Characterization of organosulfates from the photooxidation of isoprene and unsaturated fatty acids in ambient aerosol using liquid chromatography/(−) electrospray ionization mass spectrometry. Gómez-González, Y., Surratt, J., D., Cuyckens, F., Szmigielski, R., Vermeylen, R., Jaoui, M., Lewandowski, M., Offenberg, J., H., Kleindienst, T., E., Edney, E., O., Blockhuys, F., Van Alsenoy, C., Maenhaut, W., & Claeys, M. Journal of Mass Spectrometry, 43(3):371-382, 3, 2008.
Paper
Website abstract bibtex The administration of synthetic steroid copies is one of the most important issues facing sports. Doping control laboratories accredited by the World Anti-Doping Agency (WADA) require methods of analysis that allow endogenous steroids to be distinguished from their synthetic analogs in urine. The ability to measure isotope distribution at natural abundance with high accuracy and precision has increased the application of Gas Chromatography-Combustion-Isotope Ratio Mass Spectrometry (GC-C-IRMS) to doping control in recent years. GC-C-IRMS is capable of measuring the carbon isotope ratio (delta(13)C) of urinary steroids and confirm their synthetic origin based on the abnormal (13)C content. This tutorial describes some of the complexities encountered by obtaining valid delta(13)C measurements from GC-C-IRMS and the need for careful interpretation of all relevant information concerning an individual's metabolism in order to make an informed decision with respect to a doping violation.
@article{
title = {Characterization of organosulfates from the photooxidation of isoprene and unsaturated fatty acids in ambient aerosol using liquid chromatography/(−) electrospray ionization mass spectrometry},
type = {article},
year = {2008},
identifiers = {[object Object]},
keywords = {aerosol,humic-like substances,hydroxyacids,isoprene,organosulfates,secondary organic,sulfate esters,unsaturated fatty acids},
pages = {371-382},
volume = {43},
websites = {http://doi.wiley.com/10.1002/jms.1329},
month = {3},
id = {e9f80c1a-10c1-3221-96d8-53fa7e426429},
created = {2015-08-12T00:23:30.000Z},
file_attached = {true},
profile_id = {5a758209-74fb-3a9c-b322-2ae7f22f7b6c},
group_id = {63e349d6-2c70-3938-9e67-2f6483f6cbab},
last_modified = {2015-08-12T00:30:17.000Z},
read = {true},
starred = {false},
authored = {false},
confirmed = {true},
hidden = {false},
abstract = {The administration of synthetic steroid copies is one of the most important issues facing sports. Doping control laboratories accredited by the World Anti-Doping Agency (WADA) require methods of analysis that allow endogenous steroids to be distinguished from their synthetic analogs in urine. The ability to measure isotope distribution at natural abundance with high accuracy and precision has increased the application of Gas Chromatography-Combustion-Isotope Ratio Mass Spectrometry (GC-C-IRMS) to doping control in recent years. GC-C-IRMS is capable of measuring the carbon isotope ratio (delta(13)C) of urinary steroids and confirm their synthetic origin based on the abnormal (13)C content. This tutorial describes some of the complexities encountered by obtaining valid delta(13)C measurements from GC-C-IRMS and the need for careful interpretation of all relevant information concerning an individual's metabolism in order to make an informed decision with respect to a doping violation.},
bibtype = {article},
author = {Gómez-González, Yadian and Surratt, Jason D. and Cuyckens, Filip and Szmigielski, Rafal and Vermeylen, Reinhilde and Jaoui, Mohammed and Lewandowski, Michael and Offenberg, John H. and Kleindienst, Tadeusz E. and Edney, Edward O. and Blockhuys, Frank and Van Alsenoy, Christian and Maenhaut, Willy and Claeys, Magda},
journal = {Journal of Mass Spectrometry},
number = {3}
}
Downloads: 0
{"_id":"LKCYNBSaGAGvGa9dn","bibbaseid":"gmezgonzlez-surratt-cuyckens-szmigielski-vermeylen-jaoui-lewandowski-offenberg-etal-characterizationoforganosulfatesfromthephotooxidationofisopreneandunsaturatedfattyacidsinambientaerosolusingliquidchromatographyelectrosprayionizationmassspectrometry-2008","downloads":0,"creationDate":"2017-01-12T21:32:12.189Z","title":"Characterization of organosulfates from the photooxidation of isoprene and unsaturated fatty acids in ambient aerosol using liquid chromatography/(−) electrospray ionization mass spectrometry","author_short":["Gómez-González, Y.","Surratt, J., D.","Cuyckens, F.","Szmigielski, R.","Vermeylen, R.","Jaoui, M.","Lewandowski, M.","Offenberg, J., H.","Kleindienst, T., E.","Edney, E., O.","Blockhuys, F.","Van Alsenoy, C.","Maenhaut, W.","Claeys, M."],"year":2008,"bibtype":"article","biburl":null,"bibdata":{"title":"Characterization of organosulfates from the photooxidation of isoprene and unsaturated fatty acids in ambient aerosol using liquid chromatography/(−) electrospray ionization mass spectrometry","type":"article","year":"2008","identifiers":"[object Object]","keywords":"aerosol,humic-like substances,hydroxyacids,isoprene,organosulfates,secondary organic,sulfate esters,unsaturated fatty acids","pages":"371-382","volume":"43","websites":"http://doi.wiley.com/10.1002/jms.1329","month":"3","id":"e9f80c1a-10c1-3221-96d8-53fa7e426429","created":"2015-08-12T00:23:30.000Z","file_attached":"true","profile_id":"5a758209-74fb-3a9c-b322-2ae7f22f7b6c","group_id":"63e349d6-2c70-3938-9e67-2f6483f6cbab","last_modified":"2015-08-12T00:30:17.000Z","read":"true","starred":false,"authored":false,"confirmed":"true","hidden":false,"abstract":"The