@article{
 title = {Copper(I)-mediated living radical polymerization under fluorous biphasic conditions},
 type = {article},
 year = {2000},
 pages = {1542-1543},
 volume = {122},
 websites = {http://pubs.acs.org/doi/abs/10.1021/ja993478f?journalCode=jacsat},
 publisher = {the American Chemical Society},
 id = {f7420166-dbf0-3784-89c9-286866139ec7},
 created = {2024-01-02T14:09:40.264Z},
 file_attached = {false},
 profile_id = {36921318-7a81-32e6-acca-75b835acd8f1},
 group_id = {f2d52f92-0a5a-3712-a53b-a4492da8da5f},
 last_modified = {2024-01-02T14:09:40.264Z},
 read = {false},
 starred = {false},
 authored = {false},
 confirmed = {true},
 hidden = {false},
 citation_key = {haddleton2000copper},
 source_type = {article},
 private_publication = {false},
 abstract = {The title process as applied to methacrylates involves the use of the fluorous biphase as a medium for atom-transfer polymn. that would allow for the recovery of catalyst-free product and for reuse of catalyst. Atom-transfer living polymn. of Me methacrylate in perfluoromethylcyclohexane contg. CuBr and ligand pentakis-N-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecyl)-1,4,7-triazaheptane proceeds very effectively, allowing sepn. of product from catalyst, leaving the catalyst in a reusable state, which gives very reproducible results after repeated uses. [on SciFinder (R)]},
 bibtype = {article},
 author = {Haddleton, David M. and Jackson, Stuart G. and Bon, Stefan A F},
 doi = {10.1021/ja993478f},
 journal = {Journal of the American Chemical Society},
 number = {7}
}

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