@article{Iglesias-Juez2004a,
abstract = {A series of monometallic Pd and bimetallic Pd-Cr catalysts supported on CeOx/Al2O3 (CA) and (Ce, Zr)O x/Al2O3 (CZA) materials have been characterized using a combination of X-ray diffraction (XRD), electron microscopy, and Raman spectroscopy, and employing electron paramagnetic resonance and in situ diffuse reflectance Fourier transform infrared and X-ray near-edge structure spectroscopies to analyze the redox and chemical processes taking place under light-off conditions in a gaseous, stoichiometric mixture containing CO, NO, and O2. The catalytic behavior of these mono and bimetallic systems was strongly affected by the nature of the cerium-containing promoter. The Pd-ceria interface appeared significantly more active than Pd-ceria/zirconia in both CO oxidation and NO reduction processes under stoichiometric conditions. This factor seems to dominate the differential behavior of Pd monometallic systems. In the case of Pd-Cr bimetallic systems, an additional strong influence of the base metal on the oxidation state of Pd appears of importance in explaining the catalytic behavior of the samples. For the CeOx/Al2O3 supported catalyst, the formation of Pd(0) at lower temperatures leads to an initial enhancement in activity, while formation of a Pd-Cr alloy above 473K suppressed full NO conversion at high temperatures. These effects were absent in the (Ce, Zr)O x/Al2O3 supported system. © 2003 Elsevier B.V. All rights reserved.},
address = {Inst. Catalisis y Petroleoquimica, CSIC, Campus Cantoblanco, 28049 Madrid, Spain},
annote = {Cited By (since 1996): 12

        
Export Date: 15 January 2013

        
Source: Scopus

        
CODEN: ACAGE

        
doi: 10.1016/j.apcata.2003.09.020

        
Language of Original Document: English

        
Correspondence Address: Fern\'{a}ndez-Garc\'{\i}a, M.; Inst. Catalisis y Petroleoquimica, CSIC, Campus Cantoblanco, 28049 Madrid, Spain; email: m.fernandez@icp.csic.es

        
References: Lox, E.S.J., Engler, B.H., (1999) Environmental Catalysis, p. 1. , G. Ertl, H. Kn\"{o}zinger, J. Weitkamp (Eds.), Wiley, New York; 
Trovarelli, A., (2002) Catalysis by Ceria and Related Materials, , Imperial College Press, London; 
Fern\'{a}ndez-Garc\'{\i}a, M., Mart\'{\i}nez-Arias, A., Salamanca, L.N., Coronado, J.M., Anderson, J.A., Conesa, J.C., Soria, J., (1999) J. Catal., 187, p. 474; 
Luo, M.F., Zheng, X.M., (1999) Appl. Catal. A, 189, p. 15; 
Bera, P., Jayaram, V., Subbana, G.N., Hegde, M.S., (2000) J. Catal., 196, p. 293; 
Fern\'{a}ndez-Garc\'{\i}a, M., Mart\'{\i}nez-Arias, A., Iglesias-Juez, A., Hungr\'{\i}a, A.B., Anderson, J.A., Conesa, J.C., Soria, J., (2001) Appl. Catal. B, 31, p. 39; 
Priolkar, K.R., Bera, P., Saroda, P.R., Hegde, M.S., Emura, S., Kumashiro, R., Lalla, N.P., (2002) Chem. Mater., 14, p. 2120; 
Fern\'{a}ndez-Garc\'{\i}a, M., Mart\'{\i}nez-Arias, A., Belver, C., Anderson, J.A., Conesa, J.C., Soria, J., (2000) J. Catal., 190, p. 387; 
Holles, J.H., Davis, J.R., Murray, T.M., Howe, J.M., (2000) J. Catal., 195, p. 193; 
Mart\'{\i}nez-Arias, A., Fern\'{a}ndez-Garc\'{\i}a, M., Iglesias-Juez, A., Hungr\'{\i}a, A.B., Anderson, J.A., Conesa, J.C., Soria, J., (2001) Appl. Catal. B, 31, p. 51; 
