NKU Tungsten isocyanide research 1: Synthesis of a new ligand to maximize excited-state stability. Kramer, S., A., Seger, R., A., & Walters, K., A. In Abstracts of Papers, 237th ACS National Meeting, Salt Lake City, UT, United States, March 22-26, 2009, pages CHED-591, 2009. American Chemical Society.
abstract   bibtex   
This poster is the first of three focusing on the synthetic and photophys. properties of tungsten(0) isocyanide complexes. These mols. are of great interest in "green" photocatalytic applications, as they undergo photoinduced charge transfer and deliver practically their entire excited-state energy to the reactant. This portion of the research project focuses on synthesizing a new aniline precursor that combines the steric hindrance and electron-withdrawing capabilities of previously studied isocyanide ligands. The resulting precursor will hopefully lead to a complex with a sufficiently long-lived excited state to permit electron transfer while still being thermally robust. Following synthesis of the aniline, it is converted to an isocyanide ligand and complexed to tungsten(0). [on SciFinder(R)]
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 title = {NKU Tungsten isocyanide research 1: Synthesis of a new ligand to maximize excited-state stability.},
 type = {inProceedings},
 year = {2009},
 pages = {CHED-591},
 publisher = {American Chemical Society},
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 abstract = {This poster is the first of three focusing on the synthetic and photophys. properties of tungsten(0) isocyanide complexes.  These mols. are of great interest in "green" photocatalytic applications, as they undergo photoinduced charge transfer and deliver practically their entire excited-state energy to the reactant.  This portion of the research project focuses on synthesizing a new aniline precursor that combines the steric hindrance and electron-withdrawing capabilities of previously studied isocyanide ligands.  The resulting precursor will hopefully lead to a complex with a sufficiently long-lived excited state to permit electron transfer while still being thermally robust.  Following synthesis of the aniline, it is converted to an isocyanide ligand and complexed to tungsten(0). [on SciFinder(R)]},
 bibtype = {inProceedings},
 author = {Kramer, Stephanie A and Seger, Rebecca A and Walters, Keith A},
 booktitle = {Abstracts of Papers, 237th ACS National Meeting, Salt Lake City, UT, United States, March 22-26, 2009}
}

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