@article{guillet_synthesis_2020,
	title = {Synthesis and {Characterization} of a {Linear} {Triiron}({II}) {Extended} {Metal} {Atom} {Chain} {Complex} with {Fe}-{Fe} {Bonds}},
	volume = {59},
	copyright = {All rights reserved},
	issn = {1520-510X},
	abstract = {Extended metal atom chain (EMAC) complexes of first-row transition metals with metal-metal bonds have the potential to elicit unique magnetic properties and reactivities.  Until now, the library of EMAC complexes with late-first-row transition metals was incomplete because of the omission of a triiron species with Fe-Fe bonding.  Herein we report the synthesis and preliminary investigation of the first linear, triiron(II) complex containing close Fe-Fe interactions.  The complex is supported by three dianionic 2,6-bis[(trimethylsilyl)amido]pyridine ligands (L), with an overall composition of Fe3L3, and pseudohelical ligand coordination stabilizing the local trigonal-planar geometry at each iron.  Fe3L3 was characterized by X-ray diffraction, (1)H NMR, cyclic voltammetry, electronic absorption, and Mossbauer spectroscopies.  Evans method analysis indicated a large uncompensated spin and an S = 6 ground state, suggesting ferromagnetic coupling in the triiron chain, likely due to direct exchange.[on SciFinder (R)]},
	journal = {Inorganic chemistry},
	author = {Guillet, Gary L. and Arpin, Kathleen Y. and Boltin, Alan M. and Rave, Justin A. and Gordon, Jesse B. and Hillesheim, Patrick C.},
	year = {2020},
	pages = {11238--11243},
	url_paper={https://api.zotero.org/users/5598735/publications/items/BPJTAAFA/file/view}
}

{"_id":"axoG8STBcGgMskSyS","bibbaseid":"guillet-arpin-boltin-rave-gordon-hillesheim-synthesisandcharacterizationofalineartriironiiextendedmetalatomchaincomplexwithfefebonds-2020","author_short":["Guillet, G. L.","Arpin, K. Y.","Boltin, A. M.","Rave, J. A.","Gordon, J. B.","Hillesheim, P. C."],"bibdata":{"bibtype":"article","type":"article","title":"Synthesis and Characterization of a Linear Triiron(II) Extended Metal Atom Chain Complex with Fe-Fe Bonds","volume":"59","copyright":"All rights reserved","issn":"1520-510X","abstract":"Extended metal atom chain (EMAC) complexes of first-row transition metals with metal-metal bonds have the potential to elicit unique magnetic properties and reactivities. Until now, the library of EMAC complexes with late-first-row transition metals was incomplete because of the omission of a triiron species with Fe-Fe bonding. Herein we report the synthesis and preliminary investigation of the first linear, triiron(II) complex containing close Fe-Fe interactions. The complex is supported by three dianionic 2,6-bis[(trimethylsilyl)amido]pyridine ligands (L), with an overall composition of Fe3L3, and pseudohelical ligand coordination stabilizing the local trigonal-planar geometry at each iron. Fe3L3 was characterized by X-ray diffraction, (1)H NMR, cyclic voltammetry, electronic absorption, and Mossbauer spectroscopies. Evans method analysis indicated a large uncompensated spin and an S = 6 ground state, suggesting ferromagnetic coupling in the triiron chain, likely due to direct exchange.[on SciFinder (R)]","journal":"Inorganic chemistry","author":[{"propositions":[],"lastnames":["Guillet"],"firstnames":["Gary","L."],"suffixes":[]},{"propositions":[],"lastnames":["Arpin"],"firstnames":["Kathleen","Y."],"suffixes":[]},{"propositions":[],"lastnames":["Boltin"],"firstnames":["Alan","M."],"suffixes":[]},{"propositions":[],"lastnames":["Rave"],"firstnames":["Justin","A."],"suffixes":[]},{"propositions":[],"lastnames":["Gordon"],"firstnames":["Jesse","B."],"suffixes":[]},{"propositions":[],"lastnames":["Hillesheim"],"firstnames":["Patrick","C."],"suffixes":[]}],"year":"2020","pages":"11238–11243","url_paper":"https://api.zotero.org/users/5598735/publications/items/BPJTAAFA/file/view","bibtex":"@article{guillet_synthesis_2020,\n\ttitle = {Synthesis and {Characterization} of a {Linear} {Triiron}({II}) {Extended} {Metal} {Atom} {Chain} {Complex} with {Fe}-{Fe} {Bonds}},\n\tvolume = {59},\n\tcopyright = {All rights reserved},\n\tissn = {1520-510X},\n\tabstract = {Extended metal atom chain (EMAC) complexes of first-row transition metals with metal-metal bonds have the potential to elicit unique magnetic properties and reactivities. Until now, the library of EMAC complexes with late-first-row transition metals was incomplete because of the omission of a triiron species with Fe-Fe bonding. Herein we report the synthesis and preliminary investigation of the first linear, triiron(II) complex containing close Fe-Fe interactions. The complex is supported by three dianionic 2,6-bis[(trimethylsilyl)amido]pyridine ligands (L), with an overall composition of Fe3L3, and pseudohelical ligand coordination stabilizing the local trigonal-planar geometry at each iron. Fe3L3 was characterized by X-ray diffraction, (1)H NMR, cyclic voltammetry, electronic absorption, and Mossbauer spectroscopies. Evans method analysis indicated a large uncompensated spin and an S = 6 ground state, suggesting ferromagnetic coupling in the triiron chain, likely due to direct exchange.[on SciFinder (R)]},\n\tjournal = {Inorganic chemistry},\n\tauthor = {Guillet, Gary L. and Arpin, Kathleen Y. and Boltin, Alan M. and Rave, Justin A. and Gordon, Jesse B. and Hillesheim, Patrick C.},\n\tyear = {2020},\n\tpages = {11238--11243},\n\turl_paper={https://api.zotero.org/users/5598735/publications/items/BPJTAAFA/file/view}\n}\n\n\n\n","author_short":["Guillet, G. L.","Arpin, K. Y.","Boltin, A. M.","Rave, J. A.","Gordon, J. B.","Hillesheim, P. C."],"key":"guillet_synthesis_2020","id":"guillet_synthesis_2020","bibbaseid":"guillet-arpin-boltin-rave-gordon-hillesheim-synthesisandcharacterizationofalineartriironiiextendedmetalatomchaincomplexwithfefebonds-2020","role":"author","urls":{" paper":"https://api.zotero.org/users/5598735/publications/items/BPJTAAFA/file/view"},"metadata":{"authorlinks":{}},"downloads":0,"html":""},"bibtype":"article","biburl":"https://bibbase.org/zotero-mypublications/SentientToast","dataSources":["ehszj4YRysFoDwA2R"],"keywords":[],"search_terms":["synthesis","characterization","linear","triiron","extended","metal","atom","chain","complex","bonds","guillet","arpin","boltin","rave","gordon","hillesheim"],"title":"Synthesis and Characterization of a Linear Triiron(II) Extended Metal Atom Chain Complex with Fe-Fe Bonds","year":2020}