Enabling Reversible Addition-Fragmentation Chain-Transfer Polymerization for Brush Copolymers with a Poly(2-oxazoline) Backbone. Kim, J., Cattoz, B., Leung, A. H. M., Parish, J. D., & Becer, C. R. MACROMOLECULES, 55(11):4411–4419, June, 2022. Infineum UK Ltddoi abstract bibtex The combination of different monomer classes has been sought after to access a wider range of brush copolymers owing to their unique properties derived from their dense macromolecular structures. Herein, we report the synthesis of a 2oxazoline monomer (RAFTOx) containing a chain transfer agent at the 2-position and its subsequent utilization in reversible addition-fragmentation chain-transfer (RAFT) polymerization. With the aim of tuning the brush density in these polymers, homopolymers, block copolymers, and gradient copolymers of various ratios with 2-ethyl-2-oxazoline and RAFTOx have been prepared. Selected brush macroCTAs were then used for the RAFT polymerization of N,N-dimethylacrylamide and 2-ethyhexyl acrylate to prepare brush copolymers of different architectures.
@article{kim_enabling_2022,
title = {Enabling {Reversible} {Addition}-{Fragmentation} {Chain}-{Transfer} {Polymerization} for {Brush} {Copolymers} with a {Poly}(2-oxazoline) {Backbone}},
volume = {55},
issn = {0024-9297},
doi = {10.1021/acs.macromol.2c00497},
abstract = {The combination of different monomer classes has been sought after to access a wider range of brush copolymers owing to their unique properties derived from their dense macromolecular structures. Herein, we report the synthesis of a 2oxazoline monomer (RAFTOx) containing a chain transfer agent at the 2-position and its subsequent utilization in reversible addition-fragmentation chain-transfer (RAFT) polymerization. With the aim of tuning the brush density in these polymers, homopolymers, block copolymers, and gradient copolymers of various ratios with 2-ethyl-2-oxazoline and RAFTOx have been prepared. Selected brush macroCTAs were then used for the RAFT polymerization of N,N-dimethylacrylamide and 2-ethyhexyl acrylate to prepare brush copolymers of different architectures.},
number = {11},
urldate = {2022-06-24},
journal = {MACROMOLECULES},
author = {Kim, Jungyeon and Cattoz, Beatrice and Leung, Alice H. M. and Parish, James D. and Becer, C. Remzi},
month = jun,
year = {2022},
note = {Infineum UK Ltd},
pages = {4411--4419},
}
Downloads: 0
{"_id":"iLtFtxNHSQ6he6zab","bibbaseid":"kim-cattoz-leung-parish-becer-enablingreversibleadditionfragmentationchaintransferpolymerizationforbrushcopolymerswithapoly2oxazolinebackbone-2022","author_short":["Kim, J.","Cattoz, B.","Leung, A. H. M.","Parish, J. D.","Becer, C. R."],"bibdata":{"bibtype":"article","type":"article","title":"Enabling Reversible Addition-Fragmentation Chain-Transfer Polymerization for Brush Copolymers with a Poly(2-oxazoline) Backbone","volume":"55","issn":"0024-9297","doi":"10.1021/acs.macromol.2c00497","abstract":"The combination of different monomer classes has been sought after to access a wider range of brush copolymers owing to their unique properties derived from their dense macromolecular structures. Herein, we report the synthesis of a 2oxazoline monomer (RAFTOx) containing a chain transfer agent at the 2-position and its subsequent utilization in reversible addition-fragmentation chain-transfer (RAFT) polymerization. With the aim of tuning the brush density in these polymers, homopolymers, block copolymers, and gradient copolymers of various ratios with 2-ethyl-2-oxazoline and RAFTOx have been prepared. Selected brush macroCTAs were then used for the RAFT polymerization of N,N-dimethylacrylamide and 2-ethyhexyl acrylate to prepare brush copolymers of different architectures.","number":"11","urldate":"2022-06-24","journal":"MACROMOLECULES","author":[{"propositions":[],"lastnames":["Kim"],"firstnames":["Jungyeon"],"suffixes":[]},{"propositions":[],"lastnames":["Cattoz"],"firstnames":["Beatrice"],"suffixes":[]},{"propositions":[],"lastnames":["Leung"],"firstnames":["Alice","H.","M."],"suffixes":[]},{"propositions":[],"lastnames":["Parish"],"firstnames":["James","D."],"suffixes":[]},{"propositions":[],"lastnames":["Becer"],"firstnames":["C.","Remzi"],"suffixes":[]}],"month":"June","year":"2022","note":"Infineum UK Ltd","pages":"4411–4419","bibtex":"@article{kim_enabling_2022,\n\ttitle = {Enabling {Reversible} {Addition}-{Fragmentation} {Chain}-{Transfer} {Polymerization} for {Brush} {Copolymers} with a {Poly}(2-oxazoline) {Backbone}},\n\tvolume = {55},\n\tissn = {0024-9297},\n\tdoi = {10.1021/acs.macromol.2c00497},\n\tabstract = {The combination of different monomer classes has been sought after to access a wider range of brush copolymers owing to their unique properties derived from their dense macromolecular structures. Herein, we report the synthesis of a 2oxazoline monomer (RAFTOx) containing a chain transfer agent at the 2-position and its subsequent utilization in reversible addition-fragmentation chain-transfer (RAFT) polymerization. With the aim of tuning the brush density in these polymers, homopolymers, block copolymers, and gradient copolymers of various ratios with 2-ethyl-2-oxazoline and RAFTOx have been prepared. Selected brush macroCTAs were then used for the RAFT polymerization of N,N-dimethylacrylamide and 2-ethyhexyl acrylate to prepare brush copolymers of different architectures.},\n\tnumber = {11},\n\turldate = {2022-06-24},\n\tjournal = {MACROMOLECULES},\n\tauthor = {Kim, Jungyeon and Cattoz, Beatrice and Leung, Alice H. M. and Parish, James D. and Becer, C. Remzi},\n\tmonth = jun,\n\tyear = {2022},\n\tnote = {Infineum UK Ltd},\n\tpages = {4411--4419},\n}\n\n","author_short":["Kim, J.","Cattoz, B.","Leung, A. H. M.","Parish, J. D.","Becer, C. R."],"key":"kim_enabling_2022","id":"kim_enabling_2022","bibbaseid":"kim-cattoz-leung-parish-becer-enablingreversibleadditionfragmentationchaintransferpolymerizationforbrushcopolymerswithapoly2oxazolinebackbone-2022","role":"author","urls":{},"metadata":{"authorlinks":{}},"html":""},"bibtype":"article","biburl":"https://warwick.ac.uk/fac/cross_fac/wesic/research/wpg/research/WPGsep2024.bib","dataSources":["m4fxWT6XKrYfGbZFR","GBhqMC9hjyD5vqptk","6idaYK6okJY39mWgG"],"keywords":[],"search_terms":["enabling","reversible","addition","fragmentation","chain","transfer","polymerization","brush","copolymers","poly","oxazoline","backbone","kim","cattoz","leung","parish","becer"],"title":"Enabling Reversible Addition-Fragmentation Chain-Transfer Polymerization for Brush Copolymers with a Poly(2-oxazoline) Backbone","year":2022}