@ARTICLE{Intrieri20141811,
author={Intrieri, D. and Gac, S.L. and Caselli, A. and Rose, E. and Boitrel, B. and Gallo, E.},
title={Highly diastereoselective cyclopropanation of α-methylstyrene catalysed by a C 2-symmetrical chiral iron porphyrin complex},
journal={Chemical Communications},
year={2014},
volume={50},
number={15},
pages={1811-1813},
doi={10.1039/c3cc48605b},
note={cited By 28},
url={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84893073939&doi=10.1039%2fc3cc48605b&partnerID=40&md5=71f74439c14e4f80a5b9eda5e308eb8e},
affiliation={Dipartimento di Chimica, Università degli Studi di Milano, Via Golgi 19, Milano, 20133, Italy; Institut des Sciences Chimiques de Rennes, UMR CNRS 6226, Université de Rennes 1, 263 avenue du Général Leclerc, CS 74205, Cedex, Rennes, 35042, France; Université P. Et M. Curie, UPMC Paris 06, IPCM, UMR CNRS 7201, Bâtiment F, 4 Place Jussieu, Cedex 05, Paris, 75252, France},
abstract={A new chiral iron porphyrin-based catalyst performed α-methylstyrene stereoselective cyclopropanation with excellent yields (up to 99%), enantio- and diastereoselectivities (ee trans up to 87%, trans/cis ratios up to 99 : 1) and outstanding TON and TOF values (up to 20 000 and 120 000 h−1 respectively). 2014 © The Royal Society of Chemistry.},
keywords={alpha-methylstyrol;  cyclopropane derivative;  iron;  metalloporphyrin;  styrene derivative;  alpha methylstyrene;  hexane;  iron;  porphyrin derivative, catalysis;  chemistry;  enzyme specificity;  stereoisomerism;  article;  catalyst;  chirality;  cis trans isomerism;  cyclopropanation;  decomposition;  enantioselectivity;  proton nuclear magnetic resonance;  room temperature;  stereochemistry, Catalysis;  Cyclopropanes;  Iron;  Metalloporphyrins;  Stereoisomerism;  Styrenes;  Substrate Specificity},
chemicals_cas={iron, 14093-02-8, 53858-86-9, 7439-89-6; alpha methylstyrene, 98-83-9; hexane, 110-54-3; alpha-methylstyrol; Cyclopropanes; Iron; Metalloporphyrins; Styrenes},
references={Tang, P., Qin, Y., (2012) Synthesis, pp. 2969-2984; Kumar, A.K., (2013) Int. J. Pharm. Pharm. Sci., 5, pp. 467-472; Carson, C.A., Kerr, M.A., (2009) Chem. Soc. Rev., 38, pp. 3051-3060; Donaldson, W.A., (2001) Tetrahedron, 57, pp. 8589-8627; Lebel, H., Marcoux, J.-F., Molinaro, C., Charette, A.B., (2003) Chem. Rev., 103, pp. 977-1050; David, E., Milanole, G., Ivashkin, P., Couve-Bonnaire, S., Jubault, P., Pannecoucke, X., (2012) Chem. Eur. J., 18, pp. 14904-14917; Boysen, M.M.K., (2013) Carbohydrates Tools for Stereoselective Synthesis, pp. 313-318. , Wiley-VCH Verlag GmbH & Co. KGaA; Doyle, M.P., Duffy, R., Ratnikov, M., Zhou, L., (2010) Chem. Rev., 110, pp. 704-724; Huang, W., Wang, L.