@article{liu_radical_2024,
	title = {Radical polymerisation and thiol-ene post-polymerisation functionalisation of terpenoid acrylates in conventional and renewably sourced organic solvents},
	volume = {15},
	issn = {1759-9954},
	doi = {10.1039/d4py00340c},
	abstract = {Geranyl acrylate has been synthesized and polymerized by various radical polymerisation techniques. Due to the structural diversity, a number of post polymerisation functionalization options were explored. Monomer conversion, polymer structure and the molecular weight were assessed by NMR, FT-IR and size exclusion chromatography (SEC). Free radical polymerization and Cu-mediated reversible deactivation radical polymerization (RDRP) were used to synthesise poly(geranyl acrylate) of various molecular weight in both conventional petro-derived organic and bio-based renewably sourced solvents. Cu0 wire-mediated RDRP was found to be a suitable polymerisation method when compared to CuII-mediated photoinduced RDRP giving the optimal living radical polymerisation method for the synthesis of poly(geranyl acrylate) in Cyrene (Mn, SEC = 3000, \& Dstrok;SEC = 1.25). The residual allylic double bonds provided a useful option for post-polymerization modification. Poly(geranyl acrylate) was subjected to photoinduced thiol-ene reactions, using different thiols with a variety of functional groups. The success of the functionalization reaction was evaluated by NMR, FT-IR spectroscopy, and SEC. In addition, differential scanning calorimetry was used to investigate changes in the thermal properties of the polymer, before and after thiol-ene functionalization.Geranyl acrylate has been synthesized and polymerized by various radical polymerisation techniques.},
	number = {28},
	urldate = {2024-07-08},
	journal = {POLYMER CHEMISTRY},
	author = {Liu, Huizhe and Maugein, Vincent A. and Haddleton, David M.},
	month = jul,
	year = {2024},
	pages = {2862--2872},
}

{"_id":"jriTnNy4EmYG5aePD","bibbaseid":"liu-maugein-haddleton-radicalpolymerisationandthiolenepostpolymerisationfunctionalisationofterpenoidacrylatesinconventionalandrenewablysourcedorganicsolvents-2024","author_short":["Liu, H.","Maugein, V. A.","Haddleton, D. M."],"bibdata":{"bibtype":"article","type":"article","title":"Radical polymerisation and thiol-ene post-polymerisation functionalisation of terpenoid acrylates in conventional and renewably sourced organic solvents","volume":"15","issn":"1759-9954","doi":"10.1039/d4py00340c","abstract":"Geranyl acrylate has been synthesized and polymerized by various radical polymerisation techniques. Due to the structural diversity, a number of post polymerisation functionalization options were explored. Monomer conversion, polymer structure and the molecular weight were assessed by NMR, FT-IR and size exclusion chromatography (SEC). Free radical polymerization and Cu-mediated reversible deactivation radical polymerization (RDRP) were used to synthesise poly(geranyl acrylate) of various molecular weight in both conventional petro-derived organic and bio-based renewably sourced solvents. Cu0 wire-mediated RDRP was found to be a suitable polymerisation method when compared to CuII-mediated photoinduced RDRP giving the optimal living radical polymerisation method for the synthesis of poly(geranyl acrylate) in Cyrene (Mn, SEC = 3000, & Dstrok;SEC = 1.25). The residual allylic double bonds provided a useful option for post-polymerization modification. Poly(geranyl acrylate) was subjected to photoinduced thiol-ene reactions, using different thiols with a variety of functional groups. The success of the functionalization reaction was evaluated by NMR, FT-IR spectroscopy, and SEC. In addition, differential scanning calorimetry was used to investigate changes in the thermal properties of the polymer, before and after thiol-ene functionalization.Geranyl acrylate has been synthesized and polymerized by various radical polymerisation techniques.","number":"28","urldate":"2024-07-08","journal":"POLYMER CHEMISTRY","author":[{"propositions":[],"lastnames":["Liu"],"firstnames":["Huizhe"],"suffixes":[]},{"propositions":[],"lastnames":["Maugein"],"firstnames":["Vincent","A."],"suffixes":[]},{"propositions":[],"lastnames":["Haddleton"],"firstnames":["David","M."],"suffixes":[]}],"month":"July","year":"2024","pages":"2862–2872","bibtex":"@article{liu_radical_2024,\n\ttitle = {Radical polymerisation and thiol-ene post-polymerisation functionalisation of terpenoid acrylates in conventional and renewably sourced organic solvents},\n\tvolume = {15},\n\tissn = {1759-9954},\n\tdoi = {10.1039/d4py00340c},\n\tabstract = {Geranyl acrylate has been synthesized and polymerized by various radical polymerisation techniques. Due to the structural diversity, a number of post polymerisation functionalization options were explored. Monomer conversion, polymer structure and the molecular weight were assessed by NMR, FT-IR and size exclusion chromatography (SEC). Free radical polymerization and Cu-mediated reversible deactivation radical polymerization (RDRP) were used to synthesise poly(geranyl acrylate) of various molecular weight in both conventional petro-derived organic and bio-based renewably sourced solvents. Cu0 wire-mediated RDRP was found to be a suitable polymerisation method when compared to CuII-mediated photoinduced RDRP giving the optimal living radical polymerisation method for the synthesis of poly(geranyl acrylate) in Cyrene (Mn, SEC = 3000, \\& Dstrok;SEC = 1.25). The residual allylic double bonds provided a useful option for post-polymerization modification. Poly(geranyl acrylate) was subjected to photoinduced thiol-ene reactions, using different thiols with a variety of functional groups. The success of the functionalization reaction was evaluated by NMR, FT-IR spectroscopy, and SEC. In addition, differential scanning calorimetry was used to investigate changes in the thermal properties of the polymer, before and after thiol-ene functionalization.Geranyl acrylate has been synthesized and polymerized by various radical polymerisation techniques.},\n\tnumber = {28},\n\turldate = {2024-07-08},\n\tjournal = {POLYMER CHEMISTRY},\n\tauthor = {Liu, Huizhe and Maugein, Vincent A. and Haddleton, David M.},\n\tmonth = jul,\n\tyear = {2024},\n\tpages = {2862--2872},\n}\n\n","author_short":["Liu, H.","Maugein, V. A.","Haddleton, D. M."],"key":"liu_radical_2024","id":"liu_radical_2024","bibbaseid":"liu-maugein-haddleton-radicalpolymerisationandthiolenepostpolymerisationfunctionalisationofterpenoidacrylatesinconventionalandrenewablysourcedorganicsolvents-2024","role":"author","urls":{},"metadata":{"authorlinks":{}},"html":""},"bibtype":"article","biburl":"https://warwick.ac.uk/fac/cross_fac/wesic/research/wpg/research/WPGsep2024.bib","dataSources":["m4fxWT6XKrYfGbZFR","GBhqMC9hjyD5vqptk","6idaYK6okJY39mWgG"],"keywords":[],"search_terms":["radical","polymerisation","thiol","ene","post","polymerisation","functionalisation","terpenoid","acrylates","conventional","renewably","sourced","organic","solvents","liu","maugein","haddleton"],"title":"Radical polymerisation and thiol-ene post-polymerisation functionalisation of terpenoid acrylates in conventional and renewably sourced organic solvents","year":2024}