Substrate Water 18O Exchange Kinetics in the S2 State of Photosystem II. Hillier, W., Messinger, J., & Wydrzynski, T. In Photosynthesis: Mechanisms and Effects: Volume I–V: Proceedings of the XIth International Congress on Photosynthesis, Budapest, Hungary, August 17–22, 1998, pages 1307–1310. Springer Netherlands, Dordrecht, 1998.
Paper doi abstract bibtex The oxidation of water into molecular oxygen during photosynthesis is catalyzed by a subdomain of photosystem II (PSII) termed the water oxidizing complex (WOC). Contained within the WOC is a redox-active Mn/tyrosine motif which forms, in part, the catalytic site. Fundamental to the water oxidation mechanism is the periodicity of four in the release of O2 upon flash illumination. This unique behavior can readily be explained by a phenomenological model in which the WOC cycles through five intermediate states called the S-states (or Sn where n=0-4). Upon attaining the metastable S4 state, O2 is released, the S0 state is regenerated, and the S-state cycle begins again [1].
@incollection{hillier_substrate_1998,
address = {Dordrecht},
title = {Substrate {Water} {18O} {Exchange} {Kinetics} in the {S2} {State} of {Photosystem} {II}},
isbn = {978-94-011-3953-3},
url = {https://doi.org/10.1007/978-94-011-3953-3_308},
abstract = {The oxidation of water into molecular oxygen during photosynthesis is catalyzed by a subdomain of photosystem II (PSII) termed the water oxidizing complex (WOC). Contained within the WOC is a redox-active Mn/tyrosine motif which forms, in part, the catalytic site. Fundamental to the water oxidation mechanism is the periodicity of four in the release of O2 upon flash illumination. This unique behavior can readily be explained by a phenomenological model in which the WOC cycles through five intermediate states called the S-states (or Sn where n=0-4). Upon attaining the metastable S4 state, O2 is released, the S0 state is regenerated, and the S-state cycle begins again [1].},
language = {en},
urldate = {2024-11-29},
booktitle = {Photosynthesis: {Mechanisms} and {Effects}: {Volume} {I}–{V}: {Proceedings} of the {XIth} {International} {Congress} on {Photosynthesis}, {Budapest}, {Hungary}, {August} 17–22, 1998},
publisher = {Springer Netherlands},
author = {Hillier, Warwick and Messinger, Johannes and Wydrzynski, Tom},
editor = {Garab, G.},
year = {1998},
doi = {10.1007/978-94-011-3953-3_308},
pages = {1307--1310},
}
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