A novel CoOx/La-modified-CeO2 formulation for powdered and washcoated onto cordierite honeycomb catalysts with application in VOCs oxidation. Gómez, D., Gatica, J., Hernández-Garrido, J., Cifredo, G., Montes, M., Sanz, O., Rebled, J. d, & Vidal, H. Applied Catalysis B: Environmental, 144:425-434, 2013. cited By 7
Paper doi abstract bibtex A novel Co (15wt.%)/La-modified-CeO2 catalyst was prepared for the oxidation of toluene and ethyl acetate, showing lower light-off temperature (around 20-40°C) than that of a Pt (3wt.%)/La-CeO2 catalyst under the same experimental conditions. Upon washcoating onto cordierite it was still more active than the noble metal reference. The activity remained stable even after 80h of reaction. Adherence tests indicated a 98% stability of the washcoat, while SEM-EDS study evidenced its homogeneous distribution on the cordierite. ICP analysis and X-ray diffraction demonstrated that the composition and cobalt phase (Co3O4) of the powdered catalyst were the same in the washcoat. Moreover textural properties improved according to N2 physisorption studies due to inclusion of colloidal alumina in the slurry. © 2013 Elsevier B.V.
@ARTICLE{Gomez2013425,
author={Gómez, D.M.a and Gatica, J.M.a and Hernández-Garrido, J.C.a and Cifredo, G.A.a and Montes, M.b and Sanz, O.b and Rebled, J.M.c d and Vidal, H.a },
title={A novel CoOx/La-modified-CeO2 formulation for powdered and washcoated onto cordierite honeycomb catalysts with application in VOCs oxidation},
journal={Applied Catalysis B: Environmental},
year={2013},
volume={144},
pages={425-434},
doi={10.1016/j.apcatb.2013.07.045},
note={cited By 7},
url={https://www.scopus.com/inward/record.url?eid=2-s2.0-84882747697&partnerID=40&md5=22fa02e2cbffeea00a9277e440806067},
affiliation={Departamento de Ciencia de Materiales e Ingenieria Metalurgica y Quimica Inorganica, Universidad de Cádiz, 11510 Puerto Real, Spain; Departamento de Química Aplicada, UFI 11/56, Universidad del País Vasco UPV/EHU, Apdo. 1072, 20080 San Sebastian, Spain; LENS-MIND-IN2UB Departament d'Electrònica, Universitat de Barcelona, Barcelona 08028, Spain; Institut de Ciència de Materials de Barcelona-CSIC, Campus UAB 08193, Spain},
abstract={A novel Co (15wt.%)/La-modified-CeO2 catalyst was prepared for the oxidation of toluene and ethyl acetate, showing lower light-off temperature (around 20-40°C) than that of a Pt (3wt.%)/La-CeO2 catalyst under the same experimental conditions. Upon washcoating onto cordierite it was still more active than the noble metal reference. The activity remained stable even after 80h of reaction. Adherence tests indicated a 98% stability of the washcoat, while SEM-EDS study evidenced its homogeneous distribution on the cordierite. ICP analysis and X-ray diffraction demonstrated that the composition and cobalt phase (Co3O4) of the powdered catalyst were the same in the washcoat. Moreover textural properties improved according to N2 physisorption studies due to inclusion of colloidal alumina in the slurry. © 2013 Elsevier B.V.},
author_keywords={Cobalt catalysts; Honeycomb monolith; La-modified-CeO2; VOCs oxidation; Washcoating},
document_type={Article},
source={Scopus},
}
Downloads: 0
{"_id":"W8e3kftHkkd2Yfdz5","bibbaseid":"gmez-gatica-hernndezgarrido-cifredo-montes-sanz-rebled-vidal-anovelcooxlamodifiedceo2formulationforpowderedandwashcoatedontocordieritehoneycombcatalystswithapplicationinvocsoxidation-2013","downloads":0,"creationDate":"2015-09-03T11:56:27.860Z","title":"A novel CoOx/La-modified-CeO2 formulation for powdered and washcoated onto cordierite honeycomb catalysts with application in VOCs oxidation","author_short":["Gómez, D.","Gatica, J.","Hernández-Garrido, J.","Cifredo, G.","Montes, M.","Sanz, O.","Rebled, J. d","Vidal, H."],"year":2013,"bibtype":"article","biburl":"http://www2.uca.es/dept/cmat_qinor/nanomat/people/GROUP.bib","bibdata":{"bibtype":"article","type":"article","author":[{"propositions":[],"lastnames":["Gómez"],"firstnames":["D.M.a"],"suffixes":[]},{"propositions":[],"lastnames":["Gatica"],"firstnames":["J.M.a"],"suffixes":[]},{"propositions":[],"lastnames":["Hernández-Garrido"],"firstnames":["J.C.a"],"suffixes":[]},{"propositions":[],"lastnames":["Cifredo"],"firstnames":["G.A.a"],"suffixes":[]},{"propositions":[],"lastnames":["Montes"],"firstnames":["M.b"],"suffixes":[]},{"propositions":[],"lastnames":["Sanz"],"firstnames":["O.b"],"suffixes":[]},{"propositions":[],"lastnames":["Rebled"],"firstnames":["J.M.c","d"],"suffixes":[]},{"propositions":[],"lastnames":["Vidal"],"firstnames":["H.a"],"suffixes":[]}],"title":"A novel CoOx/La-modified-CeO2 formulation for powdered and washcoated onto cordierite honeycomb catalysts with