UV irradiation of Cu-based complexes with aliphatic amine ligands as used in living radical polymerization. Liarou, E., Staniforth, M., Town, J. S., Marathianos, A., Grypioti, M., Li, Y., Chang, Y., Efstathiou, S., Hancox, E., Wemyss, A. M., Wilson, P., Jones, B. A., Aljuaid, M., Stavros, V. G., & Haddleton, D. M. EUROPEAN POLYMER JOURNAL, January, 2020. doi abstract bibtex The effect UV irradiation on Cu(II)-based complexes with aliphatic amine ligands is investigated. Four aliphatic amines are used as ligands and Cu(II)Br-2 as the metal source for the formation of catalyst complexes that can be used for the photoinduced Cu-RDRP of methyl acrylate. Different characterization techniques such as transient electronic absorption spectroscopy (TEAS), ultraviolet-visible (UV-Vis) spectroscopy, electrospray ionization time of flight mass spectrometry (ESI-ToF-MS) and cyclic voltammetry (CV) are applied in order to provide insights into the catalyst behaviour upon photo-irradiation. The excited-state dynamics, the electrochemical behaviour of the Cu(II)/Cu(I) redox couples and the detection of different species upon complexation of the ligand to the metal center (before and after UV irradiation) are further depicted in the quality of the obtained polymers.
@article{liarou_uv_2020,
title = {{UV} irradiation of {Cu}-based complexes with aliphatic amine ligands as used in living radical polymerization},
volume = {123},
issn = {0014-3057},
doi = {10.1016/j.eurpolymj.2019.109388},
abstract = {The effect UV irradiation on Cu(II)-based complexes with aliphatic amine ligands is investigated. Four aliphatic amines are used as ligands and Cu(II)Br-2 as the metal source for the formation of catalyst complexes that can be used for the photoinduced Cu-RDRP of methyl acrylate. Different characterization techniques such as transient electronic absorption spectroscopy (TEAS), ultraviolet-visible (UV-Vis) spectroscopy, electrospray ionization time of flight mass spectrometry (ESI-ToF-MS) and cyclic voltammetry (CV) are applied in order to provide insights into the catalyst behaviour upon photo-irradiation. The excited-state dynamics, the electrochemical behaviour of the Cu(II)/Cu(I) redox couples and the detection of different species upon complexation of the ligand to the metal center (before and after UV irradiation) are further depicted in the quality of the obtained polymers.},
urldate = {2020-02-18},
journal = {EUROPEAN POLYMER JOURNAL},
author = {Liarou, Evelina and Staniforth, Michael and Town, James S. and Marathianos, Arkadios and Grypioti, Maria and Li, Yongguang and Chang, Yujing and Efstathiou, Spyridon and Hancox, Ellis and Wemyss, Alan M. and Wilson, Paul and Jones, Bryn A. and Aljuaid, Mohammed and Stavros, Vasilios G. and Haddleton, David M.},
month = jan,
year = {2020},
}
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Different characterization techniques such as transient electronic absorption spectroscopy (TEAS), ultraviolet-visible (UV-Vis) spectroscopy, electrospray ionization time of flight mass spectrometry (ESI-ToF-MS) and cyclic voltammetry (CV) are applied in order to provide insights into the catalyst behaviour upon photo-irradiation. The excited-state dynamics, the electrochemical behaviour of the Cu(II)/Cu(I) redox couples and the detection of different species upon complexation of the ligand to the metal center (before and after UV irradiation) are further depicted in the quality of the obtained polymers.","urldate":"2020-02-18","journal":"EUROPEAN POLYMER JOURNAL","author":[{"propositions":[],"lastnames":["Liarou"],"firstnames":["Evelina"],"suffixes":[]},{"propositions":[],"lastnames":["Staniforth"],"firstnames":["Michael"],"suffixes":[]},{"propositions":[],"lastnames":["Town"],"firstnames":["James","S."],"suffixes":[]},{"propositions":[],"lastnames":["Marathianos"],"firstnames":["Arkadios"],"suffixes":[]},{"propositions":[],"lastnames":["Grypioti"],"firstnames":["Maria"],"suffixes":[]},{"propositions":[],"lastnames":["Li"],"firstnames":["Yongguang"],"suffixes":[]},{"propositions":[],"lastnames":["Chang"],"firstnames":["Yujing"],"suffixes":[]},{"propositions":[],"lastnames":["Efstathiou"],"firstnames":["Spyridon"],"suffixes":[]},{"propositions":[],"lastnames":["Hancox"],"firstnames":["Ellis"],"suffixes":[]},{"propositions":[],"lastnames":["Wemyss"],"firstnames":["Alan","M."],"suffixes":[]},{"propositions":[],"lastnames":["Wilson"],"firstnames":["Paul"],"suffixes":[]},{"propositions":[],"lastnames":["Jones"],"firstnames":["Bryn","A."],"suffixes":[]},{"propositions":[],"lastnames":["Aljuaid"],"firstnames":["Mohammed"],"suffixes":[]},{"propositions":[],"lastnames":["Stavros"],"firstnames":["Vasilios","G."],"suffixes":[]},{"propositions":[],"lastnames":["Haddleton"],"firstnames":["David","M."],"suffixes":[]}],"month":"January","year":"2020","bibtex":"@article{liarou_uv_2020,\n\ttitle = {{UV} irradiation of {Cu}-based complexes with aliphatic amine ligands as used in living radical polymerization},\n\tvolume = {123},\n\tissn = {0014-3057},\n\tdoi = {10.1016/j.eurpolymj.2019.109388},\n\tabstract = {The effect UV irradiation on Cu(II)-based complexes with aliphatic amine ligands is investigated. Four aliphatic amines are used as ligands and Cu(II)Br-2 as the metal source for the formation of catalyst complexes that can be used for the photoinduced Cu-RDRP of methyl acrylate. Different characterization techniques such as transient electronic absorption spectroscopy (TEAS), ultraviolet-visible (UV-Vis) spectroscopy, electrospray ionization time of flight mass spectrometry (ESI-ToF-MS) and cyclic voltammetry (CV) are applied in order to provide insights into the catalyst behaviour upon photo-irradiation. 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