Ozonolysis of α-pinene: Parameterization of secondary organic aerosol mass fraction. Pathak, R., K., Presto, A., A., Lane, T., E., Stanier, C., O., Donahue, N., M., & Pandis, S., N. Atmospheric Chemistry and Physics, 7(14):3811-3821, COPERNICUS PUBLICATIONS, 2007. abstract bibtex Existing parameterizations tend to underpredict the alpha-pinene aerosol mass fraction (AMF) or yield by a factor of 2 & ndash;5 at low organic aerosol concentrations (< 5 mu g m(-3)). A wide range of smog chamber results obtained at various conditions (low/high NOx, presence/absence of UV radiation, dry/humid conditions, and temperatures ranging from 15-40 degrees C) collected by various research teams during the last decade are used to derive new parameterizations of the SOA formation from alpha-pinene ozonolysis. Parameterizations are developed by fitting experimental data to a basis set of saturation concentrations (from 10(-2) to 10(4) mu g m(-3)) using an absorptive equilibrium partitioning model. Separate parameterizations for alpha-pinene SOA mass fractions are developed for: 1) Low NOx, dark, and dry conditions, 2) Low NOx, UV, and dry conditions, 3) Low NOx, dark, and high RH conditions, 4) High NOx, dark, and dry conditions, 5) High NOx, UV, and dry conditions. According to the proposed parameterizations the alpha-pinene SOA mass fractions in an atmosphere with 5 mu g m(-3) of organic aerosol range from 0.032 to 0.1 for reacted alpha-pinene concentrations in the 1 ppt to 5 ppb range.
@article{
title = {Ozonolysis of α-pinene: Parameterization of secondary organic aerosol mass fraction},
type = {article},
year = {2007},
pages = {3811-3821},
volume = {7},
publisher = {COPERNICUS PUBLICATIONS},
city = {MAX-PLANCK-STR 13, KATHLENBURG-LINDAU, 37191, GERMANY},
id = {880a5b04-7af6-3d25-82f9-ddbbee9912b0},
created = {2014-10-08T16:28:18.000Z},
file_attached = {false},
profile_id = {363623ef-1990-38f1-b354-f5cdaa6548b2},
group_id = {02267cec-5558-3876-9cfc-78d056bad5b9},
last_modified = {2017-03-14T17:32:24.802Z},
read = {false},
starred = {false},
authored = {false},
confirmed = {true},
hidden = {false},
citation_key = {Pathak:acp:2007a},
source_type = {article},
private_publication = {false},
abstract = {Existing parameterizations tend to underpredict the alpha-pinene aerosol mass fraction (AMF) or yield by a factor of 2 & ndash;5 at low organic aerosol concentrations (< 5 mu g m(-3)). A wide range of smog chamber results obtained at various conditions (low/high NOx, presence/absence of UV radiation, dry/humid conditions, and temperatures ranging from 15-40 degrees C) collected by various research teams during the last decade are used to derive new parameterizations of the SOA formation from alpha-pinene ozonolysis. Parameterizations are developed by fitting experimental data to a basis set of saturation concentrations (from 10(-2) to 10(4) mu g m(-3)) using an absorptive equilibrium partitioning model. Separate parameterizations for alpha-pinene SOA mass fractions are developed for: 1) Low NOx, dark, and dry conditions, 2) Low NOx, UV, and dry conditions, 3) Low NOx, dark, and high RH conditions, 4) High NOx, dark, and dry conditions, 5) High NOx, UV, and dry conditions. According to the proposed parameterizations the alpha-pinene SOA mass fractions in an atmosphere with 5 mu g m(-3) of organic aerosol range from 0.032 to 0.1 for reacted alpha-pinene concentrations in the 1 ppt to 5 ppb range.},
bibtype = {article},
author = {Pathak, R K and Presto, A A and Lane, T E and Stanier, C O and Donahue, N M and Pandis, S N},
journal = {Atmospheric Chemistry and Physics},
number = {14}
}
Downloads: 0
{"_id":{"_str":"5411bfbb480d3bb0580029ec"},"__v":0,"authorIDs":[],"author_short":["Pathak, R., K.","Presto, A., A.","Lane, T., E.","Stanier, C., O.","Donahue, N., M.","Pandis, S., N."],"bibbaseid":"pathak-presto-lane-stanier-donahue-pandis-ozonolysisofpineneparameterizationofsecondaryorganicaerosolmassfraction-2007","bibdata":{"title":"Ozonolysis of α-pinene: Parameterization of secondary organic aerosol mass fraction","type":"article","year":"2007","pages":"3811-3821","volume":"7","publisher":"COPERNICUS PUBLICATIONS","city":"MAX-PLANCK-STR 13, KATHLENBURG-LINDAU, 37191, GERMANY","id":"880a5b04-7af6-3d25-82f9-ddbbee9912b0","created":"2014-10-08T16:28:18.000Z","file_attached":false,"profile_id":"363623ef-1990-38f1-b354-f5cdaa6548b2","group_id":"02267cec-5558-3876-9cfc-78d056bad5b9","last_modified":"2017-03-14T17:32:24.802Z","read":false,"starred":false,"authored":false,"confirmed":"true","hidden":false,"citation_key":"Pathak:acp:2007a","source_type":"article","private_publication":false,"abstract":"Existing parameterizations tend to underpredict the alpha-pinene aerosol mass fraction (AMF) or yield by a factor of 2 & ndash;5 at low organic aerosol concentrations (< 5 mu g m(-3)). A wide range of smog chamber results obtained at various conditions (low/high NOx, presence/absence of UV radiation, dry/humid conditions, and temperatures ranging from 15-40 degrees C) collected by various research teams during the last decade are used to derive new parameterizations of the SOA formation from alpha-pinene ozonolysis. Parameterizations are developed by fitting experimental data to a basis set of saturation concentrations (from 10(-2) to 10(4) mu g m(-3)) using an absorptive equilibrium partitioning model. Separate parameterizations for alpha-pinene SOA mass fractions are developed for: 1) Low NOx, dark, and dry conditions, 2) Low NOx, UV, and dry conditions, 3) Low NOx, dark, and high RH conditions, 4) High NOx, dark, and dry conditions, 5) High NOx, UV, and dry conditions. According to the proposed parameterizations the alpha-pinene SOA mass fractions in an atmosphere with 5 mu g m(-3) of organic aerosol range from 0.032 to 0.1 for reacted alpha-pinene concentrations in the 1 ppt to 5 ppb range.","bibtype":"article","author":"Pathak, R K and Presto, A A and Lane, T E and Stanier, C O and Donahue, N M and Pandis, S N","journal":"Atmospheric Chemistry and Physics","number":"14","bibtex":"@article{\n title = {Ozonolysis of α-pinene: Parameterization of secondary organic aerosol mass fraction},\n type = {article},\n year = {2007},\n pages = {3811-3821},\n volume = {7},\n publisher = {COPERNICUS PUBLICATIONS},\n city = {MAX-PLANCK-STR 13, KATHLENBURG-LINDAU, 37191, GERMANY},\n id = {880a5b04-7af6-3d25-82f9-ddbbee9912b0},\n created = {2014-10-08T16:28:18.000Z},\n file_attached = {false},\n profile_id = {363623ef-1990-38f1-b354-f5cdaa6548b2},\n group_id = {02267cec-5558-3876-9cfc-78d056bad5b9},\n last_modified = {2017-03-14T17:32:24.802Z},\n read = {false},\n starred = {false},\n authored = {false},\n confirmed = {true},\n hidden = {false},\n citation_key = {Pathak:acp:2007a},\n source_type = {article},\n private_publication = {false},\n abstract = {Existing parameterizations tend to underpredict the alpha-pinene aerosol mass fraction (AMF) or yield by a factor of 2 & ndash;5 at low organic aerosol concentrations (< 5 mu g m(-3)). A wide range of smog chamber results obtained at various conditions (low/high NOx, presence/absence of UV radiation, dry/humid conditions, and temperatures ranging from 15-40 degrees C) collected by various research teams during the last decade are used to derive new parameterizations of the SOA formation from alpha-pinene ozonolysis. Parameterizations are developed by fitting experimental data to a basis set of saturation concentrations (from 10(-2) to 10(4) mu g m(-3)) using an absorptive equilibrium partitioning model. Separate parameterizations for alpha-pinene SOA mass fractions are developed for: 1) Low NOx, dark, and dry conditions, 2) Low NOx, UV, and dry conditions, 3) Low NOx, dark, and high RH conditions, 4) High NOx, dark, and dry conditions, 5) High NOx, UV, and dry conditions. According to the proposed parameterizations the alpha-pinene SOA mass fractions in an atmosphere with 5 mu g m(-3) of organic aerosol range from 0.032 to 0.1 for reacted alpha-pinene concentrations in the 1 ppt to 5 ppb range.},\n bibtype = {article},\n author = {Pathak, R K and Presto, A A and Lane, T E and Stanier, C O and Donahue, N M and Pandis, S N},\n journal = {Atmospheric Chemistry and Physics},\n number = {14}\n}","author_short":["Pathak, R., K.","Presto, A., A.","Lane, T., E.","Stanier, C., O.","Donahue, N., M.","Pandis, S., N."],"bibbaseid":"pathak-presto-lane-stanier-donahue-pandis-ozonolysisofpineneparameterizationofsecondaryorganicaerosolmassfraction-2007","role":"author","urls":{},"downloads":0},"bibtype":"article","biburl":null,"creationDate":"2014-09-11T15:28:59.032Z","downloads":0,"keywords":["absorption-model","acidity","biogenic hydrocarbons","oxidation","ozone","products","relative-humidity","systems","terpene ozonolysis","yields"],"search_terms":["ozonolysis","pinene","parameterization","secondary","organic","aerosol","mass","fraction","pathak","presto","lane","stanier","donahue","pandis"],"title":"Ozonolysis of α-pinene: Parameterization of secondary organic aerosol mass fraction","year":2007}