@article{
 title = {Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes.},
 type = {article},
 year = {2010},
 identifiers = {[object Object]},
 keywords = {*Hydroxyl Radical,Aerosols,Aerosols/chemistry,Aerosols: chemistry,Alkenes,Alkenes/*chemistry,Alkenes: chemistry,Ammonia,Ammonia/chemistry,Ammonia: chemistry,Atmosphere,Carbon,Carbon/chemistry,Carbon: chemistry,Chemical,Chemistry,Chromatography,Environmental Monitoring,Environmental Monitoring/methods,Environmental Monitoring: methods,High Pressure Liquid,High Pressure Liquid/methods,High Pressure Liquid: methods,Hydroxyl Radical,Mass Spectrometry,Mass Spectrometry/methods,Mass Spectrometry: methods,Models,Nitrates,Nitrates/*chemistry,Nitrates: chemistry,Organic,Organic/methods,Organic: methods,Particle Size,Ultraviolet Rays,Water,Water/chemistry,Water: chemistry},
 pages = {6664-6669},
 volume = {107},
 websites = {http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=2872378&tool=pmcentrez&rendertype=abstract,http://www.ncbi.nlm.nih.gov/pubmed/20080570},
 month = {4},
 day = {13},
 edition = {2010/01/19},
 id = {ed2248e9-15ec-3605-95cf-1651be7ffd2f},
 created = {2015-10-30T20:07:32.000Z},
 accessed = {2013-05-28},
 file_attached = {true},
 profile_id = {5a758209-74fb-3a9c-b322-2ae7f22f7b6c},
 group_id = {63e349d6-2c70-3938-9e67-2f6483f6cbab},
 last_modified = {2015-10-30T20:22:36.000Z},
 read = {false},
 starred = {false},
 authored = {false},
 confirmed = {true},
 hidden = {false},
 source_type = {Journal Article},
 language = {eng},
 notes = {<b>From Duplicate 2 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, Aiko; Ziemann, Paul J)<br/></b><br/><b>From Duplicate 1 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, Aiko; Ziemann, Paul J)<br/></b><br/><b>From Duplicate 2 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, Aiko; Ziemann, Paul J)<br/></b><br/><b>From Duplicate 2 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, A; Ziemann, P J)<br/>And Duplicate 3 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, A; Ziemann, P J)<br/></b><br/>Matsunaga, Aiko<br/>Ziemann, Paul J<br/>Research Support, U.S. Gov't, Non-P.H.S.<br/>United States<br/>Proceedings of the National Academy of Sciences of the United States of America<br/>Proc Natl Acad Sci U S A. 2010 Apr 13;107(15):6664-9. doi: 10.1073/pnas.0910585107. Epub 2009 Dec 31.},
 abstract = {Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates, in particles formed from OH radical-initiated reactions of C(9)-C(15) 2-methyl-1-alkenes in the presence of NO(x) were measured by using a thermal desorption particle beam mass spectrometer coupled to a high-performance liquid chromatograph with a UV-visible (UV-vis) detector. Yields of beta-hydroxynitrates and dihydroxynitrates increased with carbon number primarily due to enhanced gas-to-particle partitioning before reaching plateaus at approximately C(14)-C(15), where the compounds were essentially entirely in the particle phase. Plateau yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates were 0.183 +/- 0.005, 0.045 +/- 0.005, and 0.034 +/- 0.005, and, after normalization for OH radical addition to the C = C double bond, were 0.225 +/- 0.007, 0.055 +/- 0.006, and 0.042 +/- 0.006. The fractions of 1-hydroxy and 2-hydroxy beta-hydroxynitrate isomers were 0.90/0.10. Yields measured here and in our previous study of reactions of linear internal alkenes and linear 1-alkenes indicate that, for these alkene classes, the relative branching ratios for forming tertiary, secondary, and primary beta-hydroxyalkyl radicals by OH radical addition to the C=C double bond are 4.3/1.9/1.0, and the branching ratios for forming beta-hydroxynitrates from reactions of tertiary, secondary, and primary beta-hydroxyperoxy radicals with NO are 0.25, 0.15, and 0.12. The effects of H(2)O vapor and NH(3) on yields were also explored.},
