Paper  abstract   bibtex   

@article{Hollenstein2007,
	title = {Rovibronic photoionization dynamics of ammonia isotopomers},
	volume = {105},
	issn = {0026-8976},
	url = {http://www.informaworld.com/10.1080/00268970701429889},
	abstract = {PFI-ZEKE photoelectron spectra of the {\textless}a name="ILM0001"{\textgreater}�{\textless}/a{\textgreater} $^{\textrm{2}}$\textit{B}$_{\textrm{1}}$
(\textit{v}$_{\textrm{2}}$$^{\textrm{+=3}}$) cationic vibrational state and
photoionization spectra of autoionizing Rydberg series converging
on the +=1 ionization threshold of the mixed isotopomers of ammonia,
NH$_{\textrm{2}}$D and ND$_{\textrm{2}}$H, are reported for the first time.
The observed rovibronic photoionization propensities and the quantum
defects of the Rydberg series indicate that the photoelectron is
ejected as a superposition of even (s and d) partial-wave components
in agreement with predictions from the orbital-ionization model [S.
Willitsch and F. Merkt, Int. J. Mass Spectrom. \textbf{245,} 14 (2005)].
The ionization energies of the \textit{v}$_{\textrm{2}}$$^{\textrm{+=3}}$
thresholds of NH$_{\textrm{2}}$D and ND$_{\textrm{2}}$H were determined
to be \textit{IE}\ /\ \textit{hc}\ =\ 84\ 792.9(6)
cm$^{\textrm{-\ 1}}$ and \textit{IE}\ /\ \textit{hc}\ =\ 84\ 595.9(8)
cm$^{\textrm{-\ 1}}$, respectively, and rotational constants for
the {\textless}a name="ILM0002"{\textgreater}�{\textless}/a{\textgreater}\ =\ 3 states of both isotopomers
are derived.},
	number = {11},
	journal = {Molecular Physics},
	author = {Hollenstein, U and Merkt, F and Meyer, L and Seiler, R and Softley, T P and Willitsch, S},
	year = {2007},
	note = {Publisher: Taylor \& Francis},
	keywords = {\#nosource},
	pages = {1711--1722},
}