Unparalleled selectivity and electronic structure of heterometallic [LnLn′Ln] molecules as 3-qubit quantum gates

Unparalleled selectivity and electronic structure of heterometallic [LnLn′Ln] molecules as 3-qubit quantum gates. Maniaki, D., Garay-Ruiz, D., Barrios, L. A., Martins, D. O. T. A., Aguilà, D., Tuna, F., Reta, D., Roubeau, O., Bo, C., & Aromí, G. Chemical Science, 13(19):5574–5581, The Royal Society of Chemistry, May, 2022.

Paper doi abstract bibtex

Heterometallic lanthanide [LnLn′] coordination complexes that are accessible thermodynamically are very scarce because the metals of this series have very similar chemical behaviour. Trinuclear systems of this category have not been reported. A coordination chemistry scaffold has been shown to produce molecules of type [LnLn′Ln] of high purity, i.e. exhibiting high metal distribution ability, based on their differences in ionic radius. Through a detailed analysis of density functional theory (DFT) based calculations, we discern the energy contributions that lead to the unparalleled chemical selectivity of this molecular system. Some of the previously reported examples are compared here with the newly prepared member of this exotic list, [Er2Pr(LA)2(LB)2(py)(H2O)2](NO3) (1) (H2LA and H2LB are two β-diketone ligands). A magnetic analysis extracted from magnetization and calorimetry determinations identifies the necessary attributes for it to act as an addressable, conditional multiqubit spin-based quantum gate. Complementary ab initio calculations confirm the feasibility of these complexes as composite quantum gates, since they present well-isolated ground states with highly anisotropic and distinct g-tensors. The electronic structure of 1 has also been analyzed by EPR. Pulsed experiments have allowed the establishment of the quantum coherence of the transitions within the relevant spin states, as well as the feasibility of a coherent control of these states via nutation experiments.

@article{maniaki_unparalleled_2022,
	title = {Unparalleled selectivity and electronic structure of heterometallic [{LnLn}′{Ln}] molecules as 3-qubit quantum gates},
	volume = {13},
	issn = {2041-6539},
	url = {https://pubs.rsc.org/en/content/articlelanding/2022/sc/d2sc00436d},
	doi = {10.1039/D2SC00436D},
	abstract = {Heterometallic lanthanide [LnLn′] coordination complexes that are accessible thermodynamically are very scarce because the metals of this series have very similar chemical behaviour. Trinuclear systems of this category have not been reported. A coordination chemistry scaffold has been shown to produce molecules of type [LnLn′Ln] of high purity, i.e. exhibiting high metal distribution ability, based on their differences in ionic radius. Through a detailed analysis of density functional theory (DFT) based calculations, we discern the energy contributions that lead to the unparalleled chemical selectivity of this molecular system. Some of the previously reported examples are compared here with the newly prepared member of this exotic list, [Er2Pr(LA)2(LB)2(py)(H2O)2](NO3) (1) (H2LA and H2LB are two β-diketone ligands). A magnetic analysis extracted from magnetization and calorimetry determinations identifies the necessary attributes for it to act as an addressable, conditional multiqubit spin-based quantum gate. Complementary ab initio calculations confirm the feasibility of these complexes as composite quantum gates, since they present well-isolated ground states with highly anisotropic and distinct g-tensors. The electronic structure of 1 has also been analyzed by EPR. Pulsed experiments have allowed the establishment of the quantum coherence of the transitions within the relevant spin states, as well as the feasibility of a coherent control of these states via nutation experiments.},
	language = {en},
	number = {19},
	urldate = {2024-04-18},
	journal = {Chemical Science},
	publisher = {The Royal Society of Chemistry},
	author = {Maniaki, Diamantoula and Garay-Ruiz, Diego and Barrios, Leoní A. and Martins, Daniel O. T. A. and Aguilà, David and Tuna, Floriana and Reta, Daniel and Roubeau, Olivier and Bo, Carles and Aromí, Guillem},
	month = may,
	year = {2022},
	pages = {5574--5581},
}

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