Trovarelli, A., (1996) Catal. Rev. Sci. Eng., 38, p. 97; 
Ka\v{s}par, J., Fornasiero, P., Graziani, M., (1999) Catal. Today, 50, p. 351; 
Fern\'{a}ndez-Garc\'{\i}a, M., Mart\'{\i}nez-Arias, A., Iglesias-Juez, A., Belver, C., Hungr\'{\i}a, A.B., Conesa, J.C., Soria, J., (2000) J. Catal., 194, p. 385; 
Fern\'{a}ndez-Garc\'{\i}a, M., Mart\'{\i}nez-Arias, A., Iglesias-Juez, A., Belver, C., Hungr\'{\i}a, A.B., Conesa, J.C., Soria, J., (2002) Phys. Chem. Chem. Phys., 4, p. 2473; 
Van Yperen, R., Lindner, D., Mubmann, L., Lox, E.S., Kreuzer, T., (1998) Stud. Surf. Sci. Catal., 116, p. 51; 
Hu, Z., Wan, C.Z., Lui, Y.K., Dettling, J., Steger, J.J., (1996) Catal. Today, 30, p. 83; 
Skoglundh, M., Johansson, H., L\"{o}wendahl, L., Jansson, K., Dahl, L., Hirschauer, B., (1996) Appl. Catal. B, 7, p. 299; 
El Hamdaoui, A., Bergeret, G., Massadier, J., Primet, M., Renouprez, A.J., (1994) J. Catal., 148, p. 47; 
Coq, B., Figueras, F., (2001) J. Mol. Catal. A, 173, p. 117; 
Fern\'{a}ndez-Garc\'{\i}a, M., Mart\'{\i}nez-Arias, A., Iglesias-Juez, A., Hungr\'{\i}a, A.B., Anderson, J.A., Conesa, J.C., Soria, J., (2003) J. Catal., 214, p. 220; 
Mart\'{\i}nez-Arias, A., Fern\'{a}ndez-Garc\'{\i}a, M., Ballesteros, V., Salamanca, L.N., Otero, C., Conesa, J.C., Soria, J., (1999) Langmuir, 15, p. 4796; 
Fern\'{a}ndez-Garc\'{\i}a, M., M\'{a}rquez-Alvarez, C., Haller, G.L., (1995) J. Phys. Chem., 99, p. 12565; 
M\'{a}rquez-Alvarez, C., Rodr\'{\i}guez-Ramos, I., Guerrero-Ruiz, A., Haller, G.L., Fern\'{a}ndez-Garc\'{\i}a, M., (1997) J. Am. Chem. Soc., 119, p. 2905; 
Fern\'{a}ndez-Garc\'{\i}a, M., (2002) Catal. Rev. Sci. Eng., 44, p. 59; 
Malinowsky, E.R., (1991) Factor Analysis in Chemistry, , Wiley, New York; 
Weckhuysen, B.M., Wachs, I.E., (1997) J. Phys. Chem. B, 101, p. 2793; 
Grzybowska, B., Sloczynski, J., Grabowski, R., Wcislo, K., Kozlowska, A., Stoch, J., Zielinski, J., (1998) J. Catal., 178, p. 687; 
Cherian, M., Rao, M.S., Hirt, A.M., Wachs, I.E., Deo, G., (2002) J. Catal., 211, p. 482; 
Mcbridge, J.R., Kass, K.C., Weber, W.H., (1991) Phys. Rev. B, 44, p. 5016; 
Wang, D., Cleway, J.D., Flanegan, T.B., (2000) J. Alloys Compd., 325, p. 151; 
Lee, Y.S., Lim, K.Y., Whang, C.N., Jeon, Y., (2000) Appl. Phys. A, 70, p. 59; 
Sobczak, J.W., Sobczak, E., Kosinki, A., Bilinski, A., (2001) J. Alloys Compd., 328, p. 132; 
Fern\'{a}ndez-Garc\'{\i}a, M., Anderson, J.A., Haller, G.L., (1996) J. Phys. Chem., 100, p. 16247; 
Massalki, T.B., (1993) Binary Alloy Phase Diagram, Second Ed., 1. , ASM International, USA; 
Ellison, A., Diakun, G., Worthington, P., (1998) J. Mol. Catal., 46, p. 131; 
Pykavy, M., Staemmler, V., Seiferth, O., Freund, H.J., (2001) Surf. Sci., 479, p. 11. , and references therein; 
Xu, X., Goodman, D.W., (1993) J. Phys. Chem., 97, p. 7711; 
Bensalem, A., Muller, J.C., Tessier, D., Bozon-Verduraz, F., (1996) J. Chem. Soc., Faraday Trans., 92, p. 3233; 
Xu, X., Chen, P., Goodman, D.W., (1994) J. Phys. Chem., 98, p. 9242; 
Honkala, K., Pirila, P., Laasonen, K., (2001) Surf. Sci., 489, p. 72. , and references therein; 
Anderson, J.A., M\'{a}rquez-Alvarez, C., L\'{o}pez-Mu\~{n}oz, M.J., Rodr\'{\i}guez-Ramos, I., Guerrero-Ruiz, A., (1997) Appl. Catal. B, 14, p. 189; 
