@ARTICLE{Mongay1982307,
author={Mongay, C. and Garcia, M.C. and Ramis, G.},
title={Calculation of neutralization enthalpies from thermometric titrations of diprotic and triprotic acids using a linear least-squares method},
journal={Thermochimica Acta},
year={1982},
volume={56},
number={3},
pages={307-323},
doi={10.1016/0040-6031(82)87039-1},
note={cited By 3},
url={https://www.scopus.com/inward/record.uri?eid=2-s2.0-26344462293&doi=10.1016%2f0040-6031%2882%2987039-1&partnerID=40&md5=0e6a81da288ded0ad4aa0ab03053d2e7},
affiliation={Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, Valencia, Spain},
abstract={The application of thermometric titrimetries to the determination of enthalpies of neutralization of diprotic and triprotic acids using a linear least-squares method is studied critically. The best way of fitting is investigated by analyzing the experimental data for a series of simulated titration curves of a number of acids. The conclusions are applied to the calculation of the enthalpies of maleinimidedioxime, thiodi- propionic and thiodiglycolic acids (diprotic systems), and citric acid. © 1982.},
references={Borrull, (1981) Licenciature Thesis, , Faculty of Chemistry, University of Barcelona; Christensen, Izatt, Hansen, Partridge, (1966) J. Phys. Chem., 70, p. 2003; Izatt, Christensen, THERMODYNAMICS OF PROTON DISSOCIATION IN DILUTE AQUEOUS SOLUTION. I. EQUILIBRIUM CONSTANTS FOR THE STEPWISE DISSOCIATION OF PROTONS FROM PROTONATED ADENINE, ADENOSINE, RIBOSE-5-PHOSPHATE AND ADENOSINEDIPHOSPHATE1 (1962) The Journal of Physical Chemistry, 66, p. 1030; E. Casassas, F. Borrull, M. Esteban and V. Cerdá, Thermochim. Acta, in press; M.L. Albelda, V. Cerdá and C. Mongay, J. Therm. Anal., in press; Barthel, Becker, Schmahl, Untersuchungen über die Grundlagen der thermometrischen Titration* (1961) Zeitschrift für Physikalische Chemie, 29, p. 58; Sillén, High-speed Computers as Supplement to Graphical Methods. I. Functional Behavior of the Error Square Sum. (1962) Acta Chemica Scandinavica, 16, p. 159; Mongay, Ramis, Garcia, (1982) Spectrochim. Acta Part A, 38, p. 247; Grenthe, Ots, Ginstrup, A Calorimetric Determination of the Enthalpy of Ionization of Water and the Enthalpy of Protonation of THAM at 5, 20, 25, 35, and 50 Degrees C. (1970) Acta Chemica Scandinavica, 24, p. 1067; Davies, Hoyle, 842. The interaction of calcium ions with some phosphate and citrate buffers (1953) Journal of the Chemical Society (Resumed), p. 4134; Bates, Pinching, (1949) J. Am. Chem. Soc., 71, p. 1274; Arena, Cali, Grasso, Musumeci, Sammartano, (1980) Thermochim. Acta., 36, p. 329},
correspondence_address1={Mongay, C.; Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, Valencia, Spain},
issn={00406031},
coden={THACA},
language={English},
abbrev_source_title={Thermochim Acta},
document_type={Article},
source={Scopus},
}

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The best way of fitting is investigated by analyzing the experimental data for a series of simulated titration curves of a number of acids. The conclusions are applied to the calculation of the enthalpies of maleinimidedioxime, thiodi- propionic and thiodiglycolic acids (diprotic systems), and citric acid. © 1982.","references":"Borrull, (1981) Licenciature Thesis, , Faculty of Chemistry, University of Barcelona; Christensen, Izatt, Hansen, Partridge, (1966) J. Phys. Chem., 70, p. 2003; Izatt, Christensen, THERMODYNAMICS OF PROTON DISSOCIATION IN DILUTE AQUEOUS SOLUTION. I. EQUILIBRIUM CONSTANTS FOR THE STEPWISE DISSOCIATION OF PROTONS FROM PROTONATED ADENINE, ADENOSINE, RIBOSE-5-PHOSPHATE AND ADENOSINEDIPHOSPHATE1 (1962) The Journal of Physical Chemistry, 66, p. 1030; E. Casassas, F. Borrull, M. Esteban and V. Cerdá, Thermochim. Acta, in press; M.L. Albelda, V. Cerdá and C. Mongay, J. Therm. Anal., in press; Barthel, Becker, Schmahl, Untersuchungen über die Grundlagen der thermometrischen Titration* (1961) Zeitschrift für Physikalische Chemie, 29, p. 58; Sillén, High-speed Computers as Supplement to Graphical Methods. I. Functional Behavior of the Error Square Sum. (1962) Acta Chemica Scandinavica, 16, p. 159; Mongay, Ramis, Garcia, (1982) Spectrochim. Acta Part A, 38, p. 247; Grenthe, Ots, Ginstrup, A Calorimetric Determination of the Enthalpy of Ionization of Water and the Enthalpy of Protonation of THAM at 5, 20, 25, 35, and 50 Degrees C. (1970) Acta Chemica Scandinavica, 24, p. 1067; Davies, Hoyle, 842. The interaction of calcium ions with some phosphate and citrate buffers (1953) Journal of the Chemical Society (Resumed), p. 4134; Bates, Pinching, (1949) J. Am. Chem. Soc., 71, p. 1274; Arena, Cali, Grasso, Musumeci, Sammartano, (1980) Thermochim. 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The best way of fitting is investigated by analyzing the experimental data for a series of simulated titration curves of a number of acids. The conclusions are applied to the calculation of the enthalpies of maleinimidedioxime, thiodi- propionic and thiodiglycolic acids (diprotic systems), and citric acid. © 1982.},\nreferences={Borrull, (1981) Licenciature Thesis, , Faculty of Chemistry, University of Barcelona; Christensen, Izatt, Hansen, Partridge, (1966) J. Phys. Chem., 70, p. 2003; Izatt, Christensen, THERMODYNAMICS OF PROTON DISSOCIATION IN DILUTE AQUEOUS SOLUTION. I. EQUILIBRIUM CONSTANTS FOR THE STEPWISE DISSOCIATION OF PROTONS FROM PROTONATED ADENINE, ADENOSINE, RIBOSE-5-PHOSPHATE AND ADENOSINEDIPHOSPHATE1 (1962) The Journal of Physical Chemistry, 66, p. 1030; E. Casassas, F. Borrull, M. Esteban and V. Cerdá, Thermochim. Acta, in press; M.L. Albelda, V. Cerdá and C. Mongay, J. Therm. 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