Model-based analysis of anion-exchanger positioning in direct methanol fuel cell systems. Kraus, M., Schröder, D., & Krewer, U. Journal of Power Sources, 262:364–371, 2014.
doi  abstract   bibtex   
In this work we present a model based study to investigate the presence of anion exchangers in direct methanol fuel cell (DMFC) systems. It is well known that environmental or fuel impurities lead to accumulation of harmful anions, such as chloride, in the system. However, due to DMFC anodic reaction, a carbonate system is present. These corbanate anions have to be taken into account for the anion exchanger design and placement as well as for the system operation strategy with and without anion exchanger, which is the objective of this study. For this purpose, the expected amount of harmful chloride ions in a DMFC system is estimated, and that of carbonate ions is calculated with a model of the carbonate system in a DMFC system. The predicition of durability and dimensions of an anion exchanger is based on a monovalent anion exchange model. The design of gas liquid separators in the DMFC system has a major influence on the amount of dissolved carbon dioxide, which is crucial for durability and dimension of a system integrated anion exchanger. Finally, feasible positions of anion exchanger in a DMFC system are elaborated to fulfill the needs for long term and stable DMFC operation. © 2014 Elsevier B.V. All rights reserved.
@article{kraus_model-based_2014,
	title = {Model-based analysis of anion-exchanger positioning in direct methanol fuel cell systems},
	volume = {262},
	copyright = {All rights reserved},
	issn = {03787753},
	doi = {10.1016/j.jpowsour.2014.03.068},
	abstract = {In this work we present a model based study to investigate the presence of anion exchangers in direct methanol fuel cell (DMFC) systems. It is well known that environmental or fuel impurities lead to accumulation of harmful anions, such as chloride, in the system. However, due to DMFC anodic reaction, a carbonate system is present. These corbanate anions have to be taken into account for the anion exchanger design and placement as well as for the system operation strategy with and without anion exchanger, which is the objective of this study. For this purpose, the expected amount of harmful chloride ions in a DMFC system is estimated, and that of carbonate ions is calculated with a model of the carbonate system in a DMFC system. The predicition of durability and dimensions of an anion exchanger is based on a monovalent anion exchange model. The design of gas liquid separators in the DMFC system has a major influence on the amount of dissolved carbon dioxide, which is crucial for durability and dimension of a system integrated anion exchanger. Finally, feasible positions of anion exchanger in a DMFC system are elaborated to fulfill the needs for long term and stable DMFC operation. © 2014 Elsevier B.V. All rights reserved.},
	journal = {Journal of Power Sources},
	author = {Kraus, Maik and Schröder, Daniel and Krewer, Ulrike},
	year = {2014},
	keywords = {Anion exchanger, DMFC, Ionic impurities, Modeling},
	pages = {364--371},
}

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