Manganese-Catalyzed Batch and Continuous Flow Cationic RAFT Polymerization Induced by Visible Light. Li, J., Kerr, A., Song, Q., Yang, J., Hakkinen, S., Pan, X., Zhang, Z., Zhu, J., & Perrier, S. ACS MACRO LETTERS, 10(5):570–575, May, 2021. doi abstract bibtex We present a robust manganese-catalyzed cationic reversible addition-fragmentation chain transfer (RAFT) polymerization induced by visible light. Well-defined poly(vinyl ether)s with controlled molecular weight and molecular weight distributions (MWDs) can be conveniently prepared at room temperature without monomer purification. The commercially available manganese carbonyl bromide is used as the photocatalyst for cationic RAFT polymerization. Moreover, this method has been further applied in both batch and continuous flow systems, providing a visible light induced flow cationic polymerization under mild conditions.
@article{li_manganese-catalyzed_2021,
title = {Manganese-{Catalyzed} {Batch} and {Continuous} {Flow} {Cationic} {RAFT} {Polymerization} {Induced} by {Visible} {Light}},
volume = {10},
issn = {2161-1653},
doi = {10.1021/acsmacrolett.1c00180},
abstract = {We present a robust manganese-catalyzed cationic reversible addition-fragmentation chain transfer (RAFT) polymerization induced by visible light. Well-defined poly(vinyl ether)s with controlled molecular weight and molecular weight distributions (MWDs) can be conveniently prepared at room temperature without monomer purification. The commercially available manganese carbonyl bromide is used as the photocatalyst for cationic RAFT polymerization. Moreover, this method has been further applied in both batch and continuous flow systems, providing a visible light induced flow cationic polymerization under mild conditions.},
number = {5},
urldate = {2021-06-05},
journal = {ACS MACRO LETTERS},
author = {Li, Jiajia and Kerr, Andrew and Song, Qiao and Yang, Jie and Hakkinen, Satu and Pan, Xiangqiang and Zhang, Zhengbiao and Zhu, Jian and Perrier, Sebastien},
month = may,
year = {2021},
pages = {570--575},
}
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