Solymosi, F., Bansagi, T., (1995) J. Catal., 156, p. 75. , and references therein; 
Rask\'{o}, J., Solymosi, F., (1981) J. Catal., 71, p. 219; 
Kameota, S., Chafit, T., Ukisu, Y., Miyadera, T., (1998) Catal. Lett., 55, p. 211; 
Rask\'{o}, J., Solymosi, F., (1984) J. Chem. Soc., Faraday Trans. I, 80, p. 1841; 
Mart\'{\i}nez-Arias, A., Fern\'{a}ndez-Garc\'{\i}a, M., Salamanca, L.N., Conesa, J.C., Soria, J., (2000) J. Phys. Chem. B, 104, p. 4038; 
Cordishi, D., Campa, M.C., Indovina, V., Occhiozzi, M., (1994) J. Chem. Soc., Faraday Trans., 90, p. 207; 
Zhu, Z., Hartmann, M., Maes, E.M., Czernuszevich, R.S., Kevan, L., (2000) J. Phys. Chem. B, 104, p. 4690; 
Mart\'{\i}nez-Arias, A., Fern\'{a}ndez-Garc\'{\i}a, M., Belver, C., Conesa, J.C., Soria, J., (2000) Catal. Lett., 65, p. 197; 
Mart\'{\i}nez-Arias, A., Hungr\'{\i}a, A.B., Fern\'{a}ndez-Garc\'{\i}a, M., Iglesias-Juez, A., Anderson, J.A., Conesa, J.C., J. Catal., , in press; 
Fern\'{a}ndez-Garc\'{\i}a, M., Mart\'{\i}nez-Arias, A., Iglesias-Juez, A., Hungr\'{\i}a, A.B., Anderson, J.A., Conesa, J.C., Soria, J., doi: 10.1016/S0021-9517(03)00277-XHoffman, J., Meusel, I., Hartmann, J., Libuda, J., Freund, H.-J., (2001) J. Catal., 204, p. 378; 
Tarasov, A.L., Przheval'skaya, L.K., Shevts, V.A., Kazanskii, V.B., (1989) Kinet. Catal., 29, p. 1020; 
Boaro, M., Leitenburg, C., Dolcetti, G., Trovarelli, A., (2000) J. Catal., 193, p. 338},
author = {Iglesias-Juez, A and Mart\'{\i}nez-Arias, A and Hungr\'{\i}a, A B and Anderson, J A and Conesa, J C and Soria, J and Fern\'{a}ndez-Garc\'{\i}a, M},
issn = {0926860X (ISSN)},
journal = {Applied Catalysis A: General},
keywords = {Bimetals,Catalysis,Emulsions,Gas emissions,Infrared spectroscopy,Materials science,Palladium,Principal component analysis,Raman spectroscopy,Synthesis (chemical),Three-way catalysts,X ray diffraction analysis,X-ray diffraction,X-ray near-edge structures,XANES},
number = {2},
pages = {207--220},
title = {{Influence of the nature of the Ce-promoter on the behavior of Pd and Pd-Cr TWC systems}},
url = {https://www.scopus.com/inward/record.url?eid=2-s2.0-1242287674&partnerID=40&md5=9e37407171058208414cec96cfd7aaf2},
volume = {259},
year = {2004}
}

{"_id":"HTyb774qjtrgozJjg","bibbaseid":"iglesiasjuez-martnezarias-hungra-anderson-conesa-soria-fernndezgarca-influenceofthenatureofthecepromoteronthebehaviorofpdandpdcrtwcsystems-2004","downloads":0,"creationDate":"2015-12-06T18:10:15.367Z","title":"Influence of the nature of the Ce-promoter on the behavior of Pd and Pd-Cr TWC systems","author_short":["Iglesias-Juez, A","Martínez-Arias, A","Hungría, A B","Anderson, J A","Conesa, J C","Soria, J","Fernández-García, M"],"year":2004,"bibtype":"article","biburl":"www2.uca.es/dept/cmat_qinor/nanomat/people/Hungria.bib","bibdata":{"bibtype":"article","type":"article","abstract":"A series of monometallic Pd and bimetallic Pd-Cr catalysts supported on CeOx/Al2O3 (CA) and (Ce, Zr)O x/Al2O3 (CZA) materials have been characterized using a combination of X-ray diffraction (XRD), electron microscopy, and Raman spectroscopy, and employing electron paramagnetic resonance and in situ diffuse reflectance Fourier transform infrared and X-ray near-edge structure spectroscopies to analyze the redox and chemical processes taking