@article{lu_hydrogen_2017,
	title = {Hydrogen storage properties of core-shell structured {Mg}@{TM} ({TM} = {Co}, {V}) composites},
	volume = {42},
	issn = {0360-3199},
	url = {https://www.sciencedirect.com/science/article/pii/S036031991731443X},
	doi = {10.1016/j.ijhydene.2017.04.063},
	abstract = {Target improving the hydrogen sorption properties of Mg, core-shell structured Mg@TM (TM = Co, V) composites were synthesized via an approach combining arc plasma method and electroless plating. The core-shell structures with the MgH2 core and V or Co containing hydride shells for hydrogenated Mg@TM particles were observed through HAADF-STEM and HRTEM techniques. The measured hydrogenation enthalpy (ΔHabs = −70.02 kJ/mol H2) and activation energy (Ea = 67.66 kJ/mol H2) of the ternary Mg@Co@V composite were lower than those of binary composites and the pure Mg powder. In addition, the onset dehydrogenation temperature for the hydrogenated ternary composite measured from DSC was 323 °C, about 60 °C lower than that of pure MgH2. On one hand, these improved properties can be attributed to the core-shell structure which may introduce more contacts between catalysts and Mg, thus providing more nucleation sites for hydrogen sorption. On the other hand, the co-effect of MgCo hydrides (Mg2CoH5\&Mg3CoH5) acting as “hydrogen pump” and V2H accelerating the dissociation of H2 might also contribute to the improved hydrogen sorption properties of Mg.},
	language = {en},
	number = {22},
	urldate = {2023-03-13},
	journal = {International Journal of Hydrogen Energy},
	author = {Lu, Chong and Zou, Jianxin and Zeng, Xiaoqin and Ding, Wenjiang},
	month = jun,
	year = {2017},
	note = {review-205},
	keywords = {0},
	pages = {15246--15255},
}

{"_id":"8D2dEqiWsmmYu89nY","bibbaseid":"lu-zou-zeng-ding-hydrogenstoragepropertiesofcoreshellstructuredmgtmtmcovcomposites-2017","author_short":["Lu, C.","Zou, J.","Zeng, X.","Ding, W."],"bibdata":{"bibtype":"article","type":"article","title":"Hydrogen storage properties of core-shell structured Mg@TM (TM = Co, V) composites","volume":"42","issn":"0360-3199","url":"https://www.sciencedirect.com/science/article/pii/S036031991731443X","doi":"10.1016/j.ijhydene.2017.04.063","abstract":"Target improving the hydrogen sorption properties of Mg, core-shell structured Mg@TM (TM = Co, V) composites were synthesized via an approach combining arc plasma method and electroless plating. The core-shell structures with the MgH2 core and V or Co containing hydride shells for hydrogenated Mg@TM particles were observed through HAADF-STEM and HRTEM techniques. The measured hydrogenation enthalpy (ΔHabs = −70.02 kJ/mol H2) and activation energy (Ea = 67.66 kJ/mol H2) of the ternary Mg@Co@V composite were lower than those of binary composites and the pure Mg powder. In addition, the onset dehydrogenation temperature for the hydrogenated ternary composite measured from DSC was 323 °C, about 60 °C lower than that of pure MgH2. On one hand, these improved properties can be attributed to the core-shell structure which may introduce more contacts between catalysts and Mg, thus providing more nucleation sites for hydrogen sorption. On the other hand, the co-effect of MgCo hydrides (Mg2CoH5&Mg3CoH5) acting as “hydrogen pump” and V2H accelerating the dissociation of H2 might also contribute to the improved hydrogen sorption properties of Mg.","language":"en","number":"22","urldate":"2023-03-13","journal":"International Journal of Hydrogen Energy","author":[{"propositions":[],"lastnames":["Lu"],"firstnames":["Chong"],"suffixes":[]},{"propositions":[],"lastnames":["Zou"],"firstnames":["Jianxin"],"suffixes":[]},{"propositions":[],"lastnames":["Zeng"],"firstnames":["Xiaoqin"],"suffixes":[]},{"propositions":[],"lastnames":["Ding"],"firstnames":["Wenjiang"],"suffixes":[]}],"month":"June","year":"2017","note":"review-205","keywords":"0","pages":"15246–15255","bibtex":"@article{lu_hydrogen_2017,\n\ttitle = {Hydrogen storage properties of core-shell structured {Mg}@{TM} ({TM} = {Co}, {V}) composites},\n\tvolume = {42},\n\tissn = {0360-3199},\n\turl = {https://www.sciencedirect.com/science/article/pii/S036031991731443X},\n\tdoi = {10.1016/j.ijhydene.2017.04.063},\n\tabstract = {Target improving the hydrogen sorption properties of Mg, core-shell structured Mg@TM (TM = Co, V) composites were synthesized via an approach combining arc plasma method and electroless plating. The core-shell structures with the MgH2 core and V or Co containing hydride shells for hydrogenated Mg@TM particles were observed through HAADF-STEM and HRTEM techniques. The measured hydrogenation enthalpy (ΔHabs = −70.02 kJ/mol H2) and activation energy (Ea = 67.66 kJ/mol H2) of the ternary Mg@Co@V composite were lower than those of binary composites and the pure Mg powder. In addition, the onset dehydrogenation temperature for the hydrogenated ternary composite measured from DSC was 323 °C, about 60 °C lower than that of pure MgH2. On one hand, these improved properties can be attributed to the core-shell structure which may introduce more contacts between catalysts and Mg, thus providing more nucleation sites for hydrogen sorption. On the other hand, the co-effect of MgCo hydrides (Mg2CoH5\\&Mg3CoH5) acting as “hydrogen pump” and V2H accelerating the dissociation of H2 might also contribute to the improved hydrogen sorption properties of Mg.},\n\tlanguage = {en},\n\tnumber = {22},\n\turldate = {2023-03-13},\n\tjournal = {International Journal of Hydrogen Energy},\n\tauthor = {Lu, Chong and Zou, Jianxin and Zeng, Xiaoqin and Ding, Wenjiang},\n\tmonth = jun,\n\tyear = {2017},\n\tnote = {review-205},\n\tkeywords = {0},\n\tpages = {15246--15255},\n}\n\n","author_short":["Lu, C.","Zou, J.","Zeng, X.","Ding, W."],"key":"lu_hydrogen_2017","id":"lu_hydrogen_2017","bibbaseid":"lu-zou-zeng-ding-hydrogenstoragepropertiesofcoreshellstructuredmgtmtmcovcomposites-2017","role":"author","urls":{"Paper":"https://www.sciencedirect.com/science/article/pii/S036031991731443X"},"keyword":["0"],"metadata":{"authorlinks":{}},"html":""},"bibtype":"article","biburl":"https://bibbase.org/zotero/peterschindler","dataSources":["u74ybRJPx8HT8EPuM"],"keywords":["0"],"search_terms":["hydrogen","storage","properties","core","shell","structured","composites","lu","zou","zeng","ding"],"title":"Hydrogen storage properties of core-shell structured Mg@TM (TM = Co, V) composites","year":2017}