Cobalt-mediated catalytic chain-transfer polymerization (CCTP) in water and water/alcohol solution. Haddleton, D., M., Depaquis, E., Kelly, E., J., Kukulj, D., Morsley, S., R., Bon, S., A., Eason, M., D., & Steward, A., G. Journal of Polymer Science, Part A: Polymer Chemistry, 39(14):2378-2384, John Wiley & Sons, Inc., 2001. Website doi abstract bibtex This article describes the use of cobalt-mediated catalytic chain transfer in aqueous solution under fed conditions for the preparation of macromonomers of acidic, hydroxy, and zwitterionic functional monomers. Use of a batch reaction leads to hydrolysis of catalyst, a mixture of mechanisms and poor control of the reaction. A feed process is described that adds catalyst as a solution in monomer over the course of the reaction. The feed process is applied to a range of monomers of methacrylic acid (2), 2-aminoethyl methacrylate hydrochloride (3), 2-hydroxyethyl methacrylate (4), 2-methacryloxyethyl phosphoryl choline (5), glycerol monomethyl methacrylate (6), and 3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-D-glucofuranose (7). Use of the feed process for water-soluble monomers in conjunction with 1 as a catalytic chain-transfer agent gives high-conversion, > 90%, water-soluble macromonomers. The number-average molecular mass (Mn was determined by integration of the 1H NMR spectrum comparing the vinylic end group with the remainder of the backbone. Pseudo-Mayo plots were constructed by measuring the Mn at high conversion as a function of [monomer]/[catalyst] to give observed chain-transfer constants of 1120, 958, and 1058 for 4, 6, and 2, respectively. All products were obtained as relatively high-solid, homogeneous, low-viscosity aqueous solutions.
@article{
title = {Cobalt-mediated catalytic chain-transfer polymerization (CCTP) in water and water/alcohol solution},
type = {article},
year = {2001},
keywords = {Catalytic chain transfer,Cobalt,Hydrophilic,Macromonomer,Methacrylate},
pages = {2378-2384},
volume = {39},
websites = {http://onlinelibrary.wiley.com/doi/10.1002/pola.1214/full},
publisher = {John Wiley & Sons, Inc.},
id = {61542520-0c0a-3e29-9b13-554b251a6619},
created = {2024-01-02T14:09:43.144Z},
file_attached = {false},
profile_id = {36921318-7a81-32e6-acca-75b835acd8f1},
group_id = {f2d52f92-0a5a-3712-a53b-a4492da8da5f},
last_modified = {2024-01-02T14:09:43.144Z},
read = {false},
starred = {false},
authored = {false},
confirmed = {true},
hidden = {false},
citation_key = {haddleton2001cobalt},
source_type = {article},
private_publication = {false},
abstract = {This article describes the use of cobalt-mediated catalytic chain transfer in aqueous solution under fed conditions for the preparation of macromonomers of acidic, hydroxy, and zwitterionic functional monomers. Use of a batch reaction leads to hydrolysis of catalyst, a mixture of mechanisms and poor control of the reaction. A feed process is described that adds catalyst as a solution in monomer over the course of the reaction. The feed process is applied to a range of monomers of methacrylic acid (2), 2-aminoethyl methacrylate hydrochloride (3), 2-hydroxyethyl methacrylate (4), 2-methacryloxyethyl phosphoryl choline (5), glycerol monomethyl methacrylate (6), and 3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-D-glucofuranose (7). Use of the feed process for water-soluble monomers in conjunction with 1 as a catalytic chain-transfer agent gives high-conversion, > 90%, water-soluble macromonomers. The number-average molecular mass (Mn was determined by integration of the 1H NMR spectrum comparing the vinylic end group with the remainder of the backbone. Pseudo-Mayo plots were constructed by measuring the Mn at high conversion as a function of [monomer]/[catalyst] to give observed chain-transfer constants of 1120, 958, and 1058 for 4, 6, and 2, respectively. All products were obtained as relatively high-solid, homogeneous, low-viscosity aqueous solutions.},
