Production of thiyl radicals and investigation of their reactions with oxygen and 2-sulfoethanethiosulfuric acid. Grachev, S. & Soroka, N. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 30(8):1426-1432, Kluwer Academic Publishers-Plenum Publishers, 1981. cited By 0Paper doi abstract bibtex 1. The kinetics of the oxidation of 2-aminoethanethiol, 3-aminopropanethiol, 4-aminobutanethiol, (dimethylamino)ethanethiol, and 2-mercaptoethanol by the 1,10-phenanthroline complex [Fe(phen)3]3+ were studied. The complex [Fe(phen)3]3+ only reacts with thiols containing a deprotonated mercapto group. 2. The stoichiometry and the reaction products in the 2-aminoethanethiol + [Fe(phen)3]3+ +oxygen system were studied. 3. 2-Sulfo-1-ethanethiosulfuric acid can be used as reagent for thiyl radicals. 4. The differences between the processes occurring in the thiol+[Fe(phen)3]3++O2 system at pH > 1.5 and the reactions in which RS. radicals participate during radiolysis of the thiols in the presence of oxygen were determined. © 1982 Plenum Publishing Corporation.
@ARTICLE{Grachev19811426,
author={Grachev, S.A. and Soroka, N.V.},
title={Production of thiyl radicals and investigation of their reactions with oxygen and 2-sulfoethanethiosulfuric acid},
journal={Bulletin of the Academy of Sciences of the USSR Division of Chemical Science},
year={1981},
volume={30},
number={8},
pages={1426-1432},
doi={10.1007/BF00952189},
note={cited By 0},
url={https://www.scopus.com/inward/record.uri?eid=2-s2.0-34250229218&doi=10.1007%2fBF00952189&partnerID=40&md5=9e31ffd7ee5f4bd64859f42b59e3c198},
affiliation={B. P. Konstantinov Leningrad Institute of Nuclear Physics},
abstract={1. The kinetics of the oxidation of 2-aminoethanethiol, 3-aminopropanethiol, 4-aminobutanethiol, (dimethylamino)ethanethiol, and 2-mercaptoethanol by the 1,10-phenanthroline complex [Fe(phen)3]3+ were studied. The complex [Fe(phen)3]3+ only reacts with thiols containing a deprotonated mercapto group. 2. The stoichiometry and the reaction products in the 2-aminoethanethiol + [Fe(phen)3]3+ +oxygen system were studied. 3. 2-Sulfo-1-ethanethiosulfuric acid can be used as reagent for thiyl radicals. 4. The differences between the processes occurring in the thiol+[Fe(phen)3]3++O2 system at pH > 1.5 and the reactions in which RS. radicals participate during radiolysis of the thiols in the presence of oxygen were determined. © 1982 Plenum Publishing Corporation.},
correspondence_address1={Grachev, S.A.; B. P. Konstantinov Leningrad Institute of Nuclear Physics},
publisher={Kluwer Academic Publishers-Plenum Publishers},
issn={05685230},
language={English},
abbrev_source_title={Russ Chem Bull},
document_type={Article},
source={Scopus},
}
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