Infusion mass spectrometry as a fingerprint to characterize varnishes in oil pictorial artworks. Peris-Vicente, J., Garrido-Medina, R., Simó-Alfonso, E., Gimeno-Adelantado, J., & Doménech-Carbó, M. Rapid Communications in Mass Spectrometry, 21(6):851-856, John Wiley and Sons Ltd, 2007. cited By 6
Infusion mass spectrometry as a fingerprint to characterize varnishes in oil pictorial artworks [link]Paper  doi  abstract   bibtex   
Mass spectrometry methodology to characterize drying oil used as binding media and varnishes in pictorial artworks, prior to conservation or restoration treatment, is proposed. The analytical treatment requires prior basic hydrolysis of the samples to release the fatty acids: caprylic, pelargonic, capric, sebacic, azelaic, suberic, eicosanoic, lauric, mirystic, palmitic, linolenic, linoleic, oleic and stearic, followed by separation from the matrix by a hexane/water extraction. After removing the solvent, the remaining solid is dissolved in potassium hydroxide, propanol and methanol. The mixture is directly infused into a mass spectrometer without any previous derivatization or separation steps. The detector is operated in electrospray negative ion mode and the [M-H]- ions of the fatty acids enable identification of the acids. Obtained data for fatty acid ion abundances are analyzed by linear discriminant analysis. The drying oils studied (linseed, poppy seed and walnut) were satisfactorily distinguished. The analytical method shows adequate sensitivity, reproducibility, speed and ease. The proposed methodology has been successfully applied to samples from artistic samples belonging to the Cultural Heritage of Valencia (Spain). Copyright © 2007 John Wiley & Sons, Ltd.
@ARTICLE{Peris-Vicente2007851,
author={Peris-Vicente, J. and Garrido-Medina, R. and Simó-Alfonso, E. and Gimeno-Adelantado, J.V. and Doménech-Carbó, M.T.},
title={Infusion mass spectrometry as a fingerprint to characterize varnishes in oil pictorial artworks},
journal={Rapid Communications in Mass Spectrometry},
year={2007},
volume={21},
number={6},
pages={851-856},
doi={10.1002/rcm.2913},
note={cited By 6},
url={https://www.scopus.com/inward/record.uri?eid=2-s2.0-33947238316&doi=10.1002%2frcm.2913&partnerID=40&md5=2c18a42b9ffa927886e352fb0f5af356},
affiliation={Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, C/Doctor Moliner 50, 46100-Burjassot, Valencia, Spain; Department of Conservation and Restoration of Cultural Heritage, Polytechnic University of Valencia, Camino de Vera 14, 46022-Valencia, Spain},
abstract={Mass spectrometry methodology to characterize drying oil used as binding media and varnishes in pictorial artworks, prior to conservation or restoration treatment, is proposed. The analytical treatment requires prior basic hydrolysis of the samples to release the fatty acids: caprylic, pelargonic, capric, sebacic, azelaic, suberic, eicosanoic, lauric, mirystic, palmitic, linolenic, linoleic, oleic and stearic, followed by separation from the matrix by a hexane/water extraction. After removing the solvent, the remaining solid is dissolved in potassium hydroxide, propanol and methanol. The mixture is directly infused into a mass spectrometer without any previous derivatization or separation steps. The detector is operated in electrospray negative ion mode and the [M-H]- ions of the fatty acids enable identification of the acids. Obtained data for fatty acid ion abundances are analyzed by linear discriminant analysis. The drying oils studied (linseed, poppy seed and walnut) were satisfactorily distinguished. The analytical method shows adequate sensitivity, reproducibility, speed and ease. The proposed methodology has been successfully applied to samples from artistic samples belonging to the Cultural Heritage of Valencia (Spain). Copyright © 2007 John Wiley & Sons, Ltd.},
keywords={Discriminant analysis;  Drying;  Linoleic acid;  Negative ions;  Organic solvents;  Palmitic acid;  Potassium hydroxide;  Varnish, Analytical treatment;  Basic hydrolysis;  Binding media;  Conservation treatment;  Eicosanoic;  Linoleic;  Linolenic;  matrix;  Restoration treatments;  Water extraction, Mass spectrometry},
