Molecular Ruby: Exploring the Excited State Landscape. Kitzmann, W. R. R., Ramanan, C., Naumann, R., & Heinze, K. Dalton Transactions, April, 2022. Publisher: Royal Society of Chemistry
doi  abstract   bibtex   
The discovery of the highly NIR-luminescent Molecular Ruby [Cr(ddpd)2]3+ 13+ (ddpd = N,N’-dimethyl-N,N’-dipyridine-2-ylpyridine-2,6-diamine) has been a milestone in the development of earth-abundant luminophors and has led to important new impulses...The discovery of the highly NIR-luminescent Molecular Ruby [Cr(ddpd)2]3+ 13+ (ddpd = N,N’-dimethyl-N,N’-dipyridine-2-ylpyridine-2,6-diamine) has been a milestone in the development of earth-abundant luminophors and has led to important new impulses in the field of spin-flip emitters. Its favourable optical properties such as a high photoluminescence quantum yield and long excited state lifetime are traced back to a remarkable excited state landscape which has been investigated in great detail. This article summarises the results of these studies with the aim to create a coherent picture of the excited state ordering and the ultrafast as well as long-timescale dynamics. Additional experimental data is provided to fill in gaps left by previous reports.
@article{kitzmann_molecular_2022,
	title = {Molecular {Ruby}: {Exploring} the {Excited} {State} {Landscape}},
	volume = {51},
	issn = {1477-9226},
	doi = {10.1039/d2dt00569g},
	abstract = {The discovery of the highly NIR-luminescent Molecular Ruby [Cr(ddpd)2]3+ 13+ (ddpd = N,N’-dimethyl-N,N’-dipyridine-2-ylpyridine-2,6-diamine) has been a milestone in the development of earth-abundant luminophors and has led to important new impulses...The discovery of the highly NIR-luminescent Molecular Ruby [Cr(ddpd)2]3+ 13+ (ddpd = N,N’-dimethyl-N,N’-dipyridine-2-ylpyridine-2,6-diamine) has been a milestone in the development of earth-abundant luminophors and has led to important new impulses in the field of spin-flip emitters. Its favourable optical properties such as a high photoluminescence quantum yield and long excited state lifetime are traced back to a remarkable excited state landscape which has been investigated in great detail. This article summarises the results of these studies with the aim to create a coherent picture of the excited state ordering and the ultrafast as well as long-timescale dynamics. Additional experimental data is provided to fill in gaps left by previous reports.},
	number = {17},
	journal = {Dalton Transactions},
	author = {Kitzmann, Winald Robert Robert and Ramanan, Charusheela and Naumann, Robert and Heinze, Katja},
	month = apr,
	year = {2022},
	note = {Publisher: Royal Society of Chemistry},
}

Downloads: 0