-L., (2013) J. Chem. Res., 37, pp. 380-384; Castano, B., Guidone, S., Gallo, E., Ragaini, F., Casati, N., Macchi, P., Sisti, M., Caselli, A., (2013) Dalton Trans., 42, pp. 2451-2462; Wang, H., Guptill, D.M., Varela-Alvarez, A., Musaev, D.G., Davies, H.M.L., (2013) Chem. Sci., 4, pp. 2844-2850; Caballero, A., Prieto, A., Diaz-Requejo, M.M., Perez, P.J., (2009) Eur. J. Inorg. Chem., pp. 1137-1144; Youssef, N.S., El-Seidy, A.M.A., Schiavoni, M., Castano, B., Ragaini, F., Gallo, E., Caselli, A., (2012) J. Organomet. Chem., 714, pp. 94-103; Intrieri, D., Caselli, A., Gallo, E., (2011) Eur. J. Inorg. Chem., pp. 5071-5081; Zhu, S., Xu, X., Perman, J.A., Zhang, X.P., (2010) J. Am. Chem. Soc., 132, pp. 12796-12799; Rose, E., Raoul, N., Gallo, E., (2011) J. Porphyrins Phthalocyanines, 15, pp. 602-611; Zhang, J.-L., Chan, P.W.H., Che, C.-M., (2003) Tetrahedron Lett., 44, pp. 8733-8737; Zhou, C.-Y., Huang, J.-S., Che, C.-M., (2010) Synlett, pp. 2681-2700; Djukic, J.-P., Smith, D.A., Young, V.G., Woo, L.K., (1994) Organometallics, 13, pp. 3020-3026; Smith, D.A., Reynolds, D.N., Woo, L.K., (1993) J. Am. Chem. Soc., 115, pp. 2511-2513; Bartley, D.W., Kodadek, T., (1993) J. Am. Chem. Soc., 115, pp. 1656-1660; Rosenberg, M.L., Vlasana, K., Sen, G.N., Wragg, D., Tilset, M., (2011) J. Org. Chem., 76, pp. 2465-2470; Anding, B.J., Ellern, A., Woo, L.K., (2012) Organometallics, 31, pp. 3628-3635; Zhu, S., Cui, X., Zhang, X.P., (2012) Eur. J. Inorg. Chem., pp. 430-434; Zhu, S., Ruppel, J.V., Lu, H., Wojtas, L., Zhang, X.P., (2008) J. Am. Chem. Soc., 130, pp. 5042-5043; Penoni, A., Wanke, R., Tollari, S., Gallo, E., Musella, D., Ragaini, F., Demartin, F., Cenini, S., (2003) Eur. J. Inorg. Chem., pp. 1452-1460; Morandi, B., (2012) E. M. Carreira, Science, 335, pp. 1471-1474; Kaschel, J., Schneider, T.F., Werz, D.B., (2012) Angew. Chem., Int. Ed., 51, pp. 7085-7086; Nicolas, I., Roisnel, T., Le Maux, P., Simonneaux, G., (2009) Tetrahedron Lett., 50, pp. 5149-5151; Gross, Z., Galili, N., Simkhovich, L., (1999) Tetrahedron Lett., 40, pp. 1571-1574; Fantauzzi, S., Gallo, E., Rose, E., Raoul, N., Caselli, A., Issa, S., Ragaini, F., Cenini, S., (2008) Organometallics, 27, pp. 6143-6151; Didier, A., Michaudet, L., Ricard, D., Baveux-Chambenoît, V., Richard, P., Boitrel, B., (2001) Eur. J. Org. Chem., pp. 1917-1926; Halime, Z., Lachkar, M., Roisnel, T., Richard, P., Boitrel, B., (2007) Inorg. Chem., 46, pp. 6338-6346; Hijazi, I., Roisnel, T., Even-Hernandez, P., Furet, E., Halet, J.-F., Cador, O., Boitrel, B., (2010) J. Am. Chem. Soc., 132, pp. 10652-10653; Rose, E., Raoul, N., Etheve-Quelquejeu, M., Gallo, E., Boitrel, B., Pecaut, J., Dubois, L., (2012) J. Porphyrins Phthalocyanines, 16, pp. 324-330; Halime, Z., Lachkar, M., Furet, E., Halet, J.-F., Boitrel, B., (2006) Inorg. Chem., 45, pp. 10661-10669; Prevot, L., Jaquinod, L., Fischer, J., Weiss, R., (1998) Inorg. Chim. Acta, 283, pp. 98-104; Lecomte, C., Chadwick, D.L., Coppens, P., Stevens, E.D., (1983) Inorg. Chem., 22, pp. 2982-2992; Boldini, I., Guillemot, G., Caselli, A., Proust, A., Gallo, E., (2010) Adv. Synth. Catal., 352, pp. 2365-2370; Che, C.-M., Huang, J.-S., Lee, F.-W., Li, Y., Lai, T.-S., Kwong, H.-L., Teng, P.-F., Zhou, Z.-Y., (2001) J. Am. Chem. Soc., 123, pp. 4119-4129; Salomon, R.G., Kochi, J.K., (1973) J. Am. Chem. Soc., 95, pp. 3300-3310},
correspondence_address1={Gallo, E.; Dipartimento di Chimica, Via Golgi 19, Milano, 20133, Italy; email: emma.gallo@unimi.it},
issn={13597345},
