@article{
 title = {Electron Capture Dissociation of Trithiocarbonate-Terminated Acrylamide Homo- And Copolymers: A Terminus-Directed Mechanism?},
 type = {article},
 year = {2020},
 id = {67c2811a-1ff3-3afa-9564-6f53ed8224e5},
 created = {2020-10-12T23:59:00.000Z},
 file_attached = {false},
 profile_id = {9f6c4084-7a51-3e30-8518-5a3d275e6797},
 last_modified = {2020-10-15T04:08:16.774Z},
 read = {false},
 starred = {false},
 authored = {true},
 confirmed = {false},
 hidden = {false},
 private_publication = {false},
 abstract = {Copyright © 2020 American Chemical Society. The structure and sequence elucidation of complex homo- and copolymers is key for further understanding polymers, polymer synthesis, and polymer interactions in biological processes. In this contribution, poly(dimethylacrylamide) homo- and dimethylacrylamide/4-acryloylmorpholine block copolymers were synthesized and analyzed by electron capture dissociation (ECD) and Fourier transform ion cyclotron resonance (FT-ICR) tandem mass spectrometry. Double-resonance experiments were carried out, providing a better understanding of the fragmentation process. A novel radical dissociation process is presented, and electron capture caused a specific cleavage at the terminal butyl-trithiocarbonate group, which initiated a free radical dissociation process.},
 bibtype = {article},
 author = {Morgan, T.E. and Kerr, A. and Wootton, C.A. and Barrow, M.P. and Bristow, A.W.T. and Perrier, S. and O'connor, P.B.},
 doi = {10.1021/acs.analchem.0c01224},
 journal = {Analytical Chemistry}
}

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