Effect of the substitution Ba.tautm.Sr on the Ga-1222 superstructure: an electron diffraction study. Milat, O., Van Tendeloo, G., Amelinckx, S., Wright, A., J., & Greaves, C. Chemistry of Materials, 7(9):1709-1715, AMER CHEMICAL SOC, 1995.
Effect of the substitution Ba.tautm.Sr on the Ga-1222 superstructure: an electron diffraction study [link]Website  abstract   bibtex   
The superstructure of the RE(2)(Sr0.85-xBaxNd0.15)(2)GaCU2O9 compound is found to change significantly with increasing substitution of Ba for Sr. Most of the changes take place in the (Sr0.85-xBaxNd0.15)O-GaO-(Sr0.85-xBaxNd0.15)O lamella, the rest of the basic structure being hardly affected. The structural changes for O less than or equal to x less than or equal to 0.65 are studied by electron diffraction. The arrangement of the chains of GaO4 tetrahedra in the Ba-free compound becomes disordered at x > 0.25. At x similar to 0.65 a rearrangement of the chains in the GaO layers takes place; they form a meandering arrangement, which can be described on a 4a(p) x 2a(p) x c(p) superlattice. This rearrangement is accompanied by ordering of Ba and Sr atoms in the adjacent (ST0.85-xBaxNd0.15)O layers. A simple scheme is proposed to explain the influence of the substitution of Ba for Sr on the linking of the GaO4 tetrahedra and on the geometry of the `'chains'' in the GaO layer.
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 title = {Effect of the substitution Ba.tautm.Sr on the Ga-1222 superstructure: an electron diffraction study},
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 year = {1995},
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 pages = {1709-1715},
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 abstract = {The superstructure of the RE(2)(Sr0.85-xBaxNd0.15)(2)GaCU2O9 compound is found to change significantly with increasing substitution of Ba for Sr. Most of the changes take place in the (Sr0.85-xBaxNd0.15)O-GaO-(Sr0.85-xBaxNd0.15)O lamella, the rest of the basic structure being hardly affected. The structural changes for O less than or equal to x less than or equal to 0.65 are studied by electron diffraction. The arrangement of the chains of GaO4 tetrahedra in the Ba-free compound becomes disordered at x > 0.25. At x similar to 0.65 a rearrangement of the chains in the GaO layers takes place; they form a meandering arrangement, which can be described on a 4a(p) x 2a(p) x c(p) superlattice. This rearrangement is accompanied by ordering of Ba and Sr atoms in the adjacent (ST0.85-xBaxNd0.15)O layers. A simple scheme is proposed to explain the influence of the substitution of Ba for Sr on the linking of the GaO4 tetrahedra and on the geometry of the `'chains'' in the GaO layer.},
 bibtype = {article},
 author = {Milat, Ognjen and Van Tendeloo, Gustaaf and Amelinckx, Severin and Wright, A J and Greaves, C.},
 journal = {Chemistry of Materials},
 number = {9}
}

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