Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes. He, W. & Kennepohl, P. Faraday Discussions, 220:133-143, Royal Society of Chemistry, 2019.
Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes [link]Website  doi  abstract   bibtex   3 downloads  
The details of ligand-induced backbonding in nickel diphosphine π complexes are explored using nickel L-edge (3d←2p) X-ray absorption spectroscopy as a means of quantifying the degree of backbonding derived from direct Ni 3d donation into the π ligand.
@article{
 title = {Direct experimental evaluation of ligand-induced backbonding in nickel metallacyclic complexes},
 type = {article},
 year = {2019},
 pages = {133-143},
 volume = {220},
 websites = {http://dx.doi.org/10.1039/C9FD00041K,http://xlink.rsc.org/?DOI=C9FD00041K},
 publisher = {Royal Society of Chemistry},
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 abstract = {The details of ligand-induced backbonding in nickel diphosphine π complexes are explored using nickel L-edge (3d←2p) X-ray absorption spectroscopy as a means of quantifying the degree of backbonding derived from direct Ni 3d donation into the π ligand.},
 bibtype = {article},
 author = {He, Weiying and Kennepohl, Pierre},
 doi = {10.1039/C9FD00041K},
 journal = {Faraday Discussions},
 keywords = {Computational,SSRL,X-ray Absorption Spectroscopy}
}

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