Dihydrolevoglucosenone (Cyrene™) as a bio-renewable solvent for Cu(0)wire-mediated reversible deactivation radical polymerization (RDRP) without external deoxygenation. Marathianos, A., Liarou, E., Hancox, E., Grace, J. L., Lester, D. W., & Haddleton, D. M. GREEN CHEMISTRY, 22(17):5833–5837, September, 2020. doi abstract bibtex Biorenewable dihydrolevoglucosenone (Cyrene (TM)) is used as an effective dipolar aprotic solvent for Cu(0) wire-mediated RDRP of various monomers without external deoxygenation being applied. The solvent is used to give products with a broad range of molar masses (M-n similar to 700-28 000),in situchain extension and as low as 7.8 x 10(-4)eq. of [Cu(ii)Br-2] relative to initiator.
@article{marathianos_dihydrolevoglucosenone_2020,
title = {Dihydrolevoglucosenone ({Cyrene}™) as a bio-renewable solvent for {Cu}(0)wire-mediated reversible deactivation radical polymerization ({RDRP}) without external deoxygenation},
volume = {22},
issn = {1463-9262},
doi = {10.1039/d0gc02184a},
abstract = {Biorenewable dihydrolevoglucosenone (Cyrene (TM)) is used as an effective dipolar aprotic solvent for Cu(0) wire-mediated RDRP of various monomers without external deoxygenation being applied. The solvent is used to give products with a broad range of molar masses (M-n similar to 700-28 000),in situchain extension and as low as 7.8 x 10(-4)eq. of [Cu(ii)Br-2] relative to initiator.},
number = {17},
urldate = {2020-09-15},
journal = {GREEN CHEMISTRY},
author = {Marathianos, Arkadios and Liarou, Evelina and Hancox, Ellis and Grace, James L. and Lester, Daniel W. and Haddleton, David M.},
month = sep,
year = {2020},
pages = {5833--5837},
}
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