Synthesis of carbohydrate derivatives using solid-phase work-up and scavenging techniques. MacCoss, R., N., Brennan, P., E., & Ley, S., V. Organic and Biomolecular Chemistry, 1(12):2029-2031, Royal Society of Chemistry, 2003.
Synthesis of carbohydrate derivatives using solid-phase work-up and scavenging techniques [pdf]Paper  Synthesis of carbohydrate derivatives using solid-phase work-up and scavenging techniques [link]Website  doi  abstract   bibtex   
Methods to allow the clean prepn. of oligosaccharides were investigated using techniques that do not require conventional column chromatog. or an aq. work-up. The route was designed to provide rapid access to oligosaccharides and is suitable for automation and parallel library formation. The research has focused on the glycosidations of a range of glycosyl acceptors with various selenophenyl glycosyl donors using iodine as an activator in the presence of DTBMP, a hindered org. base. Hydroxyl-contg. contaminants were removed by scavenging with polymer-supported tosyl chloride. [on SciFinder(R)]

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