Analytical theory of gamma-encoded double-quantum recoupling sequences in solid-state nuclear magnetic resonance. Pileio, G., Concistrè, M., McLean, N., Gansmüller, A., Brown, R. C D, & Levitt, M. H Journal of magnetic resonance (San Diego, Calif. : 1997), 186(1):65–74, May, 2007.
Paper doi abstract bibtex Many important double-quantum recoupling techniques in solid-state NMR are classified as being gamma-encoded. This means that the phase of the double-quantum effective Hamiltonian, but not its amplitude, depends on the third Euler angle defining the orientation of the molecular spin system in the frame of the magic-angle-spinning rotor. In this paper, we provide closed analytical solutions for the dependence of the powder-average double-quantum-filtered signal on the recoupling times, within the average Hamiltonian approximation for gamma-encoded pulse sequences. The validity of the analytical solutions is tested by numerical simulations. The internuclear distance in a (13)C(2)-labelled retinal is estimated by fitting the analytical curves to experimental double-quantum data.
@article{Pileio2007,
title = {Analytical theory of gamma-encoded double-quantum recoupling sequences in solid-state nuclear magnetic resonance.},
volume = {186},
issn = {1090-7807},
url = {http://www.ncbi.nlm.nih.gov/pubmed/17303455},
doi = {10.1016/j.jmr.2007.01.009},
abstract = {Many important double-quantum recoupling techniques in solid-state NMR are classified as being gamma-encoded. This means that the phase of the double-quantum effective Hamiltonian, but not its amplitude, depends on the third Euler angle defining the orientation of the molecular spin system in the frame of the magic-angle-spinning rotor. In this paper, we provide closed analytical solutions for the dependence of the powder-average double-quantum-filtered signal on the recoupling times, within the average Hamiltonian approximation for gamma-encoded pulse sequences. The validity of the analytical solutions is tested by numerical simulations. The internuclear distance in a (13)C(2)-labelled retinal is estimated by fitting the analytical curves to experimental double-quantum data.},
number = {1},
urldate = {2014-01-19},
journal = {Journal of magnetic resonance (San Diego, Calif. : 1997)},
author = {Pileio, Giuseppe and Concistrè, Maria and McLean, Neville and Gansmüller, Axel and Brown, Richard C D and Levitt, Malcolm H},
month = may,
year = {2007},
pmid = {17303455},
keywords = {Algorithms, Chemical, Computer Simulation, Magnetic Resonance Spectroscopy, Magnetic Resonance Spectroscopy: methods, Models, Molecular, Powders, Quantum Theory, Reproducibility of Results, Sensitivity and Specificity},
pages = {65--74},
}
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