administration of synthetic steroid copies is one of the most important issues facing sports. Doping control laboratories accredited by the World Anti-Doping Agency (WADA) require methods of analysis that allow endogenous steroids to be distinguished from their synthetic analogs in urine. The ability to measure isotope distribution at natural abundance with high accuracy and precision has increased the application of Gas Chromatography-Combustion-Isotope Ratio Mass Spectrometry (GC-C-IRMS) to doping control in recent years. GC-C-IRMS is capable of measuring the carbon isotope ratio (delta(13)C) of urinary steroids and confirm their synthetic origin based on the abnormal (13)C content. This tutorial describes some of the complexities encountered by obtaining valid delta(13)C measurements from GC-C-IRMS and the need for careful interpretation of all relevant information concerning an individual's metabolism in order to make an informed decision with respect to a doping violation.","bibtype":"article","author":"Gómez-González, Yadian and Surratt, Jason D. and Cuyckens, Filip and Szmigielski, Rafal and Vermeylen, Reinhilde and Jaoui, Mohammed and Lewandowski, Michael and Offenberg, John H. and Kleindienst, Tadeusz E. and Edney, Edward O. and Blockhuys, Frank and Van Alsenoy, Christian and Maenhaut, Willy and Claeys, Magda","journal":"Journal of Mass Spectrometry","number":"3","bibtex":"@article{\n title = {Characterization of organosulfates from the photooxidation of isoprene and unsaturated fatty acids in ambient aerosol using liquid chromatography/(−) electrospray ionization mass spectrometry},\n type = {article},\n year = {2008},\n identifiers = {[object Object]},\n keywords = {aerosol,humic-like substances,hydroxyacids,isoprene,organosulfates,secondary organic,sulfate esters,unsaturated fatty acids},\n pages = {371-382},\n volume = {43},\n websites = {http://doi.wiley.com/10.1002/jms.1329},\n month = {3},\n id = {e9f80c1a-10c1-3221-96d8-53fa7e426429},\n created = {2015-08-12T00:23:30.000Z},\n file_attached = {true},\n profile_id = {5a758209-74fb-3a9c-b322-2ae7f22f7b6c},\n group_id = {63e349d6-2c70-3938-9e67-2f6483f6cbab},\n last_modified = {2015-08-12T00:30:17.000Z},\n read = {true},\n starred = {false},\n authored = {false},\n confirmed = {true},\n hidden = {false},\n abstract = {The administration of synthetic steroid copies is one of the most important issues facing sports. Doping control laboratories accredited by the World Anti-Doping Agency (WADA) require methods of analysis that allow endogenous steroids to be distinguished from their synthetic analogs in urine. The ability to measure isotope distribution at natural abundance with high accuracy and precision has increased the application of Gas Chromatography-Combustion-Isotope Ratio Mass Spectrometry (GC-C-IRMS) to doping control in recent years. GC-C-IRMS is capable of measuring the carbon isotope ratio (delta(13)C) of urinary steroids and confirm their synthetic origin based on the abnormal (13)C content. This tutorial describes some of the complexities encountered by obtaining valid delta(13)C measurements from GC-C-IRMS and the need for careful interpretation of all relevant information concerning an individual's metabolism in order to make an informed decision with respect to a doping violation.},\n bibtype = {article},\n author = {Gómez-González, Yadian and Surratt, Jason D. and Cuyckens, Filip and Szmigielski, Rafal and Vermeylen, Reinhilde and Jaoui, Mohammed and Lewandowski, Michael and Offenberg, John H. and Kleindienst, Tadeusz E. and Edney, Edward O. and Blockhuys, Frank and Van Alsenoy, Christian and Maenhaut, Willy and Claeys, Magda},\n journal = {Journal of Mass Spectrometry},\n number = {3}\n}","author_short":["Gómez-González, Y.","Surratt, J., D.","Cuyckens, F.","Szmigielski, R.","Vermeylen, R.","Jaoui, M.","Lewandowski, M.","Offenberg, J., H.","Kleindienst, T., E.","Edney, E., O.","Blockhuys, F.","Van Alsenoy, C.","Maenhaut, W.","Claeys, M."],"urls":{"Paper":"http://bibbase.org/service/mendeley/9edae5ec-3a23-3830-8934-2c27bef6ccbe/file/5b6f6a5c-765b-6f89-4a28-e551bc2a4678/2008-Characterization_of_organosulfates_from_the_photooxidation_of_isoprene_and_unsaturated_fatty_acids_in_ambient_aeros.pdf.pdf","Website":"http://doi.wiley.com/10.1002/jms.1329"},"bibbaseid":"gmezgonzlez-surratt-cuyckens-szmigielski-vermeylen-jaoui-lewandowski-offenberg-etal-characterizationoforganosulfatesfromthephotooxidationofisopreneandunsaturatedfattyacidsinambientaerosolusingliquidchromatographyelectrosprayionizationmassspectrometry-2008","role":"author","keyword":["aerosol","humic-like substances","hydroxyacids","isoprene","organosulfates","secondary organic","sulfate esters","unsaturated fatty acids"],"downloads":0},"search_terms":["characterization","organosulfates","photooxidation","isoprene","unsaturated","fatty","acids","ambient","aerosol","using","liquid","chromatography","electrospray","ionization","mass","spectrometry","gómez-gonzález","surratt","cuyckens","szmigielski","vermeylen","jaoui","lewandowski","offenberg","kleindienst","edney","blockhuys","van alsenoy","maenhaut","claeys"],"keywords":["aerosol","humic-like substances","hydroxyacids","isoprene","organosulfates","secondary organic","sulfate esters","unsaturated fatty acids"],"authorIDs":[]}