Rhodium Dispersion in a Rh/Ce0.68Zr0.32O2 Catalyst Investigated by HRTEM and H2 Chemisorption. Gatica J.M.a Baker & c&nbsp;Fornasiero P.a Bernal S.b Blanco G.b Kašpar<nbsp>J.a, R‥ Journal of Physical Chemistry B, 104(19):4667--4672, 2000.
Rhodium Dispersion in a Rh/Ce0.68Zr0.32O2 Catalyst Investigated by HRTEM and H2 Chemisorption [link]Paper  abstract   bibtex   
The effect of reduction temperature on the hydrogen adsorption and Rh dispersion in a Rh/Ce0.68Zr0.32O2 catalyst with texturally stable Ce0.68Zr0.32O2 support was investigated. Rh dispersion data were also obtained from Rh particle size analyses made using high-resolution transmission electron microscopy (HRTEM) images. Comparison of the dispersion values obtained by using the two techniques showed that H2 adsorption at -80 °C is a suitable tool for the estimation of Rh dispersion at reduction temperature, Tred, ≤500°C. For Tred > 500°C. a partial suppression of H2 chemisorption was observed. However, after a mild reoxidation and low temperature reduction, the H2 adsorption capacity of these samples was regenerated and good agreement with the HRTEM data was again obtained.
@article{ Gatica20004667,
  abstract = {The effect of reduction temperature on the hydrogen adsorption and Rh dispersion in a Rh/Ce0.68Zr0.32O2 catalyst with texturally stable Ce0.68Zr0.32O2 support was investigated. Rh dispersion data were also obtained from Rh particle size analyses made using high-resolution transmission electron microscopy (HRTEM) images. Comparison of the dispersion values obtained by using the two techniques showed that H2 adsorption at -80 °C is a suitable tool for the estimation of Rh dispersion at reduction temperature, Tred, ≤500°C. For Tred &gt; 500°C. a partial suppression of H2 chemisorption was observed. However, after a mild reoxidation and low temperature reduction, the H2 adsorption capacity of these samples was regenerated and good agreement with the HRTEM data was again obtained.},
  annote = {cited By (since 1996)44},
  author = {{Gatica J.M.a Baker}, R.T.b c Fornasiero P.a Bernal S.b Blanco G.b Kašpar J.a},
  issn = {10895647},
  journal = {Journal of Physical Chemistry B},
  number = {19},
  pages = {4667--4672},
  title = {{Rhodium Dispersion in a Rh/Ce0.68Zr0.32O2 Catalyst Investigated by HRTEM and H2 Chemisorption}},
  url = {http://www.scopus.com/inward/record.url?eid=2-s2.0-0034682405&partnerID=40&md5=1716fe02fff14e2f6192a0fef8dbfcab},
  volume = {104},
  year = {2000}
}

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