Molecular-level characterization of the structure and the surface chemistry of periodic mesoporous organosilicates using DNP-surface enhanced NMR spectroscopy. Grüning, W. R, Rossini, A. J, Zagdoun, A., Gajan, D., Lesage, A., Emsley, L., & Copéret, C. Physical chemistry chemical physics : PCCP, 15:13270–13274, 2013.
Molecular-level characterization of the structure and the surface chemistry of periodic mesoporous organosilicates using DNP-surface enhanced NMR spectroscopy. [link]Paper  doi  abstract   bibtex   
We present the molecular level characterization of a phenylpyridine-based periodic mesoporous organosilicate and its post-functionalized organometallic derivatives through the fast acquisition of high quality natural isotopic abundance 1D (13)C, (15)N, and (29)Si and 2D (1)H-(13)C and (1)H-(29)Si solid-state NMR spectra enhanced with dynamic nuclear polarization.
@article{Gruning2013,
	title = {Molecular-level characterization of the structure and the surface chemistry of periodic mesoporous organosilicates using {DNP}-surface enhanced {NMR} spectroscopy.},
	volume = {15},
	issn = {1463-9084},
	url = {http://www.ncbi.nlm.nih.gov/pubmed/23440402},
	doi = {10.1039/c3cp00026e},
	abstract = {We present the molecular level characterization of a phenylpyridine-based periodic mesoporous organosilicate and its post-functionalized organometallic derivatives through the fast acquisition of high quality natural isotopic abundance 1D (13)C, (15)N, and (29)Si and 2D (1)H-(13)C and (1)H-(29)Si solid-state NMR spectra enhanced with dynamic nuclear polarization.},
	journal = {Physical chemistry chemical physics : PCCP},
	author = {Grüning, Wolfram R and Rossini, Aaron J and Zagdoun, Alexandre and Gajan, David and Lesage, Anne and Emsley, Lyndon and Copéret, Christophe},
	year = {2013},
	pmid = {23440402},
	keywords = {\#nosource, Magnetic Resonance Spectroscopy, Magnetic Resonance Spectroscopy: methods, Molecular Structure, Organosilicon Compounds, Organosilicon Compounds: chemistry, Particle Size, Porosity, Surface Properties},
	pages = {13270--13274},
}

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