@article{miyashita_synthesis_1998,
	title = {Synthesis and crystal structure of a dinuclear platinum ({II}) bis ({N},{N}-diethylamino) carbeniumdithiocarboxylate complex {Pt2}\{μ-({Et2N}){2C2S} 2\}{2Cl4}·0.{5CH2Cl2}: {Structural} study of the coordinated inner salt},
	volume = {283},
	issn = {00201693},
	doi = {10.1016/S0020-1693(98)00310-7},
	abstract = {The bis(diethylamino)carbeniumdithiocarboxylate-bridged Pt(II) dinuclear complex, Pt2\{(Et2N)2C2S2\} 2Cl4·0.5CH2Cl2, was synthesized and its X-ray crystal structure was solved. The two dithiocarboxylate ligands bridge the two Pt atoms in cis position. Although two possible inner-salt electronic structures, one with a C=C bond and the other with a C-C bond, had been postulated for the ligand, the actual C-C distances in the X-ray structure of the carbonium-carboxylate part of the ligand are 1.50(4) and 1.50(3) Å, suggesting that the bridging ligands are an inner-salt structure with a C-C single bond. The Pt-Pt distance is 3.094(2) Å and is not bonding. © 1998 Elsevier Science S.A. All rights reserved.},
	number = {1},
	journal = {Inorganica Chimica Acta},
	author = {Miyashita, Isao and Matsumoto, Kazuko and Kobayashi, Masaharu and Nagasawa, Akira and Nakayama, Juzo},
	year = {1998},
	keywords = {Bidentate sulfur ligand complexes, Crystal structures, Dinuclear complexes, Platinum complexes},
	pages = {256--259},
}

{"_id":"c8TrNvTE8TZDvbYQC","bibbaseid":"miyashita-matsumoto-kobayashi-nagasawa-nakayama-synthesisandcrystalstructureofadinuclearplatinumiibisnndiethylaminocarbeniumdithiocarboxylatecomplexpt2et2n2c2s22cl405ch2cl2structuralstudyofthecoordinatedinnersalt-1998","author_short":["Miyashita, I.","Matsumoto, K.","Kobayashi, M.","Nagasawa, A.","Nakayama, J."],"bibdata":{"bibtype":"article","type":"article","title":"Synthesis and crystal structure of a dinuclear platinum (II) bis (N,N-diethylamino) carbeniumdithiocarboxylate complex Pt2\\μ-(Et2N)2C2S 2\\2Cl4·0.5CH2Cl2: Structural study of the coordinated inner salt","volume":"283","issn":"00201693","doi":"10.1016/S0020-1693(98)00310-7","abstract":"The bis(diethylamino)carbeniumdithiocarboxylate-bridged Pt(II) dinuclear complex, Pt2\\(Et2N)2C2S2\\ 2Cl4·0.5CH2Cl2, was synthesized and its X-ray crystal structure was solved. The two dithiocarboxylate ligands bridge the two Pt atoms in cis position. Although two possible inner-salt electronic structures, one with a C=C bond and the other with a C-C bond, had been postulated for the ligand, the actual C-C distances in the X-ray structure of the carbonium-carboxylate part of the ligand are 1.50(4) and 1.50(3) Å, suggesting that the bridging ligands are an inner-salt structure with a C-C single bond. The Pt-Pt distance is 3.094(2) Å and is not bonding. © 1998 Elsevier Science S.A. All rights reserved.","number":"1","journal":"Inorganica Chimica Acta","author":[{"propositions":[],"lastnames":["Miyashita"],"firstnames":["Isao"],"suffixes":[]},{"propositions":[],"lastnames":["Matsumoto"],"firstnames":["Kazuko"],"suffixes":[]},{"propositions":[],"lastnames":["Kobayashi"],"firstnames":["Masaharu"],"suffixes":[]},{"propositions":[],"lastnames":["Nagasawa"],"firstnames":["Akira"],"suffixes":[]},{"propositions":[],"lastnames":["Nakayama"],"firstnames":["Juzo"],"suffixes":[]}],"year":"1998","keywords":"Bidentate sulfur ligand complexes, Crystal structures, Dinuclear complexes, Platinum complexes","pages":"256–259","bibtex":"@article{miyashita_synthesis_1998,\n\ttitle = {Synthesis and crystal structure of a dinuclear platinum ({II}) bis ({N},{N}-diethylamino) carbeniumdithiocarboxylate complex {Pt2}\\{μ-({Et2N}){2C2S} 2\\}{2Cl4}·0.{5CH2Cl2}: {Structural} study of the coordinated inner salt},\n\tvolume = {283},\n\tissn = {00201693},\n\tdoi = {10.1016/S0020-1693(98)00310-7},\n\tabstract = {The bis(diethylamino)carbeniumdithiocarboxylate-bridged Pt(II) dinuclear complex, Pt2\\{(Et2N)2C2S2\\} 2Cl4·0.5CH2Cl2, was synthesized and its X-ray crystal structure was solved. The two dithiocarboxylate ligands bridge the two Pt atoms in cis position. Although two possible inner-salt electronic structures, one with a C=C bond and the other with a C-C bond, had been postulated for the ligand, the actual C-C distances in the X-ray structure of the carbonium-carboxylate part of the ligand are 1.50(4) and 1.50(3) Å, suggesting that the bridging ligands are an inner-salt structure with a C-C single bond. The Pt-Pt distance is 3.094(2) Å and is not bonding. © 1998 Elsevier Science S.A. All rights reserved.},\n\tnumber = {1},\n\tjournal = {Inorganica Chimica Acta},\n\tauthor = {Miyashita, Isao and Matsumoto, Kazuko and Kobayashi, Masaharu and Nagasawa, Akira and Nakayama, Juzo},\n\tyear = {1998},\n\tkeywords = {Bidentate sulfur ligand complexes, Crystal structures, Dinuclear complexes, Platinum complexes},\n\tpages = {256--259},\n}\n\n\n\n","author_short":["Miyashita, I.","Matsumoto, K.","Kobayashi, M.","Nagasawa, A.","Nakayama, J."],"key":"miyashita_synthesis_1998","id":"miyashita_synthesis_1998","bibbaseid":"miyashita-matsumoto-kobayashi-nagasawa-nakayama-synthesisandcrystalstructureofadinuclearplatinumiibisnndiethylaminocarbeniumdithiocarboxylatecomplexpt2et2n2c2s22cl405ch2cl2structuralstudyofthecoordinatedinnersalt-1998","role":"author","urls":{},"keyword":["Bidentate sulfur ligand complexes","Crystal structures","Dinuclear complexes","Platinum complexes"],"metadata":{"authorlinks":{}},"html":""},"bibtype":"article","biburl":"https://bibbase.org/zotero/FRGBergamini","dataSources":["o2mL7kG99iAQPpNRJ"],"keywords":["bidentate sulfur ligand complexes","crystal structures","dinuclear complexes","platinum complexes"],"search_terms":["synthesis","crystal","structure","dinuclear","platinum","bis","diethylamino","carbeniumdithiocarboxylate","complex","pt2","et2n","2c2s","2cl4","5ch2cl2","structural","study","coordinated","inner","salt","miyashita","matsumoto","kobayashi","nagasawa","nakayama"],"title":"Synthesis and crystal structure of a dinuclear platinum (II) bis (N,N-diethylamino) carbeniumdithiocarboxylate complex Pt2\\μ-(Et2N)2C2S 2\\2Cl4·0.5CH2Cl2: Structural study of the coordinated inner salt","year":1998}