pubmed_id={24398478},
language={English},
abbrev_source_title={Chem. Commun.},
document_type={Article},
source={Scopus},
}

{"_id":"XGZ5BvFsXHJPQ9fGt","bibbaseid":"intrieri-gac-caselli-rose-boitrel-gallo-highlydiastereoselectivecyclopropanationofmethylstyrenecatalysedbyac2symmetricalchiralironporphyrincomplex-2014","author_short":["Intrieri, D.","Gac, S.","Caselli, A.","Rose, E.","Boitrel, B.","Gallo, E."],"bibdata":{"bibtype":"article","type":"article","author":[{"propositions":[],"lastnames":["Intrieri"],"firstnames":["D."],"suffixes":[]},{"propositions":[],"lastnames":["Gac"],"firstnames":["S.L."],"suffixes":[]},{"propositions":[],"lastnames":["Caselli"],"firstnames":["A."],"suffixes":[]},{"propositions":[],"lastnames":["Rose"],"firstnames":["E."],"suffixes":[]},{"propositions":[],"lastnames":["Boitrel"],"firstnames":["B."],"suffixes":[]},{"propositions":[],"lastnames":["Gallo"],"firstnames":["E."],"suffixes":[]}],"title":"Highly diastereoselective cyclopropanation of α-methylstyrene catalysed by a C 2-symmetrical chiral iron porphyrin complex","journal":"Chemical Communications","year":"2014","volume":"50","number":"15","pages":"1811-1813","doi":"10.1039/c3cc48605b","note":"cited By 28","url":"https://www.scopus.com/inward/record.uri?eid=2-s2.0-84893073939&doi=10.1039%2fc3cc48605b&partnerID=40&md5=71f74439c14e4f80a5b9eda5e308eb8e","affiliation":"Dipartimento di Chimica, Università degli Studi di Milano, Via Golgi 19, Milano, 20133, Italy; Institut des Sciences Chimiques de Rennes, UMR CNRS 6226, Université de Rennes 1, 263 avenue du Général Leclerc, CS 74205, Cedex, Rennes, 35042, France; Université P. Et M. Curie, UPMC Paris 06, IPCM, UMR CNRS 7201, Bâtiment F, 4 Place Jussieu, Cedex 05, Paris, 75252, France","abstract":"A new chiral iron porphyrin-based catalyst performed α-methylstyrene stereoselective cyclopropanation with excellent yields (up to 99%), enantio- and diastereoselectivities (ee trans up to 87%, trans/cis ratios up to 99 : 1) and outstanding TON and TOF values (up to 20 000 and 120 000 h−1 respectively). 2014 © The Royal Society of Chemistry.","keywords":"alpha-methylstyrol; cyclopropane derivative; iron; metalloporphyrin; styrene derivative; alpha methylstyrene; hexane; iron; porphyrin derivative, catalysis; chemistry; enzyme specificity; stereoisomerism; article; catalyst; chirality; cis trans isomerism; cyclopropanation; decomposition; enantioselectivity; proton nuclear magnetic resonance; room temperature; stereochemistry, Catalysis; Cyclopropanes; Iron; Metalloporphyrins; Stereoisomerism; Styrenes; Substrate Specificity","chemicals_cas":"iron, 14093-02-8, 53858-86-9, 7439-89-6; alpha methylstyrene, 98-83-9; hexane, 110-54-3; alpha-methylstyrol; Cyclopropanes; Iron; Metalloporphyrins; Styrenes","references":"Tang, P., Qin, Y., (2012) Synthesis, pp. 2969-2984; Kumar, A.K., (2013) Int. J. Pharm. Pharm. Sci., 5, pp. 467-472; Carson, C.A., Kerr, M.A., (2009) Chem. Soc. Rev., 38, pp. 3051-3060; Donaldson, W.A., (2001) Tetrahedron, 57, pp. 8589-8627; Lebel, H., Marcoux, J.