@article{
 title = {Ozonolysis and photolysis of alkene-terminated self-assembled monolayers on quartz nanoparticles: implications for photochemical aging of organic aerosol particles.},
 type = {article},
 year = {2006},
 identifiers = {[object Object]},
 pages = {2506-12},
 volume = {8},
 websites = {http://www.ncbi.nlm.nih.gov/pubmed/16721435},
 month = {6},
 day = {7},
 id = {9e6e4a12-c7b3-3de6-9089-67f402ea17e5},
 created = {2015-05-08T02:32:35.000Z},
 accessed = {2014-11-14},
 file_attached = {true},
 profile_id = {f8c267c4-4c39-31dc-80fa-3a9691373386},
 group_id = {63e349d6-2c70-3938-9e67-2f6483f6cbab},
 last_modified = {2015-05-08T09:39:27.000Z},
 read = {false},
 starred = {false},
 authored = {false},
 confirmed = {true},
 hidden = {false},
 abstract = {Photolysis of alkene-terminated self assembled monolayers (SAM) deposited on Degussa SiO(2) nanoparticles is studied following oxidation of SAM with a gaseous ozone/oxygen mixture. Infrared cavity ring-down spectroscopy is used to observe gas-phase products generated during ozonolysis and subsequent photolysis of SAM in real time. Reactions taking place during ozonolysis transform alkene-terminated SAM into a photochemically active state capable of photolysis in the tropospheric actinic window (lambda > 295 nm). Formaldehyde and formic acid are the observed photolysis products. Photodissociation action spectra of oxidized SAM and the observed pattern of gas-phase products are consistent with the well-established Criegee mechanism of ozonolysis of terminal alkenes. There is strong evidence for the presence of secondary ozonides (1,3,4-trioxalones) and other peroxides on the oxidized SAM surface. The data imply that photolysis plays a role in atmospheric aging of primary and secondary organic aerosol particles.},
 bibtype = {article},
 author = {Park, Jiho and Gomez, Anthony L and Walser, Maggie L and Lin, Ao and Nizkorodov, Sergey a},
 journal = {Physical chemistry chemical physics : PCCP},
 number = {21}
}

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Infrared cavity ring-down spectroscopy is used to observe gas-phase products generated during ozonolysis and subsequent photolysis of SAM in real time. Reactions taking place during ozonolysis transform alkene-terminated SAM into a photochemically active state capable of photolysis in the tropospheric actinic window (lambda > 295 nm). Formaldehyde and formic acid are the observed photolysis products. Photodissociation action spectra of oxidized SAM and the observed pattern of gas-phase products are consistent with the well-established Criegee mechanism of ozonolysis of terminal alkenes. There is strong evidence for the presence of secondary ozonides (1,3,4-trioxalones) and other peroxides on the oxidized SAM surface. The data imply that photolysis plays a role in atmospheric aging of primary and secondary organic aerosol particles.","bibtype":"article","author":"Park, Jiho and Gomez, Anthony L and Walser, Maggie L and Lin, Ao and Nizkorodov, Sergey a","journal":"Physical chemistry chemical physics : PCCP","number":"21","bibtex":"@article{\n title = {Ozonolysis and photolysis of alkene-terminated self-assembled monolayers on quartz nanoparticles: implications for photochemical aging of organic aerosol particles.},\n type = {article},\n year = {2006},\n identifiers = {[object Object]},\n pages = {2506-12},\n volume = {8},\n websites = {http://www.ncbi.nlm.nih.gov/pubmed/16721435},\n month = {6},\n day = {7},\n id = {9e6e4a12-c7b3-3de6-9089-67f402ea17e5},\n created = {2015-05-08T02:32:35.000Z},\n accessed = {2014-11-14},\n file_attached = {true},\n profile_id = {f8c267c4-4c39-31dc-80fa-3a9691373386},\n group_id = {63e349d6-2c70-3938-9e67-2f6483f6cbab},\n last_modified = {2015-05-08T09:39:27.000Z},\n read = {false},\n starred = {false},\n authored = {false},\n confirmed = {true},\n hidden = {false},\n abstract = {Photolysis of alkene-terminated self assembled monolayers (SAM) deposited on Degussa SiO(2) nanoparticles is studied following oxidation of SAM with a gaseous ozone/oxygen mixture. 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