place under light-off conditions in a gaseous, stoichiometric mixture containing CO, NO, and O2. The catalytic behavior of these mono and bimetallic systems was strongly affected by the nature of the cerium-containing promoter. The Pd-ceria interface appeared significantly more active than Pd-ceria/zirconia in both CO oxidation and NO reduction processes under stoichiometric conditions. This factor seems to dominate the differential behavior of Pd monometallic systems. In the case of Pd-Cr bimetallic systems, an additional strong influence of the base metal on the oxidation state of Pd appears of importance in explaining the catalytic behavior of the samples. For the CeOx/Al2O3 supported catalyst, the formation of Pd(0) at lower temperatures leads to an initial enhancement in activity, while formation of a Pd-Cr alloy above 473K suppressed full NO conversion at high temperatures. These effects were absent in the (Ce, Zr)O x/Al2O3 supported system. © 2003 Elsevier B.V. All rights reserved.","address":"Inst. Catalisis y Petroleoquimica, CSIC, Campus Cantoblanco, 28049 Madrid, Spain","annote":"Cited By (since 1996): 12 Export Date: 15 January 2013 Source: Scopus CODEN: ACAGE doi: 10.1016/j.apcata.2003.09.020 Language of Original Document: English Correspondence Address: Fernández-García, M.; Inst. Catalisis y Petroleoquimica, CSIC, Campus Cantoblanco, 28049 Madrid, Spain; email: m.fernandez@icp.csic.es References: Lox, E.S.J., Engler, B.H., (1999) Environmental Catalysis, p. 1. , G. Ertl, H. Knözinger, J. Weitkamp (Eds.), Wiley, New York; Trovarelli, A., (2002) Catalysis by Ceria and Related Materials, , Imperial College Press, London; Fernández-García, M., Martínez-Arias, A., Salamanca, L.N., Coronado, J.M., Anderson, J.A., Conesa, J.C., Soria, J., (1999) J. Catal., 187, p. 474; Luo, M.F., Zheng, X.M., (1999) Appl. Catal. A, 189, p. 15; Bera, P., Jayaram, V., Subbana, G.N., Hegde, M.S., (2000) J. Catal., 196, p. 293; Fernández-García, M., Martínez-Arias, A., Iglesias-Juez, A., Hungría, A.B., Anderson, J.A., Conesa, J.C., Soria, J., (2001) Appl. Catal. B, 31, p. 39; Priolkar, K.R., Bera, P., Saroda, P.R., Hegde, M.S., Emura, S., Kumashiro, R., Lalla, N.P., (2002) Chem. Mater., 14, p. 2120; Fernández-García, M., Martínez-Arias, A., Belver, C., Anderson, J.A., Conesa, J.C., Soria, J., (2000) J. Catal., 190, p. 387; Holles, J.H., Davis, J.R., Murray, T.M., Howe, J.M., (2000) J. Catal., 195, p. 193; Martínez-Arias, A., Fernández-García, M., Iglesias-Juez, A., Hungría, A.B., Anderson, J.A., Conesa, J.C., Soria, J., (2001) Appl. Catal. B, 31, p. 51; Trovarelli, A., (1996) Catal. Rev. Sci. Eng., 38, p. 97; Kašpar, J., Fornasiero, P., Graziani, M., (1999) Catal. Today, 50, p. 351; Fernández-García, M., Martínez-Arias, A., Iglesias-Juez, A., Belver, C., Hungría, A.B., Conesa, J.C., Soria, J., (2000) J. Catal., 194, p. 385; Fernández-García, M., Martínez-Arias, A., Iglesias-Juez, A., Belver, C., Hungría, A.B., Conesa, J.C., Soria, J., (2002) Phys. Chem. Chem. Phys., 4, p. 2473; Van Yperen, R., Lindner, D., Mubmann, L., Lox, E.S., Kreuzer, T., (1998) Stud. Surf. Sci. Catal., 116, p. 51; Hu, Z., Wan, C.Z., Lui, Y.K., Dettling, J., Steger, J.J., (1996) Catal. Today, 30, p. 