{"_id":"KNs32tEs9obowWp6F","bibbaseid":"mahbub-adios-xu-prakoso-lebeau-sumboja-redbeanpodderivedheterostructurecarbondecoratedwithhollowmixedtransitionmetalsasabifunctionalcatalystinznairbatteries-2021","author_short":["Mahbub, M. A. A.","Adios, C. G.","Xu, M.","Prakoso, B.","LeBeau, J. M","Sumboja, A."],"bibdata":{"bibtype":"article","type":"article","title":"Red Bean Pod Derived Heterostructure Carbon Decorated with Hollow Mixed Transition Metals as a Bifunctional Catalyst in Zn-Air Batteries","author":[{"propositions":[],"lastnames":["Mahbub"],"firstnames":["Muhammad","Adib","Abdillah"],"suffixes":[]},{"propositions":[],"lastnames":["Adios"],"firstnames":["Celfi","Gustine"],"suffixes":[]},{"propositions":[],"lastnames":["Xu"],"firstnames":["Michael"],"suffixes":[]},{"propositions":[],"lastnames":["Prakoso"],"firstnames":["Bagas"],"suffixes":[]},{"propositions":[],"lastnames":["LeBeau"],"firstnames":["James","M"],"suffixes":[]},{"propositions":[],"lastnames":["Sumboja"],"firstnames":["Afriyanti"],"suffixes":[]}],"journal":"Chem. Asian J.","publisher":"John Wiley and Sons Ltd","volume":"16","pages":"2559–2567","abstract":"Design and synthesis of low-cost and efficient bifunctional catalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in Zn-air batteries are essential and challenging. We report a facile method to synthesize heterostructure carbon consisting of graphitic and amorphous carbon derived from the agricultural waste of red bean pods. The heterostructure carbon possesses a large surface area of 625.5 m2 g-1 , showing ORR onset potential of 0.89 V vs. RHE and OER overpotential of 470 mV at 5 mA cm-2 . Introducing hollow FeCo nanoparticles and nitrogen dopant improves the bifunctional catalytic activity of the carbon, delivering ORR onset potential of 0.93 V vs. RHE and OER overpotential of 360 mV. Electron energy-loss spectroscopy (EELS) O K-edge map suggests the presence of localized oxygen on the FeCo nanoparticles, suggesting the oxidation of the nanoparticles. Zn-air battery with these carbon-based catalysts exhibits a peak power density as high as 116.2 mW cm-2 and stable cycling performance over 210 discharge/charge cycles. This work contributes to the advancement of bifunctional oxygen electrocatalysts while converting agricultural waste into value-added material.","month":"1 September","year":"2021","keywords":"Biomass-derived carbon; FeCo; electrocatalysis; metal-air batteries; non-precious metal catalyst;LeBeau Group","doi":"10.1002/asia.202100702","pmid":"34382330","bibtex":"@ARTICLE{Mahbub2021-ph,\n title = \"Red Bean Pod Derived Heterostructure Carbon Decorated with Hollow\n Mixed Transition Metals as a Bifunctional Catalyst in Zn-Air\n Batteries\",\n author = \"Mahbub, Muhammad Adib Abdillah and Adios, Celfi Gustine and Xu,\n Michael and Prakoso, Bagas and LeBeau, James M and Sumboja,\n Afriyanti\",\n journal = \"Chem. Asian J.\",\n publisher = \"John Wiley and Sons Ltd\",\n volume = 16,\n pages = \"2559--2567\",\n abstract = \"Design and synthesis of low-cost and efficient bifunctional\n catalysts for oxygen reduction reaction (ORR) and oxygen\n evolution reaction (OER) in Zn-air batteries are essential and\n challenging. We report a facile method to synthesize\n heterostructure carbon consisting of graphitic and amorphous\n carbon derived from the agricultural waste of red bean pods. The\n heterostructure carbon possesses a large surface area of 625.5 m2\n g-1 , showing ORR onset potential of 0.89 V vs. RHE and OER\n overpotential of 470 mV at 5 mA cm-2 . Introducing hollow FeCo\n nanoparticles and nitrogen dopant improves the bifunctional\n catalytic activity of the carbon, delivering ORR onset potential\n of 0.93 V vs. RHE and OER overpotential of 360 mV. Electron\n energy-loss spectroscopy (EELS) O K-edge map suggests the\n presence of localized oxygen on the FeCo nanoparticles,\n suggesting the oxidation of the nanoparticles. Zn-air battery\n with these carbon-based catalysts exhibits a peak power density\n as high as 116.2 mW cm-2 and stable cycling performance over 210\n discharge/charge cycles. This work contributes to the advancement\n of bifunctional oxygen electrocatalysts while converting\n agricultural waste into value-added material.\",\n month = \"1~\" # sep,\n year = 2021,\n keywords = \"Biomass-derived carbon; FeCo; electrocatalysis; metal-air\n batteries; non-precious metal catalyst;LeBeau Group\",\n doi = \"10.1002/asia.202100702\",\n pmid = 34382330\n}\n\n","author_short":["Mahbub, M. A. A.","Adios, C. G.","Xu, M.","Prakoso, B.","LeBeau, J. M","Sumboja, A."],"key":"Mahbub2021-ph","id":"Mahbub2021-ph","bibbaseid":"mahbub-adios-xu-prakoso-lebeau-sumboja-redbeanpodderivedheterostructurecarbondecoratedwithhollowmixedtransitionmetalsasabifunctionalcatalystinznairbatteries-2021","role":"author","urls":{},"keyword":["Biomass-derived carbon; FeCo; electrocatalysis; metal-air batteries; non-precious metal catalyst;LeBeau Group"],"metadata":{"authorlinks":{}},"downloads":4},"bibtype":"article","biburl":"https://paperpile.com/eb/hvQdZzcQAp","dataSources":["XvQYbdoqrgtkncm5N","T6bwdcdAx2jmtGv5a"],"keywords":["biomass-derived carbon; feco; electrocatalysis; metal-air batteries; non-precious metal catalyst;lebeau group"],"search_terms":["red","bean","pod","derived","heterostructure","carbon","decorated","hollow","mixed","transition","metals","bifunctional","catalyst","air","batteries","mahbub","adios","xu","prakoso","lebeau","sumboja"],"title":"Red Bean Pod Derived Heterostructure Carbon Decorated with Hollow Mixed Transition Metals as a Bifunctional Catalyst in Zn-Air Batteries","year":2021,"downloads":4}