application in VOCs oxidation","journal":"Applied Catalysis B: Environmental","year":"2013","volume":"144","pages":"425-434","doi":"10.1016/j.apcatb.2013.07.045","note":"cited By 7","url":"https://www.scopus.com/inward/record.url?eid=2-s2.0-84882747697&partnerID=40&md5=22fa02e2cbffeea00a9277e440806067","affiliation":"Departamento de Ciencia de Materiales e Ingenieria Metalurgica y Quimica Inorganica, Universidad de Cádiz, 11510 Puerto Real, Spain; Departamento de Química Aplicada, UFI 11/56, Universidad del País Vasco UPV/EHU, Apdo. 1072, 20080 San Sebastian, Spain; LENS-MIND-IN2UB Departament d'Electrònica, Universitat de Barcelona, Barcelona 08028, Spain; Institut de Ciència de Materials de Barcelona-CSIC, Campus UAB 08193, Spain","abstract":"A novel Co (15wt.%)/La-modified-CeO2 catalyst was prepared for the oxidation of toluene and ethyl acetate, showing lower light-off temperature (around 20-40°C) than that of a Pt (3wt.%)/La-CeO2 catalyst under the same experimental conditions. Upon washcoating onto cordierite it was still more active than the noble metal reference. The activity remained stable even after 80h of reaction. Adherence tests indicated a 98% stability of the washcoat, while SEM-EDS study evidenced its homogeneous distribution on the cordierite. ICP analysis and X-ray diffraction demonstrated that the composition and cobalt phase (Co3O4) of the powdered catalyst were the same in the washcoat. Moreover textural properties improved according to N2 physisorption studies due to inclusion of colloidal alumina in the slurry. © 2013 Elsevier B.V.","author_keywords":"Cobalt catalysts; Honeycomb monolith; La-modified-CeO2; VOCs oxidation; Washcoating","document_type":"Article","source":"Scopus","bibtex":"@ARTICLE{Gomez2013425,\r\nauthor={Gómez, D.M.a and Gatica, J.M.a and Hernández-Garrido, J.C.a and Cifredo, G.A.a and Montes, M.b and Sanz, O.b and Rebled, J.M.c d and Vidal, H.a },\r\ntitle={A novel CoOx/La-modified-CeO2 formulation for powdered and washcoated onto cordierite honeycomb catalysts with application in VOCs oxidation},\r\njournal={Applied Catalysis B: Environmental},\r\nyear={2013},\r\nvolume={144},\r\npages={425-434},\r\ndoi={10.1016/j.apcatb.2013.07.045},\r\nnote={cited By 7},\r\nurl={https://www.scopus.com/inward/record.url?eid=2-s2.0-84882747697&partnerID=40&md5=22fa02e2cbffeea00a9277e440806067},\r\naffiliation={Departamento de Ciencia de Materiales e Ingenieria Metalurgica y Quimica Inorganica, Universidad de Cádiz, 11510 Puerto Real, Spain; Departamento de Química Aplicada, UFI 11/56, Universidad del País Vasco UPV/EHU, Apdo. 1072, 20080 San Sebastian, Spain; LENS-MIND-IN2UB Departament d'Electrònica, Universitat de Barcelona, Barcelona 08028, Spain; Institut de Ciència de Materials de Barcelona-CSIC, Campus UAB 08193, Spain},\r\nabstract={A novel Co (15wt.%)/La-modified-CeO2 catalyst was prepared for the oxidation of toluene and ethyl acetate, showing lower light-off temperature (around 20-40°C) than that of a Pt (3wt.%)/La-CeO2 catalyst under the same experimental conditions. Upon washcoating onto cordierite it was still more active than the noble metal reference. The activity remained stable even after 80h of reaction. Adherence tests indicated a 98% stability of the washcoat, while SEM-EDS study evidenced its homogeneous distribution on the cordierite. ICP analysis and X-ray diffraction demonstrated that the composition and cobalt phase (Co3O4) of the powdered catalyst were the same in the washcoat. Moreover textural properties improved according to N2 physisorption studies due to inclusion of colloidal alumina in the slurry. © 2013 Elsevier B.V.},\r\nauthor_keywords={Cobalt catalysts; Honeycomb monolith; La-modified-CeO2; VOCs oxidation; Washcoating},\r\ndocument_type={Article},\r\nsource={Scopus},\r\n}\r\n\r\n","author_short":["Gómez, D.","Gatica, J.","Hernández-Garrido, J.","Cifredo, G.","Montes, M.","Sanz, O.","Rebled, J. d","Vidal, H."],"key":"Gomez2013425","id":"Gomez2013425","bibbaseid":"gmez-gatica-hernndezgarrido-cifredo-montes-sanz-rebled-vidal-anovelcooxlamodifiedceo2formulationforpowderedandwashcoatedontocordieritehoneycombcatalystswithapplicationinvocsoxidation-2013","role":"author","urls":{"Paper":"https://www.scopus.com/inward/record.url?eid=2-s2.0-84882747697&partnerID=40&md5=22fa02e2cbffeea00a9277e440806067"},"downloads":0,"html":"","metadata":{"authorlinks":{}}},"search_terms":["novel","coox","modified","ceo2","formulation","powdered","washcoated","onto","cordierite","honeycomb","catalysts","application","vocs","oxidation","gómez","gatica","hernández-garrido","cifredo","montes","sanz","rebled","vidal"],"keywords":[],"authorIDs":[],"dataSources":["BraPrFTJMD8Pu6SQ6"]}