@article{ gracia-fernandez_vitrification_2010,
  title = {A vitrification and curing study by simultaneous {TMDSC}-photocalorimetry},
  volume = {102},
  issn = {1388-6150, 1572-8943},
  url = {http://link.springer.com/article/10.1007/s10973-010-0872-z},
  doi = {10.1007/s10973-010-0872-z},
  abstract = {The development of photopolymers was helped by the development of photocalorimetry, which is now a basic technique for the study of these materials. This work shows how to obtain vitrification times in single isothermal curing experiments by monitoring the reversing heat capacity along time in modulated temperature {DSC}–photocuring systems, overcoming the time-consuming problem of standard {DSC}. The effects of the light intensity and the isothermal curing temperature on the vitrification time of a photocurable system were evaluated. The results obtained at a given curing temperature with different light intensities indicate that the {UV}-light affects the molecular mobility hindering the vitrification process. The effects of the curing temperature on the vitrification time, the conversion at the vitrification time and the maximum conversion were also evaluated.},
  language = {en},
  number = {3},
  urldate = {2014-09-15TZ},
  journal = {Journal of Thermal Analysis and Calorimetry},
  author = {Gracia-Fernández, C. A. and Davies, P. and Gómez-Barreiro, S. and Beceiro, J. López and Tarrío-Saavedra, J. and Artiaga, R.},
  month = {December},
  year = {2010},
  keywords = {Analytical Chemistry, Inorganic Chemistry, Measurement Science and Instrumentation, Photocalorimetry, Photocuring, Physical Chemistry, Polymer Sciences, {TMDSC}, Vitrification time},
  pages = {1057--1062}
}

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The effects of the light intensity and the isothermal curing temperature on the vitrification time of a photocurable system were evaluated. The results obtained at a given curing temperature with different light intensities indicate that the UV-light affects the molecular mobility hindering the vitrification process. The effects of the curing temperature on the vitrification time, the conversion at the vitrification time and the maximum conversion were also evaluated.","author":["Gracia-Fernández, C. A.","Davies, P.","Gómez-Barreiro, S.","Beceiro","López, J.","Tarrío-Saavedra, J.","Artiaga, R."],"author_short":["Gracia-Fernández, C.<nbsp>A.","Davies, P.","Gómez-Barreiro, S.","Beceiro","López, J.","Tarrío-Saavedra, J.","Artiaga, R."],"bibtex":"@article{ gracia-fernandez_vitrification_2010,\n title = {A vitrification and curing study by simultaneous {TMDSC}-photocalorimetry},\n volume = {102},\n issn = {1388-6150, 1572-8943},\n url = {http://link.springer.com/article/10.1007/s10973-010-0872-z},\n doi = {10.1007/s10973-010-0872-z},\n abstract = {The development of photopolymers was helped by the development of photocalorimetry, which is now a basic technique for the study of these materials. This work shows how to obtain vitrification times in single isothermal curing experiments by monitoring the reversing heat capacity along time in modulated temperature {DSC}–photocuring systems, overcoming the time-consuming problem of standard {DSC}. The effects of the light intensity and the isothermal curing temperature on the vitrification time of a photocurable system were evaluated. The results obtained at a given curing temperature with different light intensities indicate that the {UV}-light affects the molecular mobility hindering the vitrification process. The effects of the curing temperature on the vitrification time, the conversion at the vitrification time and the maximum conversion were also evaluated.},\n language = {en},\n number = {3},\n urldate = {2014-09-15TZ},\n journal = {Journal of Thermal Analysis and Calorimetry},\n author = {Gracia-Fernández, C. A. and Davies, P. and Gómez-Barreiro, S. and Beceiro, J. 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