bibtype = {article},
author = {Haddleton, David M. and Depaquis, Estelle and Kelly, Elizabeth J. and Kukulj, Dax and Morsley, Stuart R. and Bon, Stefan A.F. and Eason, Michael D. and Steward, Andrew G.},
doi = {10.1002/pola.1214},
journal = {Journal of Polymer Science, Part A: Polymer Chemistry},
number = {14}
}
Downloads: 0
{"_id":"6E6A5AG7ZAx6wDAtu","bibbaseid":"haddleton-depaquis-kelly-kukulj-morsley-bon-eason-steward-cobaltmediatedcatalyticchaintransferpolymerizationcctpinwaterandwateralcoholsolution-2001","downloads":0,"creationDate":"2015-12-22T20:07:00.504Z","title":"Cobalt-mediated catalytic chain-transfer polymerization (CCTP) in water and water/alcohol solution","author_short":["Haddleton, D., M.","Depaquis, E.","Kelly, E., J.","Kukulj, D.","Morsley, S., R.","Bon, S., A.","Eason, M., D.","Steward, A., G."],"year":2001,"bibtype":"article","biburl":"https://bibbase.org/service/mendeley/36921318-7a81-32e6-acca-75b835acd8f1","bibdata":{"title":"Cobalt-mediated catalytic chain-transfer polymerization (CCTP) in water and water/alcohol solution","type":"article","year":"2001","keywords":"Catalytic chain transfer,Cobalt,Hydrophilic,Macromonomer,Methacrylate","pages":"2378-2384","volume":"39","websites":"http://onlinelibrary.wiley.com/doi/10.1002/pola.1214/full","publisher":"John Wiley & Sons, Inc.","id":"61542520-0c0a-3e29-9b13-554b251a6619","created":"2024-01-02T14:09:43.144Z","file_attached":false,"profile_id":"36921318-7a81-32e6-acca-75b835acd8f1","group_id":"f2d52f92-0a5a-3712-a53b-a4492da8da5f","last_modified":"2024-01-02T14:09:43.144Z","read":false,"starred":false,"authored":false,"confirmed":"true","hidden":false,"citation_key":"haddleton2001cobalt","source_type":"article","private_publication":false,"abstract":"This article describes the use of cobalt-mediated catalytic chain transfer in aqueous solution under fed conditions for the preparation of macromonomers of acidic, hydroxy, and zwitterionic functional monomers. Use of a batch reaction leads to hydrolysis of catalyst, a mixture of mechanisms and poor control of the reaction. A feed process is described that adds catalyst as a solution in monomer over the course of the reaction. The feed process is applied to a range of monomers of methacrylic acid (2), 2-aminoethyl methacrylate hydrochloride (3), 2-hydroxyethyl methacrylate (4), 2-methacryloxyethyl phosphoryl choline (5), glycerol monomethyl methacrylate (6), and 3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-D-glucofuranose (7). Use of the feed process for water-soluble monomers in conjunction with 1 as a catalytic chain-transfer agent gives high-conversion, > 90%, water-soluble macromonomers. The number-average molecular mass (Mn was determined by integration of the 1H NMR spectrum comparing the vinylic end group with the remainder of the backbone. Pseudo-Mayo plots were constructed by measuring the Mn at high conversion as a function of [monomer]/[catalyst] to give observed chain-transfer constants of 1120, 958, and 1058 for 4, 6, and 2, respectively. All products were obtained as relatively high-solid, homogeneous, low-viscosity aqueous solutions.","bibtype":"article","author":"Haddleton, David M. and Depaquis, Estelle and Kelly, Elizabeth J. and Kukulj, Dax and Morsley, Stuart R. and Bon, Stefan A.F. and Eason, Michael D. and Steward, Andrew G.","doi":"10.1002/pola.1214","journal":"Journal of Polymer Science, Part A: Polymer Chemistry","number":"14","bibtex":"@article{\n title = {Cobalt-mediated catalytic chain-transfer polymerization (CCTP) in water and water/alcohol solution},\n type = {article},\n year = {2001},\n keywords = {Catalytic chain transfer,Cobalt,Hydrophilic,Macromonomer,Methacrylate},\n pages = {2378-2384},\n volume = {39},\n websites = {http://onlinelibrary.wiley.com/doi/10.1002/pola.1214/full},\n publisher = {John Wiley & Sons, Inc.