = {Journal Article},
 language = {English},
 notes = {<b>From Duplicate 1 (<i>Secondary organic aerosol formation and organic nitrate yield from NO3 oxidation of biogenic hydrocarbons</i> - Fry, Juliane L.; Draper, Danielle C.; Barsanti, Kelley C.; Smith, James N.; Ortega, John; Winkler, Paul M.; Lawler, Michael J.; Brown, Steven S.; Edwards, Peter M.; Cohen, Ronald C.; Lee, Lance)<br/></b><br/>ISI Document Delivery No.: AR5RJ<br/>Times Cited: 7<br/>Cited Reference Count: 41<br/>Fry, Juliane L. Draper, Danielle C. Barsanti, Kelley C. Smith, James N. Ortega, John Winkle, Paul M. Lawler, Michael J. Brown, Steven S. Edwards, Peter M. Cohen, Ronald C. Lee, Lance<br/>NOAA Climate Program Office's AC4 program [NA13OAR4310070]; Finnish Academy [251007]; U.S. Department of Energy [DE-SC0006861]; Austrian Science Fund (FWF) [J3198-N21]; National Science Foundation<br/>J.L.F. gratefully acknowledges sabbatical support from the Cooperative Institute for Research in Environmental Science (CIRES) and the National Center for Atmospheric Research Visiting Scholars Program, and J.L.F. and S.S.B. acknowledge funding from the NOAA Climate Program Office's AC4 program (Grant No. NA13OAR4310070). We thank Serena Chung, Peter McMurry, Paul Ziemann, and John Orlando for helpful discussions. J.N.S. acknowledges funding from the Finnish Academy (Grant No. 251007) and U.S. Department of Energy (Grant No. DE-SC0006861). P.M.W. acknowledges financial support from the Austrian Science Fund (FWF, Project No. J3198-N21). The National Center for Atmospheric Research is sponsored by the National Science Foundation.<br/>Amer chemical soc<br/>Washington<br/><br/><b>From Duplicate 2 (<i>Secondary Organic Aerosol Formation and Organic Nitrate Yield from NO3 Oxidation of Biogenic Hydrocarbons</i> - Fry, Juliane L; Draper, Danielle C; Barsanti, Kelley C; Smith, James N; Ortega, John; Winkle, Paul M; Lawler, Michael J; Brown, Steven S; Edwards, Peter M; Cohen, Ronald C; Lee, Lance)<br/></b><br/>Times Cited: 0},
 private_publication = {false},
 abstract = {The secondary organic aerosol (SOA) mass yields from NO3 oxidation of a series of biogenic volatile organic compounds (BVOCs), consisting of five monoterpenes and one sesquiterpene (α-pinene, β-pinene, Δ-3-carene, limonene, sabinene, and β-caryophyllene), were investigated in a series of continuous flow experiments in a 10 m3 indoor Teflon chamber. By making in situ measurements of the nitrate radical and employing a kinetics box model, we generate time-dependent yield curves as a function of reacted BVOC. SOA yields varied dramatically among the different BVOCs, from zero for α-pinene to 38-65% for Δ-3-carene and 86% for β-caryophyllene at mass loading of 10 μg m-3, suggesting that model mechanisms that treat all NO3 + monoterpene reactions equally will lead to errors in predicted SOA depending on each location's mix of BVOC emissions. In most cases, organonitrate is a dominant component of the aerosol produced, but in the case of α-pinene, little organonitrate and no aerosol is formed.},
 bibtype = {article},
 author = {Fry, Juliane L. and Draper, Danielle C. and Barsanti, Kelley C. and Smith, James N. and Ortega, John and Winkle, Paul M and Lawler, Michael J. and Brown, Steven S. and Edwards, Peter M. and Cohen, Ronald C. and Lee, Lance and Winkler, Paul M. and Lawler, Michael J. and Brown, Steven S. and Edwards, Peter M. and Cohen, Ronald C. and Lee, Lance},
 doi = {10.1021/es502204x},
 journal = {Environmental Science and Technology},
 number = {20}
}

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Draper, Danielle C. Barsanti, Kelley C. Smith, James N. Ortega, John Winkle, Paul M. Lawler, Michael J. Brown, Steven S. Edwards, Peter M. Cohen, Ronald C. Lee, Lance<br/>NOAA Climate Program Office's AC4 program [NA13OAR4310070]; Finnish Academy [251007]; U.S. Department of Energy [DE-SC0006861]; Austrian Science Fund (FWF) [J3198-N21]; National Science Foundation<br/>J.L.F. gratefully acknowledges sabbatical support from the Cooperative Institute for Research in Environmental Science (CIRES) and the National Center for Atmospheric Research Visiting Scholars Program, and J.L.F. and S.S.B. acknowledge funding from the NOAA Climate Program Office's AC4 program (Grant No. NA13OAR4310070). We thank Serena Chung, Peter McMurry, Paul Ziemann, and John Orlando for helpful discussions. J.N.S. acknowledges funding from the Finnish Academy (Grant No. 251007) and U.S. Department of Energy (Grant No. DE-SC0006861). P.M.W. acknowledges financial support from the Austrian Science Fund (FWF, Project No. J3198-N21). The National Center for Atmospheric Research is sponsored by the National Science Foundation.<br/>Amer chemical soc<br/>Washington<br/><br/><b>From Duplicate 2 (<i>Secondary Organic Aerosol Formation and Organic Nitrate Yield from NO3 Oxidation of Biogenic Hydrocarbons</i> - Fry, Juliane L; Draper, Danielle C; Barsanti, Kelley C; Smith, James N; Ortega, John; Winkle, Paul M; Lawler, Michael J; Brown, Steven S; Edwards, Peter M; Cohen, Ronald C; Lee, Lance)<br/></b><br/>Times Cited: 0","private_publication":false,"abstract":"The secondary organic aerosol (SOA) mass yields from NO3 oxidation of a series of biogenic volatile organic compounds (BVOCs), consisting of five monoterpenes and one sesquiterpene (α-pinene, β-pinene, Δ-3-carene, limonene, sabinene, and β-caryophyllene), were investigated in a series of continuous flow experiments in a 10 m3 indoor Teflon chamber. By making in situ measurements of the nitrate radical and employing a kinetics box model, we generate time-dependent yield curves as a function of reacted BVOC. SOA yields varied dramatically among the different BVOCs, from zero for α-pinene to 38-65% for Δ-3-carene and 86% for β-caryophyllene at mass loading of 10 μg m-3, suggesting that model mechanisms that treat all NO3 + monoterpene reactions equally will lead to errors in predicted SOA depending on each location's mix of BVOC emissions. In most cases, organonitrate is a dominant component of the aerosol produced, but in the case of α-pinene, little organonitrate and no aerosol is formed.","bibtype":"article","author":"Fry, Juliane L. and Draper, Danielle C. and Barsanti, Kelley C. and Smith, James N. and Ortega, John and Winkle, Paul M and Lawler, Michael J. and Brown, Steven S. and Edwards, Peter M. and Cohen, Ronald C. and Lee, Lance and Winkler, Paul M. and Lawler, Michael J. and Brown, Steven S. and Edwards, Peter M. and Cohen, Ronald C. and Lee, Lance","doi":"10.1021/es502204x","journal":"Environmental Science and Technology","number":"20","bibtex":"@article{\n title = {Secondary Organic Aerosol Formation and Organic Nitrate Yield from NO3 Oxidation of Biogenic Hydrocarbons},\n type = {article},\n year = {2014},\n keywords = {alpha-pinene,emissions,gas,isoprene,model,monoterpenes,particle formation,product,radicals,soa formation},\n pages = {11944-11953},\n volume = {48},\n id = {461c4914-fd40-3571-89f8-adb5169a6166},\n created = {2023-01-31T22:46:07.292Z},\n file_attached = {false},\n profile_id = {2e2b0bf1-6573-3fd8-8628-55d1dc39fe31},\n last_modified = {2023-01-31T22:46:07.292Z},\n read = {false},\n starred = {false},\n authored = {true},\n confirmed = {true},\n hidden = {false},\n citation_key = {Fry2014a},\n source_type = {Journal Article},\n language = {English},\n notes = {<b>From Duplicate 1 (<i>Secondary organic aerosol formation and organic nitrate yield from NO3 oxidation of biogenic hydrocarbons</i> - Fry, Juliane L.; Draper, Danielle C.; Barsanti, Kelley C.; Smith, James N.; Ortega, John; Winkler, Paul M.; Lawler, Michael J.; Brown, Steven S.; Edwards, Peter M.; Cohen, Ronald C.; Lee, Lance)<br/></b><br/>ISI Document Delivery No.: AR5RJ<br/>Times Cited: 7<br/>Cited Reference Count: 41<br/>Fry, Juliane L. 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P.M.W. acknowledges financial support from the Austrian Science Fund (FWF, Project No. J3198-N21). The National Center for Atmospheric Research is sponsored by the National Science Foundation.<br/>Amer chemical soc<br/>Washington<br/><br/><b>From Duplicate 2 (<i>Secondary Organic Aerosol Formation and Organic Nitrate Yield from NO3 Oxidation of Biogenic Hydrocarbons</i> - Fry, Juliane L; Draper, Danielle C; Barsanti, Kelley C; Smith, James N; Ortega, John; Winkle, Paul M; Lawler, Michael J; Brown, Steven S; Edwards, Peter M; Cohen, Ronald C; Lee, Lance)<br/></b><br/>Times Cited: 0},\n private_publication = {false},\n abstract = {The secondary organic aerosol (SOA) mass yields from NO3 oxidation of a series of biogenic volatile organic compounds (BVOCs), consisting of five monoterpenes and one sesquiterpene (α-pinene, β-pinene, Δ-3-carene, limonene, sabinene, and β-caryophyllene), were investigated in a series of continuous flow experiments in a 10 m3 indoor Teflon chamber. By making in situ measurements of the nitrate radical and employing a kinetics box model, we generate time-dependent yield curves as a function of reacted BVOC. SOA yields varied dramatically among the different BVOCs, from zero for α-pinene to 38-65% for Δ-3-carene and 86% for β-caryophyllene at mass loading of 10 μg m-3, suggesting that model mechanisms that treat all NO3 + monoterpene reactions equally will lead to errors in predicted SOA depending on each location's mix of BVOC emissions. 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