-F., Molinaro, C., Charette, A.B., (2003) Chem. Rev., 103, pp. 977-1050; David, E., Milanole, G., Ivashkin, P., Couve-Bonnaire, S., Jubault, P., Pannecoucke, X., (2012) Chem. Eur. J., 18, pp. 14904-14917; Boysen, M.M.K., (2013) Carbohydrates Tools for Stereoselective Synthesis, pp. 313-318. , Wiley-VCH Verlag GmbH & Co. KGaA; Doyle, M.P., Duffy, R., Ratnikov, M., Zhou, L., (2010) Chem. Rev., 110, pp. 704-724; Huang, W., Wang, L.-L., (2013) J. Chem. Res., 37, pp. 380-384; Castano, B., Guidone, S., Gallo, E., Ragaini, F., Casati, N., Macchi, P., Sisti, M., Caselli, A., (2013) Dalton Trans., 42, pp. 2451-2462; Wang, H., Guptill, D.M., Varela-Alvarez, A., Musaev, D.G., Davies, H.M.L., (2013) Chem. Sci., 4, pp. 2844-2850; Caballero, A., Prieto, A., Diaz-Requejo, M.M., Perez, P.J., (2009) Eur. J. Inorg. Chem., pp. 1137-1144; Youssef, N.S., El-Seidy, A.M.A., Schiavoni, M., Castano, B., Ragaini, F., Gallo, E., Caselli, A., (2012) J. Organomet. Chem., 714, pp. 94-103; Intrieri, D., Caselli, A., Gallo, E., (2011) Eur. J. Inorg. Chem., pp. 5071-5081; Zhu, S., Xu, X., Perman, J.A., Zhang, X.P., (2010) J. Am. Chem. Soc., 132, pp. 12796-12799; Rose, E., Raoul, N., Gallo, E., (2011) J. Porphyrins Phthalocyanines, 15, pp. 602-611; Zhang, J.-L., Chan, P.W.H., Che, C.-M., (2003) Tetrahedron Lett., 44, pp. 8733-8737; Zhou, C.-Y., Huang, J.-S., Che, C.-M., (2010) Synlett, pp. 2681-2700; Djukic, J.-P., Smith, D.A., Young, V.G., Woo, L.K., (1994) Organometallics, 13, pp. 3020-3026; Smith, D.A., Reynolds, D.N., Woo, L.K., (1993) J. Am. Chem. Soc., 115, pp. 2511-2513; Bartley, D.W., Kodadek, T., (1993) J. Am. Chem. Soc., 115, pp. 1656-1660; Rosenberg, M.L., Vlasana, K., Sen, G.N., Wragg, D., Tilset, M., (2011) J. Org. Chem., 76, pp. 2465-2470; Anding, B.J., Ellern, A., Woo, L.K., (2012) Organometallics, 31, pp. 3628-3635; Zhu, S., Cui, X., Zhang, X.P., (2012) Eur. J. Inorg. Chem., pp. 430-434; Zhu, S., Ruppel, J.V., Lu, H., Wojtas, L., Zhang, X.P., (2008) J. Am. Chem. Soc., 130, pp. 5042-5043; Penoni, A., Wanke, R., Tollari, S., Gallo, E., Musella, D., Ragaini, F., Demartin, F., Cenini, S., (2003) Eur. J. Inorg. Chem., pp. 1452-1460; Morandi, B., (2012) E. M. Carreira, Science, 335, pp. 1471-1474; Kaschel, J., Schneider, T.F., Werz, D.B., (2012) Angew. Chem., Int. Ed., 51, pp. 7085-7086; Nicolas, I., Roisnel, T., Le Maux, P., Simonneaux, G., (2009) Tetrahedron Lett., 50, pp. 5149-5151; Gross, Z., Galili, N., Simkhovich, L., (1999) Tetrahedron Lett., 40, pp. 1571-1574; Fantauzzi, S., Gallo, E., Rose, E., Raoul, N., Caselli, A., Issa, S., Ragaini, F., Cenini, S., (2008) Organometallics, 27, pp. 6143-6151; Didier, A., Michaudet, L., Ricard, D., Baveux-Chambenoît, V., Richard, P., Boitrel, B., (2001) Eur. J. Org. Chem., pp. 1917-1926; Halime, Z., Lachkar, M., Roisnel, T., Richard, P., Boitrel, B., (2007) Inorg. Chem., 46, pp. 6338-6346; Hijazi, I., Roisnel, T., Even-Hernandez, P., Furet, E., Halet, J.-F., Cador, O., Boitrel, B., (2010) J. Am. Chem. Soc., 132, pp. 10652-10653; Rose, E., Raoul, N., Etheve-Quelquejeu, M., Gallo, E., Boitrel, B., Pecaut, J., Dubois, L., (2012) J. Porphyrins Phthalocyanines, 16, pp. 324-330; Halime, Z., Lachkar, M., Furet, E., Halet, J.