@article{hillesheim_effect_2013,
	title = {Effect of alkyl and aryl substitutions on 1,2,4-triazolium-based ionic liquids for carbon dioxide separation and capture.},
	volume = {3},
	copyright = {All rights reserved},
	issn = {2046-2069},
	doi = {10.1039/c2ra22646d},
	abstract = {A series of 1,2,4-triazolium-based ionic liqs. were synthesized and evaluated for their use in supported ionic liq. membrane-based CO2 sepn.  Properties of these triazolium-based compds. proved sensitive to isomeric substitutions, e.g., iso-Pr and Pr groups, and ortho and para substitutions in the aryl deriv. compds.  While phys. properties (e.g., viscosity) did not vary significantly among structural isomers, CO2 permeability, selectivity, and soly. exhibited significant changes allowing for development of task-specific triazolium-based ionic liqs. for sepn. applications.  COSMO-therm studies, done to better understand ionic liqs., demonstrated a strong correlation between exptl. and computational values for alkyl-bearing ionic liqs.  Thus, 1,2,4-triazolium-based liqs. comprise a class of compds. offering unique opportunities to examine how structural changes affect physicochem. properties necessary to continuously develop ionic liqs. with enhanced adsorption capacity and sepn. selectivity. [on SciFinder(R)]},
	journal = {RSC Advances},
	author = {Hillesheim, Patrick C. and Singh, Joseph A. and Mahurin, Shannon M. and Fulvio, Pasquale F. and Oyola, Yatsandra and Zhu, Xiang and Jiang, De-en and Dai, Sheng.},
	year = {2013},
	note = {Publisher: Royal Society of Chemistry},
	pages = {3981--3989},
	url_paper={https://api.zotero.org/users/5598735/publications/items/63RDWVXT/file/view}
}

{"_id":"2K5GzRBXrBvaPAzK6","bibbaseid":"hillesheim-singh-mahurin-fulvio-oyola-zhu-jiang-dai-effectofalkylandarylsubstitutionson124triazoliumbasedionicliquidsforcarbondioxideseparationandcapture-2013","author_short":["Hillesheim, P. C.","Singh, J. A.","Mahurin, S. M.","Fulvio, P. F.","Oyola, Y.","Zhu, X.","Jiang, D.","Dai, S."],"bibdata":{"bibtype":"article","type":"article","title":"Effect of alkyl and aryl substitutions on 1,2,4-triazolium-based ionic liquids for carbon dioxide separation and capture.","volume":"3","copyright":"All rights reserved","issn":"2046-2069","doi":"10.1039/c2ra22646d","abstract":"A series of 1,2,4-triazolium-based ionic liqs. were synthesized and evaluated for their use in supported ionic liq. membrane-based CO2 sepn. Properties of these triazolium-based compds. proved sensitive to isomeric substitutions, e.g., iso-Pr and Pr groups, and ortho and para substitutions in the aryl deriv. compds. While phys. properties (e.g., viscosity) did not vary significantly among structural isomers, CO2 permeability, selectivity, and soly. exhibited significant changes allowing for development of task-specific triazolium-based ionic liqs. for sepn. applications. COSMO-therm studies, done to better understand ionic liqs., demonstrated a strong correlation between exptl. and computational values for alkyl-bearing ionic liqs. Thus, 1,2,4-triazolium-based liqs. comprise a class of compds. offering unique opportunities to examine how structural changes affect physicochem. properties necessary to continuously develop ionic liqs. with enhanced adsorption capacity and sepn. selectivity. [on SciFinder(R)]","journal":"RSC