@article{hudec_trisdichloropropylphosphate_1981,
	title = {Tris(dichloropropyl)phosphate, a mutagenic flame retardant: frequent cocurrence in human seminal plasma.},
	volume = {211},
	issn = {0036-8075},
	url = {http://www.sciencemag.org/content/211/4485/951.abstract},
	doi = {10.1126/science.7466368},
	abstract = {Negative-chemical-ionization mass spectral screening of extracts of human seminal plasma has revealed a presence of a Cl7 ion cluster at a mass-to-charge ratio (m/z) of 463 in a significant number of the samples examined (34 out of 123). Experiments with different gases used to generate the negative-chemical-ionization plasma indicated that the ion at m/z 463 was a chloride adduca of a Cl6 molecule with a mass of 428 daltons. Negative-chemical-ionization mass measurement with ions from the iodoform mass spectrum used as reference peaks gave a mass of 427.882 daltons; C9H15PCl6 has a molecular weight of 427.883. Extraction of polyurethane foam with toluene produced an extract that consistently gave a negative-chemical-ionization spectrum containing an intense Cl7ion at m/z463. The component producing ion was isolated, and its proton nuclear magnetic resonance spectrum confirmed that it was tris (1,3-dichloro-2-propyl)phosphate, a mutagenic flame retardant. The negative-chemical-ionization screening evidence suggests that this flame retardant or its isomer tris(2,3-dichloro-l-propyl)phosphate, or both, are absorbved into the body from formulations in which they are used as flame retardants. Remedial action seems indicated to reduce human exposure to these compunds.},
	number = {4485},
	journal = {Science},
	author = {Hudec, T and Thean, J and Kuehl, D and Dougherty, R.},
	month = feb,
	year = {1981},
	keywords = {Flame retardants, ffr, hum},
	pages = {951--952},
}

{"_id":"PCvDxFAKBv6b83NF8","bibbaseid":"hudec-thean-kuehl-dougherty-trisdichloropropylphosphateamutagenicflameretardantfrequentcocurrenceinhumanseminalplasma-1981","author_short":["Hudec, T","Thean, J","Kuehl, D","Dougherty, R."],"bibdata":{"bibtype":"article","type":"article","title":"Tris(dichloropropyl)phosphate, a mutagenic flame retardant: frequent cocurrence in human seminal plasma.","volume":"211","issn":"0036-8075","url":"http://www.sciencemag.org/content/211/4485/951.abstract","doi":"10.1126/science.7466368","abstract":"Negative-chemical-ionization mass spectral screening of extracts of human seminal plasma has revealed a presence of a Cl7 ion cluster at a mass-to-charge ratio (m/z) of 463 in a significant number of the samples examined (34 out of 123). Experiments with different gases used to generate the negative-chemical-ionization plasma indicated that the ion at m/z 463 was a chloride adduca of a Cl6 molecule with a mass of 428 daltons. Negative-chemical-ionization mass measurement with ions from the iodoform mass spectrum used as reference peaks gave a mass of 427.882 daltons; C9H15PCl6 has a molecular weight of 427.883. Extraction of polyurethane foam with toluene produced an extract that consistently gave a negative-chemical-ionization spectrum containing an intense Cl7ion at m/z463. The component producing ion was isolated, and its proton nuclear magnetic resonance spectrum confirmed that it was tris (1,3-dichloro-2-propyl)phosphate, a mutagenic flame retardant. The negative-chemical-ionization screening evidence suggests that this flame retardant or its isomer tris(2,3-dichloro-l-propyl)phosphate, or both, are absorbved into the body from formulations in which they are used as flame retardants. Remedial action seems indicated to reduce human exposure to these compunds.","number":"4485","journal":"Science","author":[{"propositions":[],"lastnames":["Hudec"],"firstnames":["T"],"suffixes":[]},{"propositions":[],"lastnames":["Thean"],"firstnames":["J"],"suffixes":[]},{"propositions":[],"lastnames":["Kuehl"],"firstnames":["D"],"suffixes":[]},{"propositions":[],"lastnames":["Dougherty"],"firstnames":["R."],"suffixes":[]}],"month":"February","year":"1981","keywords":"Flame retardants, ffr, hum","pages":"951–952","bibtex":"@article{hudec_trisdichloropropylphosphate_1981,\n\ttitle = {Tris(dichloropropyl)phosphate, a mutagenic flame retardant: frequent cocurrence in human seminal plasma.},\n\tvolume = {211},\n\tissn = {0036-8075},\n\turl = {http://www.sciencemag.org/content/211/4485/951.abstract},\n\tdoi = {10.1126/science.7466368},\n\tabstract = {Negative-chemical-ionization mass spectral screening of extracts of human seminal plasma has revealed a presence of a Cl7 ion cluster at a mass-to-charge ratio (m/z) of 463 in a significant number of the samples examined (34 out of 123). Experiments with different gases used to generate the negative-chemical-ionization plasma indicated that the ion at m/z 463 was a chloride adduca of a Cl6 molecule with a mass of 428 daltons. Negative-chemical-ionization mass measurement with ions from the iodoform mass spectrum used as reference peaks gave a mass of 427.882 daltons; C9H15PCl6 has a molecular weight of 427.883. Extraction of polyurethane foam with toluene produced an extract that consistently gave a negative-chemical-ionization spectrum containing an intense Cl7ion at m/z463. The component producing ion was isolated, and its proton nuclear magnetic resonance spectrum confirmed that it was tris (1,3-dichloro-2-propyl)phosphate, a mutagenic flame retardant. The negative-chemical-ionization screening evidence suggests that this flame retardant or its isomer tris(2,3-dichloro-l-propyl)phosphate, or both, are absorbved into the body from formulations in which they are used as flame retardants. Remedial action seems indicated to reduce human exposure to these compunds.},\n\tnumber = {4485},\n\tjournal = {Science},\n\tauthor = {Hudec, T and Thean, J and Kuehl, D and Dougherty, R.},\n\tmonth = feb,\n\tyear = {1981},\n\tkeywords = {Flame retardants, ffr, hum},\n\tpages = {951--952},\n}\n\n\n\n","author_short":["Hudec, T","Thean, J","Kuehl, D","Dougherty, R."],"key":"hudec_trisdichloropropylphosphate_1981","id":"hudec_trisdichloropropylphosphate_1981","bibbaseid":"hudec-thean-kuehl-dougherty-trisdichloropropylphosphateamutagenicflameretardantfrequentcocurrenceinhumanseminalplasma-1981","role":"author","urls":{"Paper":"http://www.sciencemag.org/content/211/4485/951.abstract"},"keyword":["Flame retardants","ffr","hum"],"metadata":{"authorlinks":{}},"html":""},"bibtype":"article","biburl":"http://bibbase.org/zotero/mdedeo","dataSources":["SSfxPwd7XbkRtnZ9f"],"keywords":["flame retardants","ffr","hum"],"search_terms":["tris","dichloropropyl","phosphate","mutagenic","flame","retardant","frequent","cocurrence","human","seminal","plasma","hudec","thean","kuehl","dougherty"],"title":"Tris(dichloropropyl)phosphate, a mutagenic flame retardant: frequent cocurrence in human seminal plasma.","year":1981}