Alkyl-templated cocrystallization of long-chain 1-bromoalkanes by lipid-like ionic liquids. Musozoda, M., Muller, J. E., Anderson, G. I., Boucher, M., Zeller, M., Raymond, C. C., Hillesheim, P. C., & Mirjafari, A. Chem. Commun., 60(13):1723–1726, 2024. Publisher: The Royal Society of Chemistry
Paper doi abstract bibtex The serendipitous discovery of an unorthodox ionic cocrystallization system using 2-mercaptothiazolium-based ionic liquids as a crystallization milieu paves the way for the first report of crystal structures of long-chain 1-bromoalkanes. We used single crystal X-ray diffraction to determine the structures of 1-bromo-hexadecane and 1-octadecane with the aid of ionic liquids with alkyl side chains of equivalent length to the bromoalkane at room temperature. Long alkyl chains in combination with σ-hole interactions from strategically placed sulfur motifs synergistically function to crystallize the 1-bromoalkanes.
@article{musozoda_alkyl-templated_2024,
title = {Alkyl-templated cocrystallization of long-chain 1-bromoalkanes by lipid-like ionic liquids},
volume = {60},
copyright = {All rights reserved},
url = {http://dx.doi.org/10.1039/D3CC04834A},
doi = {10.1039/D3CC04834A},
abstract = {The serendipitous discovery of an unorthodox ionic cocrystallization system using 2-mercaptothiazolium-based ionic liquids as a crystallization milieu paves the way for the first report of crystal structures of long-chain 1-bromoalkanes. We used single crystal X-ray diffraction to determine the structures of 1-bromo-hexadecane and 1-octadecane with the aid of ionic liquids with alkyl side chains of equivalent length to the bromoalkane at room temperature. Long alkyl chains in combination with σ-hole interactions from strategically placed sulfur motifs synergistically function to crystallize the 1-bromoalkanes.},
number = {13},
journal = {Chem. Commun.},
author = {Musozoda, Muhammadiqboli and Muller, Joseph E. and Anderson, Grace I. and Boucher, Mairead and Zeller, Matthias and Raymond, Casey C. and Hillesheim, Patrick C. and Mirjafari, Arsalan},
year = {2024},
note = {Publisher: The Royal Society of Chemistry},
pages = {1723--1726},
}
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