83; Skoglundh, M., Johansson, H., Löwendahl, L., Jansson, K., Dahl, L., Hirschauer, B., (1996) Appl. Catal. B, 7, p. 299; El Hamdaoui, A., Bergeret, G., Massadier, J., Primet, M., Renouprez, A.J., (1994) J. Catal., 148, p. 47; Coq, B., Figueras, F., (2001) J. Mol. Catal. A, 173, p. 117; Fernández-García, M., Martínez-Arias, A., Iglesias-Juez, A., Hungría, A.B., Anderson, J.A., Conesa, J.C., Soria, J., (2003) J. Catal., 214, p. 220; Martínez-Arias, A., Fernández-García, M., Ballesteros, V., Salamanca, L.N., Otero, C., Conesa, J.C., Soria, J., (1999) Langmuir, 15, p. 4796; Fernández-García, M., Márquez-Alvarez, C., Haller, G.L., (1995) J. Phys. Chem., 99, p. 12565; Márquez-Alvarez, C., Rodríguez-Ramos, I., Guerrero-Ruiz, A., Haller, G.L., Fernández-García, M., (1997) J. Am. Chem. Soc., 119, p. 2905; Fernández-García, M., (2002) Catal. Rev. Sci. Eng., 44, p. 59; Malinowsky, E.R., (1991) Factor Analysis in Chemistry, , Wiley, New York; Weckhuysen, B.M., Wachs, I.E., (1997) J. Phys. Chem. B, 101, p. 2793; Grzybowska, B., Sloczynski, J., Grabowski, R., Wcislo, K., Kozlowska, A., Stoch, J., Zielinski, J., (1998) J. Catal., 178, p. 687; Cherian, M., Rao, M.S., Hirt, A.M., Wachs, I.E., Deo, G., (2002) J. Catal., 211, p. 482; Mcbridge, J.R., Kass, K.C., Weber, W.H., (1991) Phys. Rev. B, 44, p. 5016; Wang, D., Cleway, J.D., Flanegan, T.B., (2000) J. Alloys Compd., 325, p. 151; Lee, Y.S., Lim, K.Y., Whang, C.N., Jeon, Y., (2000) Appl. Phys. A, 70, p. 59; Sobczak, J.W., Sobczak, E., Kosinki, A., Bilinski, A., (2001) J. Alloys Compd., 328, p. 132; Fernández-García, M., Anderson, J.A., Haller, G.L., (1996) J. Phys. Chem., 100, p. 16247; Massalki, T.B., (1993) Binary Alloy Phase Diagram, Second Ed., 1. , ASM International, USA; Ellison, A., Diakun, G., Worthington, P., (1998) J. Mol. Catal., 46, p. 131; Pykavy, M., Staemmler, V., Seiferth, O., Freund, H.J., (2001) Surf. Sci., 479, p. 11. , and references therein; Xu, X., Goodman, D.W., (1993) J. Phys. Chem., 97, p. 7711; Bensalem, A., Muller, J.C., Tessier, D., Bozon-Verduraz, F., (1996) J. Chem. Soc., Faraday Trans., 92, p. 3233; Xu, X., Chen, P., Goodman, D.W., (1994) J. Phys. Chem., 98, p. 9242; Honkala, K., Pirila, P., Laasonen, K., (2001) Surf. Sci., 489, p. 72. , and references therein; Anderson, J.A., Márquez-Alvarez, C., López-Muñoz, M.J., Rodríguez-Ramos, I., Guerrero-Ruiz, A., (1997) Appl. Catal. B, 14, p. 189; Solymosi, F., Bansagi, T., (1995) J. Catal., 156, p. 75. , and references therein; Raskó, J., Solymosi, F., (1981) J. Catal., 71, p. 219; Kameota, S., Chafit, T., Ukisu, Y., Miyadera, T., (1998) Catal. Lett., 55, p. 211; Raskó, J., Solymosi, F., (1984) J. Chem. Soc., Faraday Trans. I, 80, p. 1841; Martínez-Arias, A., Fernández-García, M., Salamanca, L.N., Conesa, J.C., Soria, J., (2000) J. Phys. Chem. B, 104, p. 4038; Cordishi, D., Campa, M.C., Indovina, V., Occhiozzi, M., (1994) J. Chem. Soc., Faraday Trans., 90, p. 207; Zhu, Z., Hartmann, M., Maes, E.M., Czernuszevich, R.S., Kevan, L., (2000) J. Phys. Chem. B, 104, p. 4690; Martínez-Arias, A., Fernández-García, M., Belver, C., Conesa, J.C., Soria, J., (2000) Catal. Lett., 65, p. 197; Martínez-Arias, A., Hungría, A.B., Fernández-García, M., Iglesias-Juez, A., Anderson, J.A., Conesa, J.C., J. Catal., , in press; Fernández-García, M., Martínez-Arias, A., Iglesias-Juez, A., Hungría, A.B., Anderson, J.A., Conesa, J.C., Soria, J., doi: 10.1016/S0021-9517(03)00277-XHoffman, J., Meusel, I., Hartmann, J., Libuda, J., Freund, H.-J., (2001) J. Catal., 204, p. 378; Tarasov, A.L., Przheval'skaya, L.K., Shevts, V.A., Kazanskii, V.B., (1989) Kinet. Catal., 29, p. 1020; Boaro, M., Leitenburg, C., Dolcetti, G., Trovarelli, A., (2000) J. Catal., 193, p. 338","author":[{"propositions":[],"lastnames":["Iglesias-Juez"],"firstnames":["A"],"suffixes":[]},{"propositions":[],"lastnames":["Martínez-Arias"],"firstnames":["A"],"suffixes":[]},{"propositions":[],"lastnames":["Hungría"],"firstnames":["A","B"],"suffixes":[]},{"propositions":[],"lastnames":["Anderson"],"firstnames":["J","A"],"suffixes":[]},{"propositions":[],"lastnames":["Conesa"],"firstnames":["J","C"],"suffixes":[]},{"propositions":[],"lastnames":["Soria"],"firstnames":["J"],"suffixes":[]},{"propositions":[],"lastnames":["Fernández-García"],"firstnames":["M"],"suffixes":[]}],"issn":"0926860X (ISSN)","journal":"Applied Catalysis A: General","keywords":"Bimetals,Catalysis,Emulsions,Gas emissions,Infrared spectroscopy,Materials science,Palladium,Principal component analysis,Raman spectroscopy,Synthesis (chemical),Three-way catalysts,X ray diffraction analysis,X-ray diffraction,X-ray near-edge structures,XANES","number":"2","pages":"207–220","title":"Influence of the nature of the Ce-promoter on the behavior of Pd and Pd-Cr TWC systems","url":"https://www.scopus.com/inward/record.url?eid=2-s2.0-1242287674&partnerID=40&md5=9e37407171058208414cec96cfd7aaf2","volume":"259","year":"2004","bibtex":"@article{Iglesias-Juez2004a,\nabstract = {A series of monometallic Pd and bimetallic Pd-Cr catalysts supported on CeOx/Al2O3 (CA) and (Ce, Zr)O x/Al2O3 (CZA) materials have been characterized using a combination of X-ray diffraction (XRD), electron microscopy, and Raman spectroscopy, and employing electron paramagnetic resonance and in situ diffuse reflectance Fourier transform infrared and X-ray near-edge structure spectroscopies to analyze the redox and chemical processes taking place under light-off conditions in a gaseous, stoichiometric mixture containing CO, NO, and O2. The catalytic behavior of these mono and bimetallic systems was strongly affected by the nature of the cerium-containing promoter. The Pd-ceria interface appeared significantly more active than Pd-ceria/zirconia in both CO oxidation and NO reduction processes under stoichiometric conditions. This factor seems to dominate the differential behavior of Pd monometallic systems. In the case of Pd-Cr bimetallic systems, an additional strong influence of the base metal on the oxidation state of Pd appears of importance in explaining the catalytic behavior of the samples. For the CeOx/Al2O3 supported catalyst, the formation of Pd(0) at lower temperatures leads to an initial enhancement in activity, while formation of a Pd-Cr alloy above 473K suppressed full NO conversion at high temperatures. These effects were absent in the (Ce, Zr)O x/Al2O3 supported system. © 2003 Elsevier B.V. All rights reserved.},\naddress = {Inst. Catalisis y Petroleoquimica, CSIC, Campus Cantoblanco, 28049 Madrid, Spain},\nannote = {Cited By (since 1996): 12\n\n \nExport Date: 15 January 2013\n\n \nSource: Scopus\n\n \nCODEN: ACAGE\n\n \ndoi: 10.1016/j.apcata.2003.09.020\n\n \nLanguage of Original Document: English\n\n \nCorrespondence Address: Fern\\'{a}ndez-Garc\\'{\\i}a, M.; Inst. Catalisis y Petroleoquimica, CSIC, Campus Cantoblanco, 28049 Madrid, Spain; email: m.fernandez@icp.csic.es\n\n \nReferences: Lox, E.S.J., Engler, B.H., (1999) Environmental Catalysis, p. 1. , G. Ertl, H. Kn\\\"{o}zinger, J. Weitkamp (Eds.), Wiley, New York; \nTrovarelli, A., (2002) Catalysis by Ceria and Related Materials, , Imperial College Press, London; \nFern\\'{a}ndez-Garc\\'{\\i}a, M., Mart\\'{\\i}nez-Arias, A., Salamanca, L.N., Coronado, J.M., Anderson, J.A., Conesa, J.C., Soria, J., (1999) J. Catal., 187, p. 474; \nLuo, M.F., Zheng, X.M., (1999) Appl. Catal. A, 189, p. 15; \nBera, P., Jayaram, V., Subbana, G.N., Hegde, M.S., (2000) J. 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Catal., 193, p. 338},\nauthor = {Iglesias-Juez, A and Mart\\'{\\i}nez-Arias, A and Hungr\\'{\\i}a, A B and Anderson, J A and Conesa, J C and Soria, J and Fern\\'{a}ndez-Garc\\'{\\i}a, M},\nissn = {0926860X (ISSN)},\njournal = {Applied Catalysis A: General},\nkeywords = {Bimetals,Catalysis,Emulsions,Gas emissions,Infrared spectroscopy,Materials science,Palladium,Principal component analysis,Raman spectroscopy,Synthesis (chemical),Three-way catalysts,X ray diffraction analysis,X-ray diffraction,X-ray near-edge structures,XANES},\nnumber = {2},\npages = {207--220},\ntitle = {{Influence of the nature of the Ce-promoter on the behavior of Pd and Pd-Cr TWC systems}},\nurl = {https://www.scopus.com/inward/record.url?eid=2-s2.0-1242287674&partnerID=40&md5=9e37407171058208414cec96cfd7aaf2},\nvolume = {259},\nyear = {2004}\n}\n","author_short":["Iglesias-Juez, A","Martínez-Arias, A","Hungría, A B","Anderson, J A","Conesa, J C","Soria, J","Fernández-García, M"],"key":"Iglesias-Juez2004a","id":"Iglesias-Juez2004a","bibbaseid":"iglesiasjuez-martnezarias-hungra-anderson-conesa-soria-fernndezgarca-influenceofthenatureofthecepromoteronthebehaviorofpdandpdcrtwcsystems-2004","role":"author","urls":{"Paper":"https://www.scopus.com/inward/record.url?eid=2-s2.0-1242287674&partnerID=40&md5=9e37407171058208414cec96cfd7aaf2"},"keyword":["Bimetals","Catalysis","Emulsions","Gas emissions","Infrared spectroscopy","Materials science","Palladium","Principal component analysis","Raman spectroscopy","Synthesis (chemical)","Three-way catalysts","X ray diffraction analysis","X-ray diffraction","X-ray near-edge structures","XANES"],"downloads":0,"html":"","metadata":{"authorlinks":{}}},"search_terms":["influence","nature","promoter","behavior","twc","systems","iglesias-juez","martínez-arias","hungría","anderson","conesa","soria","fernández-garcía"],"keywords":["bimetals","catalysis","emulsions","gas emissions","infrared spectroscopy","materials science","palladium","principal component analysis","raman spectroscopy","synthesis (chemical)","three-way catalysts","x ray diffraction analysis","x-ray diffraction","x-ray near-edge structures","xanes"],"authorIDs":[],"dataSources":["tkoLgiggidjAYidGW","SLACAPmRHCzNG5tYN","BraPrFTJMD8Pu6SQ6"]}