 bibtype = {article},
 author = {Matsunaga, Aiko and Ziemann, Paul J},
 journal = {Proceedings of the National Academy of Sciences of the United States of America},
 number = {15}
}

{"_id":"2qtLpDZWBYtyE9D7A","bibbaseid":"matsunaga-ziemann-yieldsofbetahydroxynitratesdihydroxynitratesandtrihydroxynitratesformedfromohradicalinitiatedreactionsof2methyl1alkenes-2010","downloads":0,"creationDate":"2017-01-12T21:32:12.447Z","title":"Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes.","author_short":["Matsunaga, A.","Ziemann, P., J."],"year":2010,"bibtype":"article","biburl":null,"bibdata":{"title":"Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes.","type":"article","year":"2010","identifiers":"[object Object]","keywords":"*Hydroxyl Radical,Aerosols,Aerosols/chemistry,Aerosols: chemistry,Alkenes,Alkenes/*chemistry,Alkenes: chemistry,Ammonia,Ammonia/chemistry,Ammonia: chemistry,Atmosphere,Carbon,Carbon/chemistry,Carbon: chemistry,Chemical,Chemistry,Chromatography,Environmental Monitoring,Environmental Monitoring/methods,Environmental Monitoring: methods,High Pressure Liquid,High Pressure Liquid/methods,High Pressure Liquid: methods,Hydroxyl Radical,Mass Spectrometry,Mass Spectrometry/methods,Mass Spectrometry: methods,Models,Nitrates,Nitrates/*chemistry,Nitrates: chemistry,Organic,Organic/methods,Organic: methods,Particle Size,Ultraviolet Rays,Water,Water/chemistry,Water: chemistry","pages":"6664-6669","volume":"107","websites":"http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=2872378&tool=pmcentrez&rendertype=abstract,http://www.ncbi.nlm.nih.gov/pubmed/20080570","month":"4","day":"13","edition":"2010/01/19","id":"ed2248e9-15ec-3605-95cf-1651be7ffd2f","created":"2015-10-30T20:07:32.000Z","accessed":"2013-05-28","file_attached":"true","profile_id":"5a758209-74fb-3a9c-b322-2ae7f22f7b6c","group_id":"63e349d6-2c70-3938-9e67-2f6483f6cbab","last_modified":"2015-10-30T20:22:36.000Z","read":false,"starred":false,"authored":false,"confirmed":"true","hidden":false,"source_type":"Journal Article","language":"eng","notes":"<b>From Duplicate 2 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, Aiko; Ziemann, Paul J)<br/></b><br/><b>From Duplicate 1 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, Aiko; Ziemann, Paul J)<br/></b><br/><b>From Duplicate 2 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, Aiko; Ziemann, Paul J)<br/></b><br/><b>From Duplicate 2 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, A; Ziemann, P J)<br/>And Duplicate 3 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, A; Ziemann, P J)<br/></b><br/>Matsunaga, Aiko<br/>Ziemann, Paul J<br/>Research Support, U.S. Gov't, Non-P.H.S.<br/>United States<br/>Proceedings of the National Academy of Sciences of the United States of America<br/>Proc Natl Acad Sci U S A. 2010 Apr 13;107(15):6664-9. doi: 10.1073/pnas.0910585107. Epub 2009 Dec 31.","abstract":"Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates, in particles formed from OH radical-initiated reactions of C(9)-C(15) 2-methyl-1-alkenes in the presence of NO(x) were measured by using a thermal desorption particle beam mass spectrometer coupled to a high-performance liquid chromatograph with a UV-visible (UV-vis) detector. Yields of beta-hydroxynitrates and dihydroxynitrates increased with carbon number primarily due to enhanced gas-to-particle partitioning before reaching plateaus at approximately C(14)-C(15), where the compounds were essentially entirely in the particle phase. Plateau yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates were 0.183 +/- 0.005, 0.045 +/- 0.005, and 0.034 +/- 0.005, and, after