Anchor Group Bottlebrush Polymers as Oil Additive Friction Modifiers. Kerr, A., Hakkinen, S., Hall, S. C. L., Kirkman, P., O'Hora, P., Smith, T., Kinane, C. J., Caruana, A., & Perrier, S. ACS APPLIED MATERIALS & INTERFACES, 15(41):48574–48583, October, 2023. doi abstract bibtex Surface-tethered polymers have been shown to be an efficient lubrication strategy for boundary and mixed lubrication by providing a solvated film between solid surfaces. We have assessed the performance of various graft copolymers as friction modifier additives in oil and revealed important structure-property relationships for this application. The polymers consisted of an oil-soluble, grafted poly(lauryl acrylate) segment and a polar, linear poly(4-acryloylmorpholine) anchor group. Reversible addition-fragmentation chain transfer polymerization was used to access various architectures with control of the grafting density and position of the anchor group. Macrotribological studies displayed promising results with approximate to 50% reduction in friction coefficient at low polymer treatment rates. QCM-D experiments, neutron reflectometry, small-angle neutron scattering, and atomic force microscopy were used to gather detailed information on these polymers' surface adsorption characteristics, film structure, and solution behavior.
@article{kerr_anchor_2023,
title = {Anchor {Group} {Bottlebrush} {Polymers} as {Oil} {Additive} {Friction} {Modifiers}},
volume = {15},
issn = {1944-8244},
doi = {10.1021/acsami.3c12628},
abstract = {Surface-tethered polymers have been shown to be an efficient lubrication strategy for boundary and mixed lubrication by providing a solvated film between solid surfaces. We have assessed the performance of various graft copolymers as friction modifier additives in oil and revealed important structure-property relationships for this application. The polymers consisted of an oil-soluble, grafted poly(lauryl acrylate) segment and a polar, linear poly(4-acryloylmorpholine) anchor group. Reversible addition-fragmentation chain transfer polymerization was used to access various architectures with control of the grafting density and position of the anchor group. Macrotribological studies displayed promising results with approximate to 50\% reduction in friction coefficient at low polymer treatment rates. QCM-D experiments, neutron reflectometry, small-angle neutron scattering, and atomic force microscopy were used to gather detailed information on these polymers' surface adsorption characteristics, film structure, and solution behavior.},
number = {41},
urldate = {2023-10-28},
journal = {ACS APPLIED MATERIALS \& INTERFACES},
author = {Kerr, Andrew and Hakkinen, Satu and Hall, Stephen C. L. and Kirkman, Paul and O'Hora, Paul and Smith, Timothy and Kinane, Christian J. and Caruana, Andrew and Perrier, Sebastien},
month = oct,
year = {2023},
pages = {48574--48583},
}
Downloads: 0
{"_id":"hsi5ynFrXNCwMHWeC","bibbaseid":"kerr-hakkinen-hall-kirkman-ohora-smith-kinane-caruana-etal-anchorgroupbottlebrushpolymersasoiladditivefrictionmodifiers-2023","author_short":["Kerr, A.","Hakkinen, S.","Hall, S. C. L.","Kirkman, P.","O'Hora, P.","Smith, T.","Kinane, C. J.","Caruana, A.","Perrier, S."],"bibdata":{"bibtype":"article","type":"article","title":"Anchor Group Bottlebrush Polymers as Oil Additive Friction Modifiers","volume":"15","issn":"1944-8244","doi":"10.1021/acsami.3c12628","abstract":"Surface-tethered polymers have been shown to be an efficient lubrication strategy for boundary and mixed lubrication by providing a solvated film between solid surfaces. We have assessed the performance of various graft copolymers as friction modifier additives in oil and revealed important structure-property relationships for this application. The polymers consisted of an oil-soluble, grafted poly(lauryl acrylate) segment and a polar, linear poly(4-acryloylmorpholine) anchor group. Reversible