Paths to Attenuate Radiolysis-Induced Secondary Damage in Biological CryoEM. Mecklenburg, M., Nia, S. S, Saha, A., & Hong Zhou, Z Microscopy and Microanalysis, 30(Supplement_1):ozae044.877, July, 2024.
doi  abstract   bibtex   
The imaging electrons in a transmission electron microscope are a beam of bond-breaking beta-radiation. Imaging soft materials is a challenge because of beam damage and poor contrast between the substrate and specimen. Typically, only 10-100 electrons can strike an atomically sized area before disintegration [1]. Peptide, hydrogen, disulfide bonds etc. are all irreparably broken by radiolysis while being simultaneously imaged. The total dose for loss of useful information is roughly the Henderson limit (often accumulated in a few seconds, see Figure 1), about 20 MGy [2], which is roughly 9 orders of magnitude larger than an average person receives per year [3]. This primary damage cannot be abated in small molecules, protein, or virus samples. In addition, unlike the case for x-rays, the inelastic scattering is more likely than elastic scattering for elements in atomic number less than about iron [4]. This leads to poor contrast using parallel beam imaging modalities.
@article{mecklenburgPathsAttenuateRadiolysisInduced2024,
  title = {Paths to {{Attenuate Radiolysis-Induced Secondary Damage}} in {{Biological CryoEM}}},
  author = {Mecklenburg, Matthew and Nia, Shervin S and Saha, Ambarneil and Hong Zhou, Z},
  year = {2024},
  month = jul,
  journal = {Microscopy and Microanalysis},
  volume = {30},
  number = {Supplement\_1},
  pages = {ozae044.877},
  issn = {1431-9276},
  doi = {10.1093/mam/ozae044.877},
  urldate = {2025-04-04},
  abstract = {The imaging electrons in a transmission electron microscope are a beam of bond-breaking beta-radiation. Imaging soft materials is a challenge because of beam damage and poor contrast between the substrate and specimen. Typically, only 10-100 electrons can strike an atomically sized area before disintegration [1]. Peptide, hydrogen, disulfide bonds etc. are all irreparably broken by radiolysis while being simultaneously imaged. The total dose for loss of useful information is roughly the Henderson limit (often accumulated in a few seconds, see Figure 1), about 20 MGy [2], which is roughly 9 orders of magnitude larger than an average person receives per year [3]. This primary damage cannot be abated in small molecules, protein, or virus samples. In addition, unlike the case for x-rays, the inelastic scattering is more likely than elastic scattering for elements in atomic number less than about iron [4]. This leads to poor contrast using parallel beam imaging modalities.},
  file = {C\:\\Users\\shervinnia\\Zotero\\storage\\ZXD7QZSK\\Mecklenburg et al. - 2024 - Paths to Attenuate Radiolysis-Induced Secondary Damage in Biological CryoEM.pdf;C\:\\Users\\shervinnia\\Zotero\\storage\\C67US3J9\\7720210.html}
}

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