normalization for OH radical addition to the C = C double bond, were 0.225 +/- 0.007, 0.055 +/- 0.006, and 0.042 +/- 0.006. The fractions of 1-hydroxy and 2-hydroxy beta-hydroxynitrate isomers were 0.90/0.10. Yields measured here and in our previous study of reactions of linear internal alkenes and linear 1-alkenes indicate that, for these alkene classes, the relative branching ratios for forming tertiary, secondary, and primary beta-hydroxyalkyl radicals by OH radical addition to the C=C double bond are 4.3/1.9/1.0, and the branching ratios for forming beta-hydroxynitrates from reactions of tertiary, secondary, and primary beta-hydroxyperoxy radicals with NO are 0.25, 0.15, and 0.12. The effects of H(2)O vapor and NH(3) on yields were also explored.","bibtype":"article","author":"Matsunaga, Aiko and Ziemann, Paul J","journal":"Proceedings of the National Academy of Sciences of the United States of America","number":"15","bibtex":"@article{\n title = {Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes.},\n type = {article},\n year = {2010},\n identifiers = {[object Object]},\n keywords = {*Hydroxyl Radical,Aerosols,Aerosols/chemistry,Aerosols: chemistry,Alkenes,Alkenes/*chemistry,Alkenes: chemistry,Ammonia,Ammonia/chemistry,Ammonia: chemistry,Atmosphere,Carbon,Carbon/chemistry,Carbon: chemistry,Chemical,Chemistry,Chromatography,Environmental Monitoring,Environmental Monitoring/methods,Environmental Monitoring: methods,High Pressure Liquid,High Pressure Liquid/methods,High Pressure Liquid: methods,Hydroxyl Radical,Mass Spectrometry,Mass Spectrometry/methods,Mass Spectrometry: methods,Models,Nitrates,Nitrates/*chemistry,Nitrates: chemistry,Organic,Organic/methods,Organic: methods,Particle Size,Ultraviolet Rays,Water,Water/chemistry,Water: chemistry},\n pages = {6664-6669},\n volume = {107},\n websites = {http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=2872378&tool=pmcentrez&rendertype=abstract,http://www.ncbi.nlm.nih.gov/pubmed/20080570},\n month = {4},\n day = {13},\n edition = {2010/01/19},\n id = {ed2248e9-15ec-3605-95cf-1651be7ffd2f},\n created = {2015-10-30T20:07:32.000Z},\n accessed = {2013-05-28},\n file_attached = {true},\n profile_id = {5a758209-74fb-3a9c-b322-2ae7f22f7b6c},\n group_id = {63e349d6-2c70-3938-9e67-2f6483f6cbab},\n last_modified = {2015-10-30T20:22:36.000Z},\n read = {false},\n starred = {false},\n authored = {false},\n confirmed = {true},\n hidden = {false},\n source_type = {Journal Article},\n language = {eng},\n notes = {<b>From Duplicate 2 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, Aiko; Ziemann, Paul J)<br/></b><br/><b>From Duplicate 1 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, Aiko; Ziemann, Paul J)<br/></b><br/><b>From Duplicate 2 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, Aiko; Ziemann, Paul J)<br/></b><br/><b>From Duplicate 2 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, A; Ziemann, P J)<br/>And Duplicate 3 (<i>Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates formed from OH radical-initiated reactions of 2-methyl-1-alkenes</i> - Matsunaga, A; Ziemann, P J)<br/></b><br/>Matsunaga, Aiko<br/>Ziemann, Paul J<br/>Research Support, U.S. Gov't, Non-P.H.S.<br/>United States<br/>Proceedings of the National Academy of Sciences of the United States of America<br/>Proc Natl Acad Sci U S A. 2010 Apr 13;107(15):6664-9. doi: 10.1073/pnas.0910585107. Epub 2009 Dec 31.},\n abstract = {Yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates, in particles formed from OH radical-initiated reactions of C(9)-C(15) 2-methyl-1-alkenes in the presence of NO(x) were measured by using a thermal desorption particle beam mass spectrometer coupled to a high-performance liquid chromatograph with a UV-visible (UV-vis) detector. Yields of beta-hydroxynitrates and dihydroxynitrates increased with carbon number primarily due to enhanced gas-to-particle partitioning before reaching plateaus at approximately C(14)-C(15), where the compounds were essentially entirely in the particle phase. Plateau yields of beta-hydroxynitrates, dihydroxynitrates, and trihydroxynitrates were 0.183 +/- 0.005, 0.045 +/- 0.005, and 0.034 +/- 0.005, and, after normalization for OH radical addition to the C = C double bond, were 0.225 +/- 0.007, 0.055 +/- 0.006, and 0.042 +/- 0.006. The fractions of 1-hydroxy and 2-hydroxy beta-hydroxynitrate isomers were 0.90/0.10. Yields measured here and in our previous study of reactions of linear internal alkenes and linear 1-alkenes indicate that, for these alkene classes, the relative branching ratios for forming tertiary, secondary, and primary beta-hydroxyalkyl radicals by OH radical addition to the C=C double bond are 4.3/1.9/1.0, and the branching ratios for forming beta-hydroxynitrates from reactions of tertiary, secondary, and primary beta-hydroxyperoxy radicals with NO are 0.25, 0.15, and 0.12. The effects of H(2)O vapor and NH(3) on yields were also explored.},\n bibtype = {article},\n author = {Matsunaga, Aiko and Ziemann, Paul J},\n journal = {Proceedings of the National Academy of Sciences of the United States of America},\n number = {15}\n}","author_short":["Matsunaga, A.","Ziemann, P., J."],"urls":{"Paper":"http://bibbase.org/service/mendeley/9edae5ec-3a23-3830-8934-2c27bef6ccbe/file/54b6c440-547c-de0b-6597-af7d7c2b9c2a/2010-Yields_of_beta-hydroxynitrates_dihydroxynitrates_and_trihydroxynitrates_formed_from_OH_radical-initiated_reactions_.pdf.pdf","Website":"http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=2872378&tool=pmcentrez&rendertype=abstract,http://www.ncbi.nlm.nih.gov/pubmed/20080570"},"bibbaseid":"matsunaga-ziemann-yieldsofbetahydroxynitratesdihydroxynitratesandtrihydroxynitratesformedfromohradicalinitiatedreactionsof2methyl1alkenes-2010","role":"author","keyword":["*Hydroxyl Radical","Aerosols","Aerosols/chemistry","Aerosols: chemistry","Alkenes","Alkenes/*chemistry","Alkenes: chemistry","Ammonia","Ammonia/chemistry","Ammonia: chemistry","Atmosphere","Carbon","Carbon/chemistry","Carbon: chemistry","Chemical","Chemistry","Chromatography","Environmental Monitoring","Environmental Monitoring/methods","Environmental Monitoring: methods","High Pressure Liquid","High Pressure Liquid/methods","High Pressure Liquid: methods","Hydroxyl Radical","Mass Spectrometry","Mass Spectrometry/methods","Mass Spectrometry: methods","Models","Nitrates","Nitrates/*chemistry","Nitrates: chemistry","Organic","Organic/methods","Organic: methods","Particle Size","Ultraviolet Rays","Water","Water/chemistry","Water: chemistry"],"downloads":0},"search_terms":["yields","beta","hydroxynitrates","dihydroxynitrates","trihydroxynitrates","formed","radical","initiated","reactions","methyl","alkenes","matsunaga","ziemann"],"keywords":["*hydroxyl radical","aerosols","aerosols/chemistry","aerosols: chemistry","alkenes","alkenes/*chemistry","alkenes: chemistry","ammonia","ammonia/chemistry","ammonia: chemistry","atmosphere","carbon","carbon/chemistry","carbon: chemistry","chemical","chemistry","chromatography","environmental monitoring","environmental monitoring/methods","environmental monitoring: methods","high pressure liquid","high pressure liquid/methods","high pressure liquid: methods","hydroxyl radical","mass spectrometry","mass spectrometry/methods","mass spectrometry: methods","models","nitrates","nitrates/*chemistry","nitrates: chemistry","organic","organic/methods","organic: methods","particle size","ultraviolet rays","water","water/chemistry","water: chemistry"],"authorIDs":[]}