references={Van der Berg, J.D.J., Van der Berg, K.J., Boon, J.J., (1999) Proc. 12th ICOM-CC Triennal Meeting, p. 248; Van der Berg, J.D.J., Van der Berg, K.J., Boon, J.J., (2002) J. Chromatogr. A, 950, p. 195; Van der Berg, J.D.J., Van der Berg, K.J., Boon, J.J., (2001) Progress Org. Coatings, 41, p. 143; Schillig, M.R., Khanjian, H.P., (1996) ICOM Committee for Conservation, p. 220; Regert, M., Bland, H.A., Dudd, S.N., Van Bergen, P.F., Evershed, R.P., (1998) Proc. Royal Soc, 265, p. 2027; Marinach, C., Papillon, M.C., Pepe, C., (2004) J. Cult. Heritage, 5, p. 231; Gimeno-Adelantado, J.V., Mateo-Castro, R., Doménech-Carbó, M.T., Bosch-Reig, F., Doménech-Carbó, A., De la Cruz-Cañizares, J., Casas-Catalan, M.J., (2002) Talanta, 56, p. 71; Mills, J.S., White, R., (1994) The Organic Chemistry of Museum Objects, , 4th edn, Butterworths: Oxford; Moya-Moreno, M.C.M., Mendoza-Olivares, D., Amezquita-López, F.J., Gimeno-Adelantado, J.V., Bosch-Reig, F., (1999) Talanta, 50, p. 269; Vandenabeele, P., Wehling, B., Monees, L., Edwards, H., De Reu, M., Van Hooydonk, G., (2000) Anal. Chim. Acta, 407, p. 261; Doménech-Carbó, A., Doménech-Carbó, M.T., Gimeno-Adelantado, J.V., Peris-Martínez, V., Bosch-Reig, F., (1998) Recent Res. Dev. Pure Appl. Anal. Chem, 1, p. 207; Peris-Vicente, J., Gimeno-Adelantado, J.V., Doménech-Carbó, M.T., Mateo-Castro, R., Bosch-Reig, F., (2004) J. Chromatogr. A, 1076, p. 44; Colombini, M.P., Modugno, F., Menicagli, E., Fuoco, R., Giacomelli, A., (2000) Microchem J, 67, p. 291; Surowiec, I., Kaml, I., Kenndler, E., (2004) J. Chromatogr. A, 1024, p. 245; Mateo-Castro, R., Doménech-Carbó, M.T., Peris-Martínez, V., Gimeno-Adelantado, J.V., Bosch-Reig, F., (1997) J. Chromatogr. A, 778, p. 373; Mateo-Castro, R., Gimeno-Adelantado, J.V., Bosch-Reig, F., Doménech- Carbó, A., Casas-Catalan, M.J., Osete-Cortina, L., De-la-Cruz-Cañizares, J., Doménech-Carbó, M.T., (2001) Fresenius J. Anal. Chem, 369, p. 642; Chiavari, G., Galletti, G.C., Linterna, G., Mazzeo, R., (1993) J. Anal. Appl. Pyrol, 24, p. 227; Ashes, J.R., Haken, J.K., Mills, S.C., (1980) J. Chromatogr, 187, p. 297; Colombini, M.P., Modugno, F., Fuocco, R., Tognazzi, A., (2002) Michrochem. J, 73, p. 175; Colombini, M.P., Modugno, F., Menicagli, E., Fuocco, R., Giacomelli, A., (2000) Michrochem. J, 67, p. 291; Colombini, M.P., Modugno, F., Giacomelli, A., Francesconi, S., (1999) J. Chromatogr. A, 846, p. 113; Casoli, A., Musini, P.C., Palla, G., (1996) J. Chromatogr. A, 731, p. 237; Casoli, A., Musini, P.C., Palla, G., (1996) Chromatographia, 42, p. 421; Mills, J.S., (1966) Studies in Conservation, 11, p. 92; Peris-Vicente, J., Gimeno-Adelantado, J.V., Doménech-Carbó, M.T., Mateo-Castro, R., Bosch-Reig, F., (2004) Talanta, 64, p. 326; Toyo'oka, T., (2002) Anal. Chim. Acta, 485, p. 111; Peris-Vicente, J., Simo-Alfonso, E., Gimeno-Adelantado, J.V., Doménech-Carbó, M.T., (2005) Rapid Commun. Mass Spectrom, 19, p. 3463; Chen, M.J., Chen, H.S., Lin, C.Y., Chang, H.T., (1999) J. Chromatogr. A, 853, p. 171; Kotani, A., Fuse, T., Kusu, F., (2000) Anal. Biochem, 284, p. 65; Erskine, S.R., Bobbit, D.R., (1989) Anal. Chem, 61, p. 910; Morita, H., Konishi, M., (2003) Anal. Chem, 75, p. 940; Tsuyama, Y., Ushida, T., (1992) J. Chromatogr. A, 596, p. 181; Claasen, F.W., Van de Haar, C., Van Beek, T.A., Dorado, J., Martínez- Iñigo, M.J., Sierra-Alvarez, R., (2000) Phytochem. Anal, 11, p. 241; Johnson, D.W., (2005) Clin. Biochem, 38, p. 351; Sandra, P., Medvedovici, A., Zhao, Y., David, F., (2002) J. Chromatogr. A, 974, p. 231; Gamoh, K., Saitoh, H., Wada, H., (2003) Rapid Commun. Mass Spectrom, 17, p. 685; Helaleh, M.I.H., Tanaka, K., Taoda, H., Hu, W., Hasebe, K., Haddad, P.R., (2002) J. Chromatogr. A, 956, p. 201; Latorre, A., Rigol, A., Lacorte, S., (2003) J. Chromatogr. A, 991, p. 205; Perret, D., Gentili, A., Marchese, S., Sergi, M., Caporosi, I., (1989) Rapid Commun. Mass Spectrom. 2004, 18; Odlyha, M., Cohen, N.S., Foster, G.M., (2000) Thermochim. Acta, 365, p. 34; Miller, J.N., Miller, J.C., (2000) Statistics and Chemometrics for Analytical Chemistry, , 4th edn, Prentice-Hall: Harlow, UK},
correspondence_address1={Simó-Alfonso, E.; Department of Analytical Chemistry, C/Doctor Moliner 50, 46100-Burjassot, Valencia, Spain; email: ernesto.simo@uv.es},
publisher={John Wiley and Sons Ltd},
issn={09514198},
coden={RCMSE},
language={English},
abbrev_source_title={Rapid Commun. Mass Spectrom.},
document_type={Article},
source={Scopus},
}

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