@article{
 title = {Copper-mediated living radical polymerization utilizing biological and end group modified poly(ethylene-co-butylene) macroinitiators},
 type = {article},
 year = {2000},
 pages = {182-196},
 volume = {768},
 websites = {http://pubs.acs.org/doi/abs/10.1021/bk-2000-0768.ch013},
 publisher = {ACS Publications},
 id = {6156a6d7-2d89-3b5c-9a35-531214462d97},
 created = {2024-01-02T14:09:43.840Z},
 file_attached = {false},
 profile_id = {36921318-7a81-32e6-acca-75b835acd8f1},
 group_id = {f2d52f92-0a5a-3712-a53b-a4492da8da5f},
 last_modified = {2024-01-02T14:09:43.840Z},
 read = {false},
 starred = {false},
 authored = {false},
 confirmed = {true},
 hidden = {false},
 citation_key = {haddleton2000copper},
 source_type = {article},
 private_publication = {false},
 abstract = {Copper mediated living radical polymerization can be used with a wide range of functional initiators to produce functional polymers. Block copolymers may be efficiently prepared using macroinitiators. This is demonstrated in this paper by synthesis and characterisation of a cholestrol based initiator and macroinitiators based on mono and difunctional polymers of ethylene and butylène. Polymerization of styrene and methacrylates using Schiff base ligands in conjunction with Cu(I)Br proceeds in a controlled manner yielding homopolymers, A-B diblock and A-BA triblock (co)polymers of defined molecular weight and low polydispersity. Polymers based on methacrylic acid, 2-dimethylaminoethyl methacrylate and a random copolymer of methacrylic acid and methyl methacrylate have been synthesized by use of the cholestrol initiator to give resulting water soluble/dispersible polymers.},
 bibtype = {article},
 author = {Haddleton, David M and Jarvis, Adam P and Waterson, Carl and Bon, Stefan A F and Heming, Alex M},
 doi = {10.1021/bk-2000-0768.ch013},
 journal = {ACS Symposium Series}
}

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