Photostability of oxazoline RNA-precursors in UV-rich prebiotic environments. Janicki, M. J., Roberts, S. J., Šponer, J., Powner, M. W., Góra, R. W., & Szabla, R. Chemical Communications, 54(95):13407–13410, 2018. doi abstract bibtex Pentose aminooxazolines and oxazolidinone thiones are considered as the key precursors which could have enabled the formation of RNA nucleotides under the conditions of early Earth. UV-irradiation experiments and quantum-chemical calculations demonstrate that these compounds are remarkably photostable and could accumulate over long periods of time in UV-rich prebiotic environments to undergo stereoisomeric purification.
@article{Janicki2018,
abstract = {Pentose aminooxazolines and oxazolidinone thiones are considered as the key precursors which could have enabled the formation of RNA nucleotides under the conditions of early Earth. UV-irradiation experiments and quantum-chemical calculations demonstrate that these compounds are remarkably photostable and could accumulate over long periods of time in UV-rich prebiotic environments to undergo stereoisomeric purification.},
author = {Janicki, Miko{\l}aj J. and Roberts, Samuel J. and {\v{S}}poner, Jiř{\'{i}} and Powner, Matthew W. and G{\'{o}}ra, Robert W. and Szabla, Rafa{\l}},
doi = {10.1039/c8cc07343k},
issn = {1364548X},
journal = {Chemical Communications},
number = {95},
pages = {13407--13410},
pmid = {30426980},
title = {{Photostability of oxazoline RNA-precursors in UV-rich prebiotic environments}},
volume = {54},
year = {2018}
}
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