Copper(I)-mediated living radical polymerization under fluorous biphasic conditions. Haddleton, D., M., Jackson, S., G., & Bon, S., A., F. Journal of the American Chemical Society, 122(7):1542-1543, the American Chemical Society, 2000.
Copper(I)-mediated living radical polymerization under fluorous biphasic conditions [link]Website  abstract   bibtex   
The title process as applied to methacrylates involves the use of the fluorous biphase as a medium for atom-transfer polymn. that would allow for the recovery of catalyst-free product and for reuse of catalyst. Atom-transfer living polymn. of Me methacrylate in perfluoromethylcyclohexane contg. CuBr and ligand pentakis-N-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecyl)-1,4,7-triazaheptane proceeds very effectively, allowing sepn. of product from catalyst, leaving the catalyst in a reusable state, which gives very reproducible results after repeated uses. [on SciFinder (R)]
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 title = {Copper(I)-mediated living radical polymerization under fluorous biphasic conditions},
 type = {article},
 year = {2000},
 identifiers = {[object Object]},
 pages = {1542-1543},
 volume = {122},
 websites = {http://pubs.acs.org/doi/abs/10.1021/ja993478f?journalCode=jacsat},
 publisher = {the American Chemical Society},
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 created = {2015-12-22T20:07:00.000Z},
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 last_modified = {2017-09-05T15:08:03.621Z},
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 abstract = {The title process as applied to methacrylates involves the use of the fluorous biphase as a medium for atom-transfer polymn. that would allow for the recovery of catalyst-free product and for reuse of catalyst. Atom-transfer living polymn. of Me methacrylate in perfluoromethylcyclohexane contg. CuBr and ligand pentakis-N-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecyl)-1,4,7-triazaheptane proceeds very effectively, allowing sepn. of product from catalyst, leaving the catalyst in a reusable state, which gives very reproducible results after repeated uses. [on SciFinder (R)]},
 bibtype = {article},
 author = {Haddleton, David M. and Jackson, Stuart G. and Bon, Stefan A F},
 journal = {Journal of the American Chemical Society},
 number = {7}
}

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