Advances","author":[{"propositions":[],"lastnames":["Hillesheim"],"firstnames":["Patrick","C."],"suffixes":[]},{"propositions":[],"lastnames":["Singh"],"firstnames":["Joseph","A."],"suffixes":[]},{"propositions":[],"lastnames":["Mahurin"],"firstnames":["Shannon","M."],"suffixes":[]},{"propositions":[],"lastnames":["Fulvio"],"firstnames":["Pasquale","F."],"suffixes":[]},{"propositions":[],"lastnames":["Oyola"],"firstnames":["Yatsandra"],"suffixes":[]},{"propositions":[],"lastnames":["Zhu"],"firstnames":["Xiang"],"suffixes":[]},{"propositions":[],"lastnames":["Jiang"],"firstnames":["De-en"],"suffixes":[]},{"propositions":[],"lastnames":["Dai"],"firstnames":["Sheng."],"suffixes":[]}],"year":"2013","note":"Publisher: Royal Society of Chemistry","pages":"3981–3989","url_paper":"https://api.zotero.org/users/5598735/publications/items/63RDWVXT/file/view","bibtex":"@article{hillesheim_effect_2013,\n\ttitle = {Effect of alkyl and aryl substitutions on 1,2,4-triazolium-based ionic liquids for carbon dioxide separation and capture.},\n\tvolume = {3},\n\tcopyright = {All rights reserved},\n\tissn = {2046-2069},\n\tdoi = {10.1039/c2ra22646d},\n\tabstract = {A series of 1,2,4-triazolium-based ionic liqs. were synthesized and evaluated for their use in supported ionic liq. membrane-based CO2 sepn. Properties of these triazolium-based compds. proved sensitive to isomeric substitutions, e.g., iso-Pr and Pr groups, and ortho and para substitutions in the aryl deriv. compds. While phys. properties (e.g., viscosity) did not vary significantly among structural isomers, CO2 permeability, selectivity, and soly. exhibited significant changes allowing for development of task-specific triazolium-based ionic liqs. for sepn. applications. COSMO-therm studies, done to better understand ionic liqs., demonstrated a strong correlation between exptl. and computational values for alkyl-bearing ionic liqs. Thus, 1,2,4-triazolium-based liqs. comprise a class of compds. offering unique opportunities to examine how structural changes affect physicochem. properties necessary to continuously develop ionic liqs. with enhanced adsorption capacity and sepn. selectivity. [on SciFinder(R)]},\n\tjournal = {RSC Advances},\n\tauthor = {Hillesheim, Patrick C. and Singh, Joseph A. and Mahurin, Shannon M. and Fulvio, Pasquale F. and Oyola, Yatsandra and Zhu, Xiang and Jiang, De-en and Dai, Sheng.},\n\tyear = {2013},\n\tnote = {Publisher: Royal Society of Chemistry},\n\tpages = {3981--3989},\n\turl_paper={https://api.zotero.org/users/5598735/publications/items/63RDWVXT/file/view}\n}\n\n\n\n","author_short":["Hillesheim, P. C.","Singh, J. A.","Mahurin, S. M.","Fulvio, P. F.","Oyola, Y.","Zhu, X.","Jiang, D.","Dai, S."],"key":"hillesheim_effect_2013","id":"hillesheim_effect_2013","bibbaseid":"hillesheim-singh-mahurin-fulvio-oyola-zhu-jiang-dai-effectofalkylandarylsubstitutionson124triazoliumbasedionicliquidsforcarbondioxideseparationandcapture-2013","role":"author","urls":{" paper":"https://api.zotero.org/users/5598735/publications/items/63RDWVXT/file/view"},"metadata":{"authorlinks":{}}},"bibtype":"article","biburl":"https://bibbase.org/zotero-mypublications/SentientToast","dataSources":["ehszj4YRysFoDwA2R"],"keywords":[],"search_terms":["effect","alkyl","aryl","substitutions","triazolium","based","ionic","liquids","carbon","dioxide","separation","capture","hillesheim","singh","mahurin","fulvio","oyola","zhu","jiang","dai"],"title":"Effect of alkyl and aryl substitutions on 1,2,4-triazolium-based ionic liquids for carbon dioxide separation and capture.","year":2013}