},\n id = {61542520-0c0a-3e29-9b13-554b251a6619},\n created = {2024-01-02T14:09:43.144Z},\n file_attached = {false},\n profile_id = {36921318-7a81-32e6-acca-75b835acd8f1},\n group_id = {f2d52f92-0a5a-3712-a53b-a4492da8da5f},\n last_modified = {2024-01-02T14:09:43.144Z},\n read = {false},\n starred = {false},\n authored = {false},\n confirmed = {true},\n hidden = {false},\n citation_key = {haddleton2001cobalt},\n source_type = {article},\n private_publication = {false},\n abstract = {This article describes the use of cobalt-mediated catalytic chain transfer in aqueous solution under fed conditions for the preparation of macromonomers of acidic, hydroxy, and zwitterionic functional monomers. Use of a batch reaction leads to hydrolysis of catalyst, a mixture of mechanisms and poor control of the reaction. A feed process is described that adds catalyst as a solution in monomer over the course of the reaction. The feed process is applied to a range of monomers of methacrylic acid (2), 2-aminoethyl methacrylate hydrochloride (3), 2-hydroxyethyl methacrylate (4), 2-methacryloxyethyl phosphoryl choline (5), glycerol monomethyl methacrylate (6), and 3-O-methacryloyl-1,2:5,6-di-O-isopropylidene-D-glucofuranose (7). Use of the feed process for water-soluble monomers in conjunction with 1 as a catalytic chain-transfer agent gives high-conversion, > 90%, water-soluble macromonomers. The number-average molecular mass (Mn was determined by integration of the 1H NMR spectrum comparing the vinylic end group with the remainder of the backbone. Pseudo-Mayo plots were constructed by measuring the Mn at high conversion as a function of [monomer]/[catalyst] to give observed chain-transfer constants of 1120, 958, and 1058 for 4, 6, and 2, respectively. All products were obtained as relatively high-solid, homogeneous, low-viscosity aqueous solutions.},\n bibtype = {article},\n author = {Haddleton, David M. and Depaquis, Estelle and Kelly, Elizabeth J. and Kukulj, Dax and Morsley, Stuart R. and Bon, Stefan A.F. and Eason, Michael D. and Steward, Andrew G.},\n doi = {10.1002/pola.1214},\n journal = {Journal of Polymer Science, Part A: Polymer Chemistry},\n number = {14}\n}","author_short":["Haddleton, D., M.","Depaquis, E.","Kelly, E., J.","Kukulj, D.","Morsley, S., R.","Bon, S., A.","Eason, M., D.","Steward, A., G."],"urls":{"Website":"http://onlinelibrary.wiley.com/doi/10.1002/pola.1214/full"},"biburl":"https://bibbase.org/service/mendeley/36921318-7a81-32e6-acca-75b835acd8f1","bibbaseid":"haddleton-depaquis-kelly-kukulj-morsley-bon-eason-steward-cobaltmediatedcatalyticchaintransferpolymerizationcctpinwaterandwateralcoholsolution-2001","role":"author","keyword":["Catalytic chain transfer","Cobalt","Hydrophilic","Macromonomer","Methacrylate"],"metadata":{"authorlinks":{"bon, s":"https://www.bonlab.info/publications"}},"downloads":0},"search_terms":["cobalt","mediated","catalytic","chain","transfer","polymerization","cctp","water","water","alcohol","solution","haddleton","depaquis","kelly","kukulj","morsley","bon","eason","steward"],"keywords":["catalytic chain transfer","cobalt","hydrophilic","macromonomer","methacrylate"],"authorIDs":["74yNAkKzJDypPwNAe"],"dataSources":["wdhyC6gK4W6qkYPZc","ya2CyA73rpZseyrZ8","pC6zmZiqEM2Foo9na","NcAak6LpL4rerwSST","QM3qFC2vNe7ca6T4f","W7y5fCfvoA9wPS8ig","HnQgdqk5gSojsMrCe","mSrdWAs3jeuoSxB2E","qrDxaqEHcg3eA7bSF","GxJqJfCNGPEYnWKPq","6ZG38dwbepkczBAzY"]}