-F., Boitrel, B., (2006) Inorg. Chem., 45, pp. 10661-10669; Prevot, L., Jaquinod, L., Fischer, J., Weiss, R., (1998) Inorg. Chim. Acta, 283, pp. 98-104; Lecomte, C., Chadwick, D.L., Coppens, P., Stevens, E.D., (1983) Inorg. Chem., 22, pp. 2982-2992; Boldini, I., Guillemot, G., Caselli, A., Proust, A., Gallo, E., (2010) Adv. Synth. Catal., 352, pp. 2365-2370; Che, C.-M., Huang, J.-S., Lee, F.-W., Li, Y., Lai, T.-S., Kwong, H.-L., Teng, P.-F., Zhou, Z.-Y., (2001) J. Am. Chem. Soc., 123, pp. 4119-4129; Salomon, R.G., Kochi, J.K., (1973) J. Am. Chem. Soc., 95, pp. 3300-3310","correspondence_address1":"Gallo, E.; Dipartimento di Chimica, Via Golgi 19, Milano, 20133, Italy; email: emma.gallo@unimi.it","issn":"13597345","pubmed_id":"24398478","language":"English","abbrev_source_title":"Chem. Commun.","document_type":"Article","source":"Scopus","bibtex":"@ARTICLE{Intrieri20141811,\nauthor={Intrieri, D. and Gac, S.L. and Caselli, A. and Rose, E. and Boitrel, B. and Gallo, E.},\ntitle={Highly diastereoselective cyclopropanation of α-methylstyrene catalysed by a C 2-symmetrical chiral iron porphyrin complex},\njournal={Chemical Communications},\nyear={2014},\nvolume={50},\nnumber={15},\npages={1811-1813},\ndoi={10.1039/c3cc48605b},\nnote={cited By 28},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84893073939&doi=10.1039%2fc3cc48605b&partnerID=40&md5=71f74439c14e4f80a5b9eda5e308eb8e},\naffiliation={Dipartimento di Chimica, Università degli Studi di Milano, Via Golgi 19, Milano, 20133, Italy; Institut des Sciences Chimiques de Rennes, UMR CNRS 6226, Université de Rennes 1, 263 avenue du Général Leclerc, CS 74205, Cedex, Rennes, 35042, France; Université P. Et M. Curie, UPMC Paris 06, IPCM, UMR CNRS 7201, Bâtiment F, 4 Place Jussieu, Cedex 05, Paris, 75252, France},\nabstract={A new chiral iron porphyrin-based catalyst performed α-methylstyrene stereoselective cyclopropanation with excellent yields (up to 99%), enantio- and diastereoselectivities (ee trans up to 87%, trans/cis ratios up to 99 : 1) and outstanding TON and TOF values (up to 20 000 and 120 000 h−1 respectively). 2014 © The Royal Society of Chemistry.},\nkeywords={alpha-methylstyrol; cyclopropane derivative; iron; metalloporphyrin; styrene derivative; alpha methylstyrene; hexane; iron; porphyrin derivative, catalysis; chemistry; enzyme specificity; stereoisomerism; article; catalyst; chirality; cis trans isomerism; cyclopropanation; decomposition; enantioselectivity; proton nuclear magnetic resonance; room temperature; stereochemistry, Catalysis; Cyclopropanes; Iron; Metalloporphyrins; Stereoisomerism; Styrenes; Substrate Specificity},\nchemicals_cas={iron, 14093-02-8, 53858-86-9, 7439-89-6; alpha methylstyrene, 98-83-9; hexane, 110-54-3; alpha-methylstyrol; Cyclopropanes; Iron; Metalloporphyrins; Styrenes},\nreferences={Tang, P., Qin, Y., (2012) Synthesis, pp. 2969-2984; Kumar, A.K., (2013) Int. J. Pharm. Pharm. Sci., 5, pp. 467-472; Carson, C.A., Kerr, M.A., (2009) Chem. Soc. Rev., 38, pp. 3051-3060; Donaldson, W.A., (2001) Tetrahedron, 57, pp. 8589-8627; Lebel, H., Marcoux, J.