Sulfur K-edge XAS as a probe of sulfur-centered radical intermediates.

Sulfur K-edge XAS as a probe of sulfur-centered radical intermediates. Martin-Diaconescu, V. & Kennepohl, P. J. Am. Chem. Soc., 129(11):3034-5, 3, 2007.

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Sulfur K-edge XAS as a probe of sulfur-centered radical intermediates. [link]

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Sulfur K-edge XAS is used in the identification and characterization of sulfur based radicals obtained from UV irradiated glutathione. Ground state and time-dependent DFT calculations are used to identify thiyl (RS center dot) and perthiyl (RSS center dot) radical species.

@article{
 title = {Sulfur K-edge XAS as a probe of sulfur-centered radical intermediates.},
 type = {article},
 year = {2007},
 keywords = {DFT,SSRL,X-ray Absorption Spectroscopy,photochemistry,sulfur redox},
 pages = {3034-5},
 volume = {129},
 websites = {http://www.ncbi.nlm.nih.gov/pubmed/17319664},
 month = {3},
 day = {21},
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 created = {2017-09-06T15:14:53.458Z},
 accessed = {2011-11-03},
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 last_modified = {2020-04-22T14:44:15.599Z},
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 abstract = {Sulfur K-edge XAS is used in the identification and characterization of sulfur based radicals obtained from UV irradiated glutathione. Ground state and time-dependent DFT calculations are used to identify thiyl (RS center dot) and perthiyl (RSS center dot) radical species.},
 bibtype = {article},
 author = {Martin-Diaconescu, Vlad and Kennepohl, Pierre},
 doi = {10.1021/ja0676760},
 journal = {J. Am. Chem. Soc.},
 number = {11}
}

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