addition-fragmentation chain transfer polymerization was used to access various architectures with control of the grafting density and position of the anchor group. Macrotribological studies displayed promising results with approximate to 50% reduction in friction coefficient at low polymer treatment rates. QCM-D experiments, neutron reflectometry, small-angle neutron scattering, and atomic force microscopy were used to gather detailed information on these polymers' surface adsorption characteristics, film structure, and solution behavior.","number":"41","urldate":"2023-10-28","journal":"ACS APPLIED MATERIALS & INTERFACES","author":[{"propositions":[],"lastnames":["Kerr"],"firstnames":["Andrew"],"suffixes":[]},{"propositions":[],"lastnames":["Hakkinen"],"firstnames":["Satu"],"suffixes":[]},{"propositions":[],"lastnames":["Hall"],"firstnames":["Stephen","C.","L."],"suffixes":[]},{"propositions":[],"lastnames":["Kirkman"],"firstnames":["Paul"],"suffixes":[]},{"propositions":[],"lastnames":["O'Hora"],"firstnames":["Paul"],"suffixes":[]},{"propositions":[],"lastnames":["Smith"],"firstnames":["Timothy"],"suffixes":[]},{"propositions":[],"lastnames":["Kinane"],"firstnames":["Christian","J."],"suffixes":[]},{"propositions":[],"lastnames":["Caruana"],"firstnames":["Andrew"],"suffixes":[]},{"propositions":[],"lastnames":["Perrier"],"firstnames":["Sebastien"],"suffixes":[]}],"month":"October","year":"2023","pages":"48574–48583","bibtex":"@article{kerr_anchor_2023,\n\ttitle = {Anchor {Group} {Bottlebrush} {Polymers} as {Oil} {Additive} {Friction} {Modifiers}},\n\tvolume = {15},\n\tissn = {1944-8244},\n\tdoi = {10.1021/acsami.3c12628},\n\tabstract = {Surface-tethered polymers have been shown to be an efficient lubrication strategy for boundary and mixed lubrication by providing a solvated film between solid surfaces. We have assessed the performance of various graft copolymers as friction modifier additives in oil and revealed important structure-property relationships for this application. The polymers consisted of an oil-soluble, grafted poly(lauryl acrylate) segment and a polar, linear poly(4-acryloylmorpholine) anchor group. Reversible addition-fragmentation chain transfer polymerization was used to access various architectures with control of the grafting density and position of the anchor group. Macrotribological studies displayed promising results with approximate to 50\\% reduction in friction coefficient at low polymer treatment rates. QCM-D experiments, neutron reflectometry, small-angle neutron scattering, and atomic force microscopy were used to gather detailed information on these polymers' surface adsorption characteristics, film structure, and solution behavior.},\n\tnumber = {41},\n\turldate = {2023-10-28},\n\tjournal = {ACS APPLIED MATERIALS \\& INTERFACES},\n\tauthor = {Kerr, Andrew and Hakkinen, Satu and Hall, Stephen C. L. and Kirkman, Paul and O'Hora, Paul and Smith, Timothy and Kinane, Christian J. and Caruana, Andrew and Perrier, Sebastien},\n\tmonth = oct,\n\tyear = {2023},\n\tpages = {48574--48583},\n}\n\n","author_short":["Kerr, A.","Hakkinen, S.","Hall, S. C. L.","Kirkman, P.","O'Hora, P.","Smith, T.","Kinane, C. J.","Caruana, A.","Perrier, S."],"key":"kerr_anchor_2023","id":"kerr_anchor_2023","bibbaseid":"kerr-hakkinen-hall-kirkman-ohora-smith-kinane-caruana-etal-anchorgroupbottlebrushpolymersasoiladditivefrictionmodifiers-2023","role":"author","urls":{},"metadata":{"authorlinks":{}},"html":""},"bibtype":"article","biburl":"https://warwick.ac.uk/fac/cross_fac/wesic/research/wpg/research/WPGsep2024.bib","dataSources":["m4fxWT6XKrYfGbZFR","GBhqMC9hjyD5vqptk","6idaYK6okJY39mWgG"],"keywords":[],"search_terms":["anchor","group","bottlebrush","polymers","oil","additive","friction","modifiers","kerr","hakkinen","hall","kirkman","o'hora","smith","kinane","caruana","perrier"],"title":"Anchor Group Bottlebrush Polymers as Oil Additive Friction Modifiers","year":2023}