-F., Molinaro, C., Charette, A.B., (2003) Chem. Rev., 103, pp. 977-1050; David, E., Milanole, G., Ivashkin, P., Couve-Bonnaire, S., Jubault, P., Pannecoucke, X., (2012) Chem. Eur. J., 18, pp. 14904-14917; Boysen, M.M.K., (2013) Carbohydrates Tools for Stereoselective Synthesis, pp. 313-318. , Wiley-VCH Verlag GmbH & Co. KGaA; Doyle, M.P., Duffy, R., Ratnikov, M., Zhou, L., (2010) Chem. Rev., 110, pp. 704-724; Huang, W., Wang, L.-L., (2013) J. Chem. Res., 37, pp. 380-384; Castano, B., Guidone, S., Gallo, E., Ragaini, F., Casati, N., Macchi, P., Sisti, M., Caselli, A., (2013) Dalton Trans., 42, pp. 2451-2462; Wang, H., Guptill, D.M., Varela-Alvarez, A., Musaev, D.G., Davies, H.M.L., (2013) Chem. Sci., 4, pp. 2844-2850; Caballero, A., Prieto, A., Diaz-Requejo, M.M., Perez, P.J., (2009) Eur. J. Inorg. Chem., pp. 1137-1144; Youssef, N.S., El-Seidy, A.M.A., Schiavoni, M., Castano, B., Ragaini, F., Gallo, E., Caselli, A., (2012) J. Organomet. Chem., 714, pp. 94-103; Intrieri, D., Caselli, A., Gallo, E., (2011) Eur. J. Inorg. Chem., pp. 5071-5081; Zhu, S., Xu, X., Perman, J.A., Zhang, X.P., (2010) J. Am. Chem. Soc., 132, pp. 12796-12799; Rose, E., Raoul, N., Gallo, E., (2011) J. Porphyrins Phthalocyanines, 15, pp. 602-611; Zhang, J.-L., Chan, P.W.H., Che, C.-M., (2003) Tetrahedron Lett., 44, pp. 8733-8737; Zhou, C.-Y., Huang, J.-S., Che, C.-M., (2010) Synlett, pp. 2681-2700; Djukic, J.-P., Smith, D.A., Young, V.G., Woo, L.K., (1994) Organometallics, 13, pp. 3020-3026; Smith, D.A., Reynolds, D.N., Woo, L.K., (1993) J. Am. Chem. Soc., 115, pp. 2511-2513; Bartley, D.W., Kodadek, T., (1993) J. Am. Chem. Soc., 115, pp. 1656-1660; Rosenberg, M.L., Vlasana, K., Sen, G.N., Wragg, D., Tilset, M., (2011) J. Org. Chem., 76, pp. 2465-2470; Anding, B.J., Ellern, A., Woo, L.K., (2012) Organometallics, 31, pp. 3628-3635; Zhu, S., Cui, X., Zhang, X.P., (2012) Eur. J. Inorg. Chem., pp. 430-434; Zhu, S., Ruppel, J.V., Lu, H., Wojtas, L., Zhang, X.P., (2008) J. Am. Chem. Soc., 130, pp. 5042-5043; Penoni, A., Wanke, R., Tollari, S., Gallo, E., Musella, D., Ragaini, F., Demartin, F., Cenini, S., (2003) Eur. J. Inorg. Chem., pp. 1452-1460; Morandi, B., (2012) E. M. Carreira, Science, 335, pp. 1471-1474; Kaschel, J., Schneider, T.F., Werz, D.B., (2012) Angew. Chem., Int. Ed., 51, pp. 7085-7086; Nicolas, I., Roisnel, T., Le Maux, P., Simonneaux, G., (2009) Tetrahedron Lett., 50, pp. 5149-5151; Gross, Z., Galili, N., Simkhovich, L., (1999) Tetrahedron Lett., 40, pp. 1571-1574; Fantauzzi, S., Gallo, E., Rose, E., Raoul, N., Caselli, A., Issa, S., Ragaini, F., Cenini, S., (2008) Organometallics, 27, pp. 6143-6151; Didier, A., Michaudet, L., Ricard, D., Baveux-Chambenoît, V., Richard, P., Boitrel, B., (2001) Eur. J. Org. Chem., pp. 1917-1926; Halime, Z., Lachkar, M., Roisnel, T., Richard, P., Boitrel, B., (2007) Inorg. Chem., 46, pp. 6338-6346; Hijazi, I., Roisnel, T., Even-Hernandez, P., Furet, E., Halet, J.-F., Cador, O., Boitrel, B., (2010) J. Am. Chem. Soc., 132, pp. 10652-10653; Rose, E., Raoul, N., Etheve-Quelquejeu, M., Gallo, E., Boitrel, B., Pecaut, J., Dubois, L., (2012) J. Porphyrins Phthalocyanines, 16, pp. 324-330; Halime, Z., Lachkar, M., Furet, E., Halet, J.-F., Boitrel, B., (2006) Inorg. Chem., 45, pp. 10661-10669; Prevot, L., Jaquinod, L., Fischer, J., Weiss, R., (1998) Inorg. Chim. Acta, 283, pp. 98-104; Lecomte, C., Chadwick, D.L., Coppens, P., Stevens, E.D., (1983) Inorg. Chem., 22, pp. 2982-2992; Boldini, I., Guillemot, G., Caselli, A., Proust, A., Gallo, E., (2010) Adv. Synth. Catal., 352, pp. 2365-2370; Che, C.-M., Huang, J.-S., Lee, F.-W., Li, Y., Lai, T.-S., Kwong, H.-L., Teng, P.-F., Zhou, Z.-Y., (2001) J. Am. Chem. Soc., 123, pp. 4119-4129; Salomon, R.G., Kochi, J.K., (1973) J. Am. Chem. Soc., 95, pp. 3300-3310},\ncorrespondence_address1={Gallo, E.; Dipartimento di Chimica, Via Golgi 19, Milano, 20133, Italy; email: emma.gallo@unimi.it},\nissn={13597345},\npubmed_id={24398478},\nlanguage={English},\nabbrev_source_title={Chem. Commun.},\ndocument_type={Article},\nsource={Scopus},\n}\n\n","author_short":["Intrieri, D.","Gac, S.","Caselli, A.","Rose, E.","Boitrel, B.","Gallo, E."],"key":"Intrieri20141811","id":"Intrieri20141811","bibbaseid":"intrieri-gac-caselli-rose-boitrel-gallo-highlydiastereoselectivecyclopropanationofmethylstyrenecatalysedbyac2symmetricalchiralironporphyrincomplex-2014","role":"author","urls":{"Paper":"https://www.scopus.com/inward/record.uri?eid=2-s2.0-84893073939&doi=10.1039%2fc3cc48605b&partnerID=40&md5=71f74439c14e4f80a5b9eda5e308eb8e"},"keyword":["alpha-methylstyrol; cyclopropane derivative; iron; metalloporphyrin; styrene derivative; alpha methylstyrene; hexane; iron; porphyrin derivative","catalysis; chemistry; enzyme specificity; stereoisomerism; article; catalyst; chirality; cis trans isomerism; cyclopropanation; decomposition; enantioselectivity; proton nuclear magnetic resonance; room temperature; stereochemistry","Catalysis; Cyclopropanes; Iron; Metalloporphyrins; Stereoisomerism; Styrenes; Substrate Specificity"],"metadata":{"authorlinks":{}}},"bibtype":"article","biburl":"https://cloud.alberti.top/index.php/s/xQ8igwraeGLfEPJ/download/scopus.bib","dataSources":["irnS7ryEAzf9jZde2","LBbkvwYBGL2WNBwtp","7pF76B4jHaih5QEAT"],"keywords":["alpha-methylstyrol; cyclopropane derivative; iron; metalloporphyrin; styrene derivative; alpha methylstyrene; hexane; iron; porphyrin derivative","catalysis; chemistry; enzyme specificity; stereoisomerism; article; catalyst; chirality; cis trans isomerism; cyclopropanation; decomposition; enantioselectivity; proton nuclear magnetic resonance; room temperature; stereochemistry","catalysis; cyclopropanes; iron; metalloporphyrins; stereoisomerism; styrenes; substrate specificity"],"search_terms":["highly","diastereoselective","cyclopropanation","methylstyrene","catalysed","symmetrical","chiral","iron","porphyrin","complex","intrieri","gac","caselli","rose","boitrel","gallo"],"title":"Highly diastereoselective cyclopropanation of α-methylstyrene catalysed by a C 2-symmetrical chiral iron porphyrin complex","year":2014}