Vapor pressure of three brominated flame retardants determined by using the Knudsen effusion method. Fu, J. & Suuberg, E. M Environmental toxicology and chemistry / SETAC, 31(3):574–578, March, 2012. Paper doi abstract bibtex Brominated flame retardants (BFRs) have been used in a variety of consumer products in the past four decades. The vapor pressures for three widely used BFRs, that is, tetrabromobisphenol A (TBBPA), hexabromocyclododecane (HBCD), and octabromodiphenyl ethers (octaBDEs) mixtures, were determined using the Knudsen effusion method and compared with those of decabromodiphenyl ether (BDE209). The values measured extrapolated to 298.15 K are 8.47 × 10⁻⁹, 7.47 × 10⁻¹⁰, and 2.33 × 10⁻⁹ Pa, respectively. The enthalpies of sublimation for these BFRs were estimated using the Clausius-Clapeyron equation and are 143.6 ± 0.4, 153.7 ± 3.1, and 150.8 ± 3.2 kJ/mole, respectively. In addition, the enthalpies of fusion and melting temperatures for these BFRs were also measured in the present study.
@article{fu_vapor_2012,
title = {Vapor pressure of three brominated flame retardants determined by using the {Knudsen} effusion method.},
volume = {31},
url = {http://www.ncbi.nlm.nih.gov/pubmed/22213441 file:///Users/veena/Desktop/Veena/Green Science Policy Institute/Mendeley papers/Fu 2012.pdf},
doi = {10.1002/etc.1736},
abstract = {Brominated flame retardants (BFRs) have been used in a variety of consumer products in the past four decades. The vapor pressures for three widely used BFRs, that is, tetrabromobisphenol A (TBBPA), hexabromocyclododecane (HBCD), and octabromodiphenyl ethers (octaBDEs) mixtures, were determined using the Knudsen effusion method and compared with those of decabromodiphenyl ether (BDE209). The values measured extrapolated to 298.15 K are 8.47 × 10⁻⁹, 7.47 × 10⁻¹⁰, and 2.33 × 10⁻⁹ Pa, respectively. The enthalpies of sublimation for these BFRs were estimated using the Clausius-Clapeyron equation and are 143.6 ± 0.4, 153.7 ± 3.1, and 150.8 ± 3.2 kJ/mole, respectively. In addition, the enthalpies of fusion and melting temperatures for these BFRs were also measured in the present study.},
number = {3},
journal = {Environmental toxicology and chemistry / SETAC},
author = {Fu, Jinxia and Suuberg, Eric M},
month = mar,
year = {2012},
keywords = {Brominated, Brominated: analysis, Brominated: chemistry, Flame Retardants: analysis, Flame retardants, Humans, Hydrocarbons, Polybrominated Biphenyls, Polybrominated Biphenyls: analysis, Polybrominated Biphenyls: chemistry, Thermodynamics, Vapor